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公开(公告)号：US07439406B2
公开(公告)日：2008-10-21
申请号：US10553195
申请日：2004-04-14
CPC分类号： C07C29/141 , C07C31/20
摘要： Disclosed is a method for the catalytic hydrogenation of methylol alkanals of general formula (I), where R1 and R2 independently represent an additional methylol group or an alkyl group having with 1 to 22 carbon atoms, or an alkyl group with 1 to 22 C atoms, or an aryl group or aralkyl group with 6 to 33 carbon atoms, in the liquid phase on a hydrogenation catalyst. The inventive method is characterized in that a pH value ranging between 6.3 and 7.8 is adjusted in the hydrogenation feed by adding at least one tertiary amine
摘要翻译： 公开了用于催化氢化通式（I）的羟甲基链烷烃的方法，其中R 1和R 2独立代表另外的羟甲基或具有 1〜22个碳原子，或1〜22个碳原子的烷基，或6〜33个碳原子的芳基或芳烷基。 本发明的方法的特征在于通过加入至少一种叔胺在氢化进料中调节范围在6.3和7.8之间的pH值
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2.发明申请Method for the hydrodecomposition of ammonium formates in polyolcontaining reaction mixtures 审中-公开在含多元醇的反应混合物中氢化甲酸铵的分解方法公开(公告)号：US20070197837A1
公开(公告)日：2007-08-23
申请号：US10566374
申请日：2004-07-07
IPC分类号： C07C43/32
CPC分类号： C07C29/88 , B01J21/063 , B01J23/462 , B01J37/0009 , B01J37/06 , C07C31/22
摘要： A process for removing trialkylammonium formate from methylolalkanes which have been obtained by condensation of formaldehyde with a higher aldehyde comprises decomposing trialkylammonium formate at elevated temperature in the presence of a hydrogen-containing gas over a catalyst comprising ruthenium supported on titanium dioxide. The process makes it possible to separate off the trialkylammonium formate from methylolalkanes prepared by the organic Cannizzaro process or by the hydrogenation process.
摘要翻译： 通过甲醛与较高级醛缩合得到的甲羟烷基甲烷脱甲基铵的方法包括在含氢气体存在下，在包含负载在二氧化钛上的钌的催化剂的高温下分解三烷基铵甲酸盐。 该方法使得可以从由有机Cannizzaro工艺制备的羟甲基烷烃或通过氢化方法分离三烷基铵甲酸酯。
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公开(公告)号：US20060205985A1
公开(公告)日：2006-09-14
申请号：US10553195
申请日：2004-04-14
IPC分类号： C07C29/14
CPC分类号： C07C29/141 , C07C31/20
摘要： Process for the catalytic hydrogenation of methylolalkanals of the formula where R1 and R2 are each, independently of one another, a further methylol group or an alkyl group having from 1 to 22 carbon atoms or an aryl or aralkyl group having from 6 to 33 carbon atoms, in the liquid phase over a hydrogenation catalyst, wherein the pH of the hydrogenation feed is set to from 6.3 to 7.8 by addition of at least one tertiary amine.
摘要翻译： 下式的羟甲基烷烃的催化氢化方法，其中R 1和R 2各自彼此独立地是另外的羟甲基或具有1至 22个碳原子或具有6至33个碳原子的芳基或芳烷基，在氢化催化剂中的液相中，其中通过加入至少一种叔胺将氢化进料的pH设定为6.3至7.8。
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4.发明授权公开(公告)号：US07112707B2
公开(公告)日：2006-09-26
申请号：US10497522
申请日：2002-12-06
摘要： Trimethylolpropane is isolated from a reaction mixture which has been obtained by reaction of n-butyraldehyde with formaldehyde in the presence of a base and, if appropriate, hydrogenation of the resulting mixture by distilling the mixture by means of a dividing wall column or a distillation column with a precolumn or a distillation column with an after-column. The process has low capital costs and a low energy consumption and gives reduced formation of high-boiling by-products.
摘要翻译： 三羟甲基丙烷从通过正丁醛与甲醛在碱的存在下反应获得的反应混合物中分离出来，如果合适的话，通过用分隔壁塔或蒸馏塔蒸馏所得混合物进行氢化， 用预柱或具有后柱的蒸馏塔。 该方法具有较低的资本成本和低能耗，减少了高沸点副产物的形成。
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5.发明申请Method for increasing yield in the production of polyvalent alcohols by splitting by-products containing acetal 失效通过分解含缩醛的副产物来提高多元醇生产中产率的方法公开(公告)号：US20050256346A1
公开(公告)日：2005-11-17
申请号：US10521810
申请日：2003-07-18
IPC分类号： C07C29/10 , C07C29/141 , C07C29/88 , C07C45/75 , C07C29/14
摘要： The invention relates to a method for increasing yield in the production of polyvalent alcohols, especially trimethylolpropane, obtained by condensing formaldehyde with a higher aldehyde. According to the inventive method, acid treatment is carried out on a mixture (high-boiling fraction) that is obtained by reprocessing, contains derivatives of said alcohols and has a higher boiling point than the respective alcohol, and the polyvalent alcohol is recovered from the acid-treated high-boiling fraction. The inventive method is characterised in that the water content of the high-boiling fraction amounts to between 20 and 90 wt. % in relation to the entire mixture of the high-boiling fraction and water.
摘要翻译： 本发明涉及通过将甲醛与较高级醛缩合而获得的多价醇，特别是三羟甲基丙烷的生产中提高产量的方法。 根据本发明的方法，通过后处理获得的含有所述醇的衍生物并且具有比各醇更高的沸点的混合物（高沸点馏分）进行酸处理，并且从所述醇中回收多元醇 酸处理的高沸点馏分。 本发明的方法的特征在于高沸点馏分的含水量在20-90wt。之间。 相对于高沸点馏分和水的整个混合物的％。
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6.发明授权Method for the decomposition of ammonium formates in reaction mixtures containing polyol 失效在含有多元醇的反应混合物中分解甲酸铵的方法公开(公告)号：US06914164B2
公开(公告)日：2005-07-05
申请号：US10493497
申请日：2002-10-18
CPC分类号： C07C29/88 , C07C31/12 , C07C31/20 , C07C31/22 , C07C31/205
摘要： A method for removing trialkyl ammonium formate from a methylol alkanes obtained by condensation of formaldehyde with a higher aldehyde. The invention is characterized in that trialkyl ammonium formate is decomposed at a high temperature using catalysts containing at least one metal from groups 8-12 of the classification of elements in the presence of gas containing hydrogen. The method makes it possible to separate trialkyl ammonium formate according to the organic Cannizzaro method and according to the hydrogenation method.
摘要翻译： 一种从甲醛与较高级醛缩合得到的羟甲基烷烃中除去三烷基甲酸铵的方法。 本发明的特征在于，使用含有至少一种金属的催化剂在高温下分解三烷基铵甲酸盐，所述催化剂含有元素分类的第8-12族金属。 该方法可以根据有机Cannizzaro方法和根据氢化方法分离甲酸三烷基铵。
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公开(公告)号：US20050203268A1
公开(公告)日：2005-09-15
申请号：US10512851
申请日：2003-05-21
CPC分类号： C07C29/80 , C08G18/4208 , C08G18/4219 , C08G63/12 , C08G63/78 , C07C31/20 , C07C31/22 , C07C31/205 , C07C31/245
摘要： The invention provides a process for preparing polyester polyols of polyhydric alcohols by mono- or polyesterification of at least one carboxylic acid having at least two acid groups and/or at least one derivative of a dicarboxylic acid with polyhydric alcohols, optionally with the addition of a catalyst, while removing the water of reaction, wherein the polyhydric alcohol used has a formaldehyde acetal content of less than 500 ppm.
摘要翻译： 本发明提供了通过至少一种具有至少两个酸基的羧酸和/或至少一种二羧酸衍生物与多元醇进行单酯化或聚酯化制备多元醇的聚酯多元醇的方法，任选地加入 催化剂，同时除去反应水，其中所用的多元醇具有小于500ppm的甲醛缩醛含量。
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8.发明申请公开(公告)号：US20050010065A1
公开(公告)日：2005-01-13
申请号：US10494522
申请日：2002-11-08
申请人： Alexander Wartini , Matthias Dernbach , Jurgen Schroder , Friedrich-Georg Martin , Tilman Sirch
发明人： Alexander Wartini , Matthias Dernbach , Jurgen Schroder , Friedrich-Georg Martin , Tilman Sirch
IPC分类号： C07C67/08 , C07B61/00 , C07C29/141 , C07C29/80 , C07C31/22 , C07C51/50 , C07C67/62 , C07C69/54 , C07C69/52
摘要： (Meth)acrylates of polyhydric alcohols are prepared by reacting (meth)acrylic acid and the corresponding polyhydric alcohol in the presence of at least one acidic catalyst and, if required, at least one polymerization inhibitor and in the presence or absence of a solvent, by a process in which the polyhydric alcohol used contains less than 500 ppm of bound formaldehyde.
摘要翻译： （甲基）丙烯酸酯通过使（甲基）丙烯酸和相应的多元醇在至少一种酸性催化剂和（如果需要的话）至少一种聚合抑制剂存在下反应制备，并且在溶剂存在或不存在下， 所用的多元醇含有少于500ppm的结合甲醛的方法。
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公开(公告)号：US07241914B2
公开(公告)日：2007-07-10
申请号：US10512851
申请日：2003-05-21
IPC分类号： C07C69/34
CPC分类号： C07C29/80 , C08G18/4208 , C08G18/4219 , C08G63/12 , C08G63/78 , C07C31/20 , C07C31/22 , C07C31/205 , C07C31/245
摘要： The invention provides a process for preparing polyester polyols of polyhydric alcohols by mono- or polyesterification of at least one carboxylic acid having at least two acid groups and/or at least one derivative of a dicarboxylic acid with polyhydric alcohols, optionally with the addition of a catalyst, while removing the water of reaction, wherein the polyhydric alcohol used has a formaldehyde acetal content of less than 500 ppm.
摘要翻译： 本发明提供了通过至少一种具有至少两个酸基的羧酸和/或至少一种二羧酸衍生物与多元醇进行单酯化或聚酯化制备多元醇的聚酯多元醇的方法，任选地加入 催化剂，同时除去反应水，其中所用的多元醇具有小于500ppm的甲醛缩醛含量。
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10.发明授权Method for increasing yield in the production of polyvalent alcohols by splitting by-products containing acetal 失效通过分解含缩醛的副产物来提高多元醇生产中产率的方法公开(公告)号：US07301058B2
公开(公告)日：2007-11-27
申请号：US10521810
申请日：2003-07-18
IPC分类号： C07C31/18
摘要： The invention relates to a method for increasing yield in the production of polyvalent alcohols, especially trimethylolpropane, obtained by condensing formaldehyde with a higher aldehyde. According to the inventive method, acid treatment is carried out on a mixture (high-boiling fraction) that is obtained by reprocessing, contains derivatives of said alcohols and has a higher boiling point than the respective alcohol, and the polyvalent alcohol is recovered from the acid-treated high-boiling fraction. The inventive method is characterised in that the water content of the high-boiling fraction amounts to between 20 and 90 wt. % in relation to the entire mixture of the high-boiling fraction and water.
摘要翻译： 本发明涉及通过将甲醛与较高级醛缩合而获得的多价醇，特别是三羟甲基丙烷的生产中提高产量的方法。 根据本发明的方法，通过后处理获得的含有所述醇的衍生物并且具有比各醇更高的沸点的混合物（高沸点馏分）进行酸处理，并且从所述醇中回收多元醇 酸处理的高沸点馏分。 本发明的方法的特征在于高沸点馏分的含水量在20-90wt。之间。 相对于高沸点馏分和水的整个混合物的％。
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