公开(公告)号：US07371716B2

公开(公告)日：2008-05-13

申请号：US10509331

申请日：2003-04-25

申请人： Alfred Ruland ,  Martin Scholtissek ,  Juergen Tropsch ,  Roland Boehn ,  Claus Hackmann ,  Christian Wulff

发明人： Alfred Ruland ,  Martin Scholtissek ,  Juergen Tropsch ,  Roland Boehn ,  Claus Hackmann ,  Christian Wulff

IPC分类号： C11D1/722 ,  C11D1/72 ,  C11D1/825 ,  C11D3/37

CPC分类号： C11D1/825 ,  A01N25/30 ,  A61K8/39 ,  A61K8/86 ,  A61Q19/00 ,  A61Q19/10 ,  C02F1/52 ,  C02F2305/04 ,  C09D5/027 ,  C11D1/72 ,  C11D1/722 ,  D06M13/165 ,  D06M13/17 ,  D06P1/6133 ,  D06P1/65131

摘要： The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(A)n(B)mH   (I) where A is ethyleneoxy, B is C3-10-alkyleneoxy or mixtures thereof, where groups A and B may be present in random distribution, alternately or in the form of two or more blocks in any order, n is a number from 0 to 30, m is a number from 0 to 20 n+m is at least 1 where 70 to 99% by weight of alkoxylates A1 in which C5H11 has the meaning n-C5H11, and 1 to 30% by weight of alkoxylates A2 in which C5H11 has the meaning C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, are present in the mixture.

摘要翻译： 烷氧基化物混合物包括式（I）的烷氧基​​化物：在线式描述=“In-line Formulas”end =“lead”→> 5 （C 3 H 2）CH 2（O）（A）N（B）m H（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中A是乙烯氧基，B是C 3-10 - 亚烷基氧基 或其混合物，其中组A和B可以以任意顺序交替地或以两个或多个嵌段的形式以随机分布的形式存在，n为0至30的数，m为0至20 n + m的数 至少为1，其中70至99重量％的其中C 5 H 11 N的烷氧基化物A1具有含义nC 5 H 11重量％和1至30重量％的C 5 H 11的烷氧基化物A2具有C 2 H 2 H CH 3（CH 3）CH 2和/或CH 3 CH 3（CH 3）3 >）CH 2 CH 2 2存在于混合物中。

公开(公告)号：US07335235B2

公开(公告)日：2008-02-26

申请号：US10511445

申请日：2003-04-25

申请人： Alfred Ruland ,  Martin Scholtissek ,  Juergen Tropsch ,  Richard Baur

发明人： Alfred Ruland ,  Martin Scholtissek ,  Juergen Tropsch ,  Richard Baur

IPC分类号： C11D1/72 ,  C11D1/825 ,  C11D3/37 ,  D06L1/12

CPC分类号： C07C43/11 ,  C07C41/03 ,  C08G65/2663 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825 ,  C11D1/8255

摘要： An alkoxylate mixture containing; at least one alkoxylate of the formula CnH2n+1O(A)x(B)yH where A is ethyleneoxy, B is C3-C10-alkyleneoxy or mixtures thereof, n is an integer in the range from 8 to 11, x is a number in the range from 1 to 20, y is a number in the range from 0 to 10, and (ii) at least one alkoxylate of the formula CmH2m+1O(A)v(B)wH where A is ethyleneoxy, B is C3-C10-alkyleneoxy or mixtures thereof, m is an integer in the range from 12 to 24, v is a number in the range from 1 to 50, w is a number in the range from 0 to 10.

摘要翻译： 含有烷氧基化物混合物 至少一种下式的烷氧基化物C n H 2n + 1 O（A）x（B）y H，其中A是亚乙基氧基，B是C 3 -C 10 - 亚烷基氧基或其混合物，n是8至11的整数，x是 1至20的范围，y为0至10的数值，和（ii）至少一种式C m H 2 m + 1的烷氧基化物， 其中A是乙烯氧基，B是C 3 -C 10 H（A） - 亚烷氧基或其混合物，m为12-24的整数，v为1至50的数，w为0至10的数。

公开(公告)号：US08519196B2

公开(公告)日：2013-08-27

申请号：US10575760

申请日：2004-10-14

申请人： Markus Klumpe ,  Juergen Tropsch ,  Rolf-Dieter Kahl ,  Roland Boehn ,  Susanne Stutz ,  Ralf Noerenberg

发明人： Markus Klumpe ,  Juergen Tropsch ,  Rolf-Dieter Kahl ,  Roland Boehn ,  Susanne Stutz ,  Ralf Noerenberg

IPC分类号： C11D3/20

CPC分类号： C11D3/0026 ,  C07C43/11 ,  C11D1/72 ,  C11D1/722 ,  C11D1/8255

摘要： The alkoxylate mixtures comprise alkoxylates of the formula (I) C5H11CH(C3H7)CH2O(B)p(A)n(B)m(A)qH  (I) where A is ethyleneoxy, B, in each case independently, are C3-10-alkyleneoxy or mixtures thereof, groups A and B being present in the form of blocks in the stated sequence, p is a number from 0 to 10, n is a number greater than 0 to 20, m is a number greater than 0 to 20, q is a number greater than 0 to 10, p+n+m+q is at least 1, from 70 to 99% by weight of alkoxylates A1, in which C5H11 is n-C5H11, and from 1 to 30% by weight of alkoxylates A2, in which C5H11 is C2H5CH(CH3)CH2 and/or CH3CH(CH3)CH2CH2, being present in the mixture.

摘要翻译： 烷氧基化物混合物包括式（I）的烷氧基​​化物：C 5 H 11 CH（C 3 H 7）CH 2 O（B）p（A）n（B）m（A）qH（I）其中A是亚乙基氧基，B各自独立地是C3- 10-亚烷基氧基或其混合物，基团A和B以所述顺序以嵌段的形式存在，p为0至10的数，n为大于0至20的数，m为大于0至 20，q是大于0至10的数，p + n + m + q至少为1，70至99重量％的烷氧基化物A1，其中C5H11为n-C5H11，1〜30％为 其中C5H11是C2H5CH（CH3）CH2和/或CH3CH（CH3）CH2CH2）的烷氧基​​化物A2的重量存在于混合物中。

公开(公告)号：US20130197276A1

公开(公告)日：2013-08-01

申请号：US13755561

申请日：2013-01-31

申请人： Wolfgang SPIEGLER ,  Kai-Uwe Baldenius ,  Michael Triller ,  Juergen Tropsch

发明人： Wolfgang SPIEGLER ,  Kai-Uwe Baldenius ,  Michael Triller ,  Juergen Tropsch

IPC分类号： C07C43/178 ,  C07C41/03

CPC分类号： C07C43/1785 ,  A61K8/39 ,  A61K8/86 ,  A61K2800/49 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q13/00 ,  C07C41/03 ,  C07C43/11 ,  C11D1/72 ,  C11D1/722

摘要： The present invention relates to new types of farnesol alkoxylates, based on at least partially hydrogenated farnesol; processes for the preparation of these alkoxylates and the use thereof in washing, rinsing, cleaning or finishing compositions, cosmetic compositions, compositions for papermaking, fuel additives and solubilization auxiliaries in aqueous liquid systems.

摘要翻译： 本发明涉及基于至少部分氢化的法呢醇的新型法呢醇烷氧基化物; 用于制备这些烷氧基化物的方法及其在洗涤，漂洗，清洁或整理组合物中的用途，化妆品组合物，造纸用组合物，燃料添加剂和水性液体体系中的增溶助剂。

公开(公告)号：US08123867B2

公开(公告)日：2012-02-28

申请号：US12597109

申请日：2008-04-24

申请人： Juergen Tropsch

发明人： Juergen Tropsch

IPC分类号： B08B3/04 ,  C11D1/72 ,  C11D1/825 ,  C11D3/20 ,  C11D3/33 ,  C11D3/37

CPC分类号： C11D1/825 ,  C11D1/72 ,  C11D1/721 ,  C11D1/722 ,  C11D3/33 ,  C11D3/3757 ,  C11D3/378

摘要： The present invention relates to a phosphate-free machine dishwasher detergent comprising 0.01-20% by weight of at least one alcohol alkoxylate, 0.01-10% by weight of at least one alcohol ethoxylate, 0-15% by weight of at least one sulfonate-containing polymer, 0-15% by weight of at least one hydrophilically modified polycarboxylate, 0-8% by weight of at least one polycarboxylate, 1-50% by weight of at least one complexing agent and 0.1-60% by weight of at least one further additive, where the sum of components (A), (B), (C), (D), (E), (F) and (G) is 100% by weight, to a process for rinsing surfaces of articles by treating these surfaces with the composition, and to the use of the composition for increasing the rinsing performance in the machine washing of articles.

摘要翻译： 本发明涉及一种无磷酸盐洗碗机洗涤剂，其包含0.01-20重量％的至少一种醇烷氧基化物，0.01-10重量％的至少一种醇乙氧基化物，0-15重量％的至少一种磺酸盐 至少一种亲水改性的聚羧酸酯，0-8％重量的至少一种聚羧酸酯，1-50％重量的至少一种络合剂和0.1-60％重量的至少一种聚羧酸酯， 至少一种其中组分（A），（B），（C），（D），（E），（F）和（G）的总和为100重量％ 通过用组合物处理这些表面，以及使用组合物来增加制品的机洗中的漂洗性能。

公开(公告)号：US5627151A

公开(公告)日：1997-05-06

申请号：US325177

申请日：1995-04-21

申请人： Juergen Detering ,  Christian Schade ,  Wolfgang Trieselt ,  Juergen Tropsch

发明人： Juergen Detering ,  Christian Schade ,  Wolfgang Trieselt ,  Juergen Tropsch

IPC分类号： C08F2/10 ,  C08F26/00 ,  C08F26/10 ,  C08F226/06 ,  C08F226/10 ,  C08F289/00 ,  C11D3/00 ,  C11D3/37 ,  C11D3/28

CPC分类号： C11D3/3776 ,  C08F289/00 ,  C11D3/0021 ,  C11D3/3788

摘要： There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising(a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinylimidazole or mixtures thereof,(b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally(c) up to 20% by weight of other monoethylenically unsaturated monomers,as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally(b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or(c) other monoethylenically unsaturated monomers,in an aqueous medium in the presence of water-soluble proteins and a process for the preparation of the polymers by polymerising the monomers (a) and optionally (b) and/or (c) in an aqueous medium in the presence of water-soluble proteins using from 0.5 to 400 parts by weight of protein per 100 parts by weight of monomer used in the polymerization.

摘要翻译： PCT No.PCT / EP93 / 02851 Sec。 371日期1995年04月21日 102（e）日期1995年4月21日PCT 1993年10月15日PCT公布。 公开号WO94 / 10281 日本1994年5月11日描述了通过自由基引发的单体混合物共聚获得的共聚物的用途，所述共聚物包含（a）60-99重量％的1-乙烯基吡咯烷酮，1-乙烯基咪唑或其混合物，（b）1-40重量％ 重量的游离碱形式的含氮碱性烯键式不饱和单体，以盐形式或季铵化形式，和任选地（c）最多20％重量的其它单烯属不饱和单体作为洗涤剂添加剂，用作 （a）1-乙烯基吡咯烷酮，1-乙烯基咪唑，1-乙烯基咪唑鎓化合物或其混合物，和任选地（b）可通过自由基引发的聚合获得的聚合物， 在盐水介质中以盐形式或季铵化形式的其它含氮的碱性烯属不饱和单体，和/或（c）其它单烯属不饱和单体 在水溶性蛋白质存在下，通过在水溶性蛋白质的存在下在水溶性介质中聚合单体（a）和任选地（b）和/或（c））来制备聚合物的方法，使用 相对于聚合中使用的单体100重量份，为0.5〜400重量份的蛋白质。

公开(公告)号：US08434623B2

公开(公告)日：2013-05-07

申请号：US13054702

申请日：2009-07-17

申请人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

发明人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

IPC分类号： B03D3/00

CPC分类号： H01F1/44 ,  B03C1/015 ,  H01F1/0054

摘要： The present invention relates to a process for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the following steps: (A) contacting of the mixture comprising the at least one first material and at least one second material with at least one selective hydrophobicizing agent in the presence of a suspension medium so that an adduct is formed from the at least one hydrophobicizing agent and the at least one first material but not with the at least one second material, (B) contacting of the adduct from step (A) with at least one magnetic particle which is functionalized on the surface with at least one polymeric compound having a transition temperature LCST (lower critical solution temperature) at a temperature at which the polymeric compound has hydrophobic character so that the adduct from step (A) and the at least one functionalized magnetic particle agglomerate, (C) if appropriate addition of further suspension medium to the mixture obtained in step (B), (D) separation of the agglomerate present in the suspension from step (B) or (C) from the suspension by application of a magnetic field, (E) dissociation of the agglomerate separated off in step (D) by setting of a temperature at which the polymeric compound has hydrophilic character in order to obtain the at least one first material.

摘要翻译： 本发明涉及从包含该至少一种第一材料和至少一种第二材料的混合物中分离出至少一种第一材料的方法，其包括以下步骤：（A）使包含至少一种第一材料和/ 材料和至少一种第二材料与至少一种选择性疏水剂在悬浮介质的存在下进行，使得加合物由至少一种疏水剂和至少一种第一材料形成，但不与至少一种第二材料形成 ，（B）将来自步骤（A）的加合物与至少一种在表面上官能化的磁性颗粒与至少一种具有转变温度LCST（较低临界溶解温度）的聚合化合物在聚合物 具有疏水性，使得步骤（A）和至少一种官能化磁性颗粒附聚物的加合物，（C）如果适当添加 的另外的悬浮介质加入到步骤（B）中获得的混合物中，（D）通过施加磁场从悬浮液中分离存在于步骤（B）或（C）的悬浮液中的附聚物，（E） 在步骤（D）中通过设定聚合物具有亲水特性的温度来分离聚集体，以获得至少一种第一材料。

公开(公告)号：US08152931B2

公开(公告)日：2012-04-10

申请号：US12596946

申请日：2008-04-24

申请人： Juergen Tropsch

发明人： Juergen Tropsch

IPC分类号： B08B3/04 ,  C11D1/72 ,  C11D1/722 ,  C11D1/825 ,  C11D3/06 ,  C11D3/37

CPC分类号： C11D1/8255 ,  C11D1/72 ,  C11D1/721 ,  C11D1/722 ,  C11D3/06 ,  C11D3/3757 ,  C11D3/378

摘要： The present invention relates to a phosphate-containing machine dishwasher detergent comprising 0.01-20% by weight of at least one alcohol alkoxylate, 0.01-10% by weight of at least one alcohol ethoxylate, 0-15% by weight of at least one sulfonate-containing polymer, 0-15% by weight of at least one hydrophilically modified polycarboxylate, 0-8% by weight of at least one polycarboxylate, 1-70% by weight of at least one phosphate and 0.1-60% by weight of at least one further additive, where the sum of components (A), (B), (C), (D), (E), (F) and (G) is 100% by weight, to a process for rinsing surfaces of articles by treating these surfaces with the composition, and to the use of the composition for increasing the rinsing performance in the machine washing of articles.

摘要翻译： 本发明涉及含磷酸盐的机器洗碗机洗涤剂，其包含0.01-20重量％的至少一种醇烷氧基化物，0.01-10重量％的至少一种醇乙氧基化物，0-15重量％的至少一种磺酸盐 的至少一种亲水改性的聚羧酸酯，0-8％（重量）的至少一种聚羧酸酯，1-70％（重量）至少一种磷酸酯和0.1-60％（重量）的 至少一种另外的添加剂，其中组分（A），（B），（C），（D），（E），（F）和（G）的总和为100重量％ 通过用组合物处理这些表面的物品，以及使用该组合物来增加制品的机洗中的漂洗性能。

公开(公告)号：US20110120954A1

公开(公告)日：2011-05-26

申请号：US13054713

申请日：2009-07-15

申请人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

发明人： Imme Domke ,  Alexej Michailovski ,  Norbert Mronga ,  Hartmut Hibst ,  Juergen Tropsch ,  Susanne Stutz

IPC分类号： B03C1/01 ,  B01D39/00

CPC分类号： H01F1/44 ,  B03C1/015 ,  B82Y25/00 ,  H01F1/0045

摘要： The present invention relates to a process of the invention for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) Contacting of at least one magnetic particle and at least one bifunctional molecule or an adduct of the two with the mixture comprising the at least one first material and at least one second material so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first material, (B) suspension of the adduct obtained in step (A) in a suitable suspension medium, (C) separation of the adduct present in the suspension from step (B) from the suspension by application of a magnetic field, (D) if appropriate, dissociation of the adduct separated off in step (C) in order to obtain the at least one first material. a corresponding adduct and the use of such an adduct for the separation of mixtures of materials.

摘要翻译： 本发明涉及一种本发明的方法，用于从包含该至少一种第一材料和至少一种第二材料的混合物中分离至少一种第一材料，其包括以下步骤：（A）接触至少一种磁性颗粒和 至少一种双功能分子或两者的加合物与混合物包含至少一种第一材料和至少一种第二材料，使得加合物由至少一个磁性颗粒形成，通式（I）的双官能化合物 ）和所述至少一种第一材料，（B）步骤（A）中获得的加合物的悬浮液在合适的悬浮介质中，（C）通过施用将来自步骤（B）的悬浮液中存在的加合物与悬浮液 （D）如果合适，在步骤（C）中分离的加合物的解离以获得至少一种第一材料。 相应的加合物和这种加合物用于分离材料混合物的用途。

公开(公告)号：US20100160203A1

公开(公告)日：2010-06-24

申请号：US12063036

申请日：2006-08-28

申请人： Tanja Seebeck ,  Juergen Tropsch ,  Lars Kissau

发明人： Tanja Seebeck ,  Juergen Tropsch ,  Lars Kissau

IPC分类号： C11D3/37

CPC分类号： C11D3/3757 ,  C11D3/33

摘要： The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol % acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol % of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components a) to g) is 100% by weight.

摘要翻译： 本发明涉及用于机器洗碗机的无磷酸盐清洁制剂，其包含如下组分：a）1至20重量％的a1）50至93摩尔％丙烯酸和/或丙烯酸的水溶性盐的共聚物 ，a2）5〜30摩尔％的甲基丙烯酸和/或甲基丙烯酸的水溶性盐和a）2〜20摩尔％的至少一种式（I）的非离子单体，b）1〜50摩尔％ 的选自甘氨酸-N，N-二乙酸衍生物和谷氨酸-N，N-二乙酸及其盐的络合剂，c）1至15重量％的低泡非离子表面活性剂，d ）0至30重量％的漂白剂和任选的漂白活化剂，e）0至60重量％的其它助洗剂，f）0至8重量％的酶，g）0至50重量％的一种或多种进一步的 添加剂，如阴离子或两性离子表面活性剂，漂白催化剂，碱性载体，腐蚀抑制剂，消泡剂，染料，香料，填料，有机溶剂和水 组分a）至g）的总和为100重量％。