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公开(公告)号：US06645451B1
公开(公告)日：2003-11-11
申请号：US08876529
申请日：1997-06-16
申请人： Alf Schulz , Dirk Seffer , Matthias Rieland , Werner Rudolph
发明人： Alf Schulz , Dirk Seffer , Matthias Rieland , Werner Rudolph
IPC分类号： C01B2510
CPC分类号： C01B25/10
摘要： The preparation of phosphorus pentafluoride and arsenic pentafluoride by reacting corresponding trihalides with elemental chlorine, bromine or iodine and also with hydrogen fluoride.
摘要翻译： 通过使相应的三卤化物与元素氯，溴或碘反应，并与氟化氢反应制备五氟化磷和五氟化砷。
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公开(公告)号：US06238642B1
公开(公告)日：2001-05-29
申请号：US09437258
申请日：1999-11-10
申请人： Alf Schulz , Matthias Rieland , Eckhard Hausmann
发明人： Alf Schulz , Matthias Rieland , Eckhard Hausmann
IPC分类号： C01B1745
CPC分类号： C01B17/4576
摘要： Sulfuryl fluoride is prepared selectively and in a high yield from sulfur dioxide and elemental fluorine in the presence of an alkali fluoride and hydrogen fluoride. The preferred alkali fluoride is potassium fluoride.
摘要翻译： 在碱金属氟化物和氟化氢的存在下，从二氧化硫和元素氟选择性地以高产率制备了硫酰氟。 优选的碱金属氟化物是氟化钾。
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公开(公告)号：US6143269A
公开(公告)日：2000-11-07
申请号：US362749
申请日：1999-07-29
申请人： Alf Schulz , Matthias Rieland , Lothar Zipfel , Thomas Born , Eckhard Hausmann
发明人： Alf Schulz , Matthias Rieland , Lothar Zipfel , Thomas Born , Eckhard Hausmann
CPC分类号： C01B17/4576 , C01P2006/80
摘要： Sulfuryl fluoride (SO.sub.2 F.sub.2) frequently contains chlorine, sulfur dioxide and other acidic impurities owing to its production. Effective purification is possible if the sulfuryl fluoride is contacted with hydrogen peroxide or a precursor thereof, preferably in an aqueous solution. The purified product is suitable as a pesticidal agent, for example.
摘要翻译： 硫酰氟（SO2F2）由于其生产而经常含有氯，二氧化硫和其他酸性杂质。 如果硫酰氟与过氧化氢或其前体，优选在水溶液中接触，则有效的纯化是可能的。 纯化产物例如适合作为杀虫剂。
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公开(公告)号：US06471934B2
公开(公告)日：2002-10-29
申请号：US09780428
申请日：2001-02-12
申请人： Alf Schulz , Matthias Rieland , Eckhard Hausmann
发明人： Alf Schulz , Matthias Rieland , Eckhard Hausmann
IPC分类号： C01B1745
CPC分类号： C01B17/4592 , C01B7/03 , C01B17/501
摘要： A method of preparing sulfuryl fluoride by disproportionation of sulfuryl chloride fluoride in the gas phase on activated carbon.
摘要翻译： 一种通过在气相中将酰氯氟化物在活性炭上进行歧化来制备硫酰氟的方法。
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公开(公告)号：US5336817A
公开(公告)日：1994-08-09
申请号：US950497
申请日：1992-09-25
IPC分类号： B01J31/02 , B01J27/02 , B01J27/06 , C07B61/00 , C07C17/20 , C07C17/21 , C07C17/25 , C07C19/08 , C07C21/18 , C07C17/08
摘要： A method of preparing CH.sub.2 FCF.sub.3 from fluorodichloro-ethylene using a catalytically active niobium, tantalum or molybdenum fluorosulfonate compound or a catalyst mixture which comprises a niobium, tantalum or molybdenum halide and a sulfonic acid derivative.
摘要翻译： 使用催化活性的铌，钼或钼氟磺酸盐化合物或包含铌，钽或钼卤化物和磺酸衍生物的催化剂混合物从氟代二氯乙烯制备CH 2 FCF 3的方法。
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公开(公告)号：US5254772A
公开(公告)日：1993-10-19
申请号：US849604
申请日：1992-03-12
申请人： Wolfgang W. Dukat , John H. Holloway , Eric G. Hope , Matthias Rieland , Paul J. Townson , Richard L. Powell
发明人： Wolfgang W. Dukat , John H. Holloway , Eric G. Hope , Matthias Rieland , Paul J. Townson , Richard L. Powell
CPC分类号： C07C17/10 , C07C17/208
摘要： A process for the preparation of an alkane containing fluorine by contacting a halogenated alkane containing at least one hydrogen atom and at least one halogen atom selected from chlorine, bromine and iodine with a transition metal fluoride selected from osmium hexafluoride, iridium hexafluoride, rhenium hexafluoride, ruthenium pentafluoride, chromium pentafluoride, vanadium pentafluoride, rhenium heptafluoride and uranium hexafluoride, whereby to replace at least one hydrogen atom or at least one chlorine, bromine or iodine atom in said halogenated alkane starting material by a fluorine atom.Use of certain of the defined transition metal fluorides, e.g. OsF.sub.6, IrF.sub.6 and ReF.sub.6 allows the selective replacement of halogen by fluorine, while others, e.g. UF.sub.6, VF.sub.5 and ReF.sub.7 allow selective replacement of hydrogen by fluorine.
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公开(公告)号：US06500994B1
公开(公告)日：2002-12-31
申请号：US09786589
申请日：2001-06-08
申请人： Carsten Brosch , Heinz Gress , Matthias Rieland
发明人： Carsten Brosch , Heinz Gress , Matthias Rieland
IPC分类号： C07C1908
CPC分类号： C07C17/389 , C01B7/0718 , C01B7/197 , C07C17/38 , C07C17/395 , C07C19/08
摘要： A process for purification of 1,1,1,3,3-pentafluorobutane (HFC-365mfc) containing a decreased amount of hydrogen chloride, hydrogen fluoride and/or unsaturated impurities. To this end crude 1,1,1,3,3-pentafluorobutane is treated in the liquid phase with a solid, inorganic sorption agent and/or with diatomic molecules which and to C—C multiple bonds. The product to be purified is preferably treated with elemental fluorine. The contents of hydrogen chloride and hydrogen can each be decreased to below 1 ppm. The content of unsaturated (chlorine)-fluorine-compounds can be decreased to below 20 ppm, and the content of unsaturated C2 compounds can be decreased to below 10 ppm. It has also been discovered that fluorotrichloroethylene can be used as a control substance to monitor the purification of 1,1,1,3,3-pentafluorobutane.
摘要翻译： 一种纯化含有减少量的氯化氢，氟化氢和/或不饱和杂质的1,1,1,3,3-五氟丁烷（HFC-365mfc）的方法。 为此，粗液1,1,1,3,3-五氟丁烷在液相中用固体无机吸附剂和/或与C-C多重键的双原子分子进行处理。 待纯化的产物优选用元素氟处理。 氯化氢和氢气的含量各自可以降低到1ppm以下。 不饱和（氯） - 氟化合物的含量可以降低到20ppm以下，不饱和C2化合物的含量可以降低到10ppm以下。 还已经发现，氟三氯乙烯可以用作对照物质来监测1,1,1,3,3-五氟丁烷的纯化。
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公开(公告)号：US06723874B1
公开(公告)日：2004-04-20
申请号：US09856909
申请日：2001-05-30
IPC分类号： C07C5158
CPC分类号： C01B17/4576 , C01B17/4561 , C07C51/58
摘要： Acid fluorides, for example carboxylic acid fluorides and sulfuryl fluoride are produced by reacting the corresponding acid chlorides with hydrogen fluoride adducts of ammonium fluoride or amine hydrofluorides (which act as a catalyst or as a fluorination agent). Consumed HF adducts may be regenerated with HF.
摘要翻译： 酸性氟化物，例如羧酸氟化物和硫酰氟通过使相应的酰氯与氟化铵或胺氢氟酸（其充当催化剂或氟化剂）的氟化氢加合物反应来制备。 消耗的HF加合物可以用HF再生。
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9.发明授权Method for recovering and/or separating sulfur oxyfluorides from gas mixtures 失效从气体混合物中回收和/或分离硫氧氟化物的方法公开(公告)号：US06706090B2
公开(公告)日：2004-03-16
申请号：US10213429
申请日：2002-08-07
IPC分类号： B01D5322
CPC分类号： B01D53/04 , B01D53/22 , B01D2253/108 , B01D2253/304 , B01D2253/308 , B01D2256/26 , B01D2257/204 , B01D2257/30
摘要： A method for the recovery or separation of sulfur oxyfluorides from gas mixtures, in which the gas mixture passes through at least one adsorption stage or membrane stage containing or consisting of zeolites with a modulus >10. The sulfur oxyfluorides fixed to the adsorbent may be made available for use after desorption. The sulfur oxyfluorides enriched through the membrane can be re-used directly.
摘要翻译： 用于从气体混合物中回收或分离硫氧氟酸盐的方法，其中气体混合物通过至少一个含有或多于10个模量的沸石的吸附阶段或膜段。 固定在吸附剂上的硫氧氟化物可以在解吸后使其可用。 通过膜富集的氟氧氟化硫可以直接重新使用。
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公开(公告)号：US5236597A
公开(公告)日：1993-08-17
申请号：US986292
申请日：1992-12-07
申请人： Heinz R. Feist , Werner Legat , Hans-Walter Swidersky , Matthias Rieland , Thomas Born , Andrea Feldmann
发明人： Heinz R. Feist , Werner Legat , Hans-Walter Swidersky , Matthias Rieland , Thomas Born , Andrea Feldmann
CPC分类号： B01D15/00 , B01D17/0202 , B01D53/02 , C02F1/285
摘要： A method of using rubber, preferably from tire recycling, for absorbing organic carboxylic acids containing from 1 to 3 carbon atoms optionally substituted with from 1 to 5 halogen atoms. Trifluoroacetic acid, for example, can be absorbed very effectively.
摘要翻译： 使用橡胶，优选轮胎再循环的方法，用于吸收任选被1至5个卤素原子取代的含有1至3个碳原子的有机羧酸。 例如，三氟乙酸可以非常有效地被吸收。
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