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1.发明授权
公开(公告)号：US4746762A
公开(公告)日：1988-05-24
申请号：US6407
申请日：1987-01-23
申请人： Amos A. Avidan , Tai-Sheng Chou , Hartley Owen , Jorge L. Soto , Samuel A. Tabak
发明人： Amos A. Avidan , Tai-Sheng Chou , Hartley Owen , Jorge L. Soto , Samuel A. Tabak
IPC分类号： B01J8/24 , B01J29/40 , C07C1/20 , C07C2/00 , C10G3/00 , C10G35/095 , C10G50/00 , C10G57/02 , C07C2/12
CPC分类号： C07C1/20 , B01J29/40 , C07C2/00 , C10G50/00 , B01J2208/00265 , B01J2229/42 , C07C2529/40 , C10G2300/1092 , C10G2300/4081 , C10G2400/30 , Y02P20/52 , Y02P30/20
摘要： A fluidized bed catalytic process for conversion of light olefinic gas feedstock containing ethene to produce hydrocarbons rich in C.sub.5.sup.+ liquids, comprising the steps of maintaining a fluidized bed of zeolite catalyst particles in a turbulent reactor bed at a temperature of about 315.degree. to 510.degree. C., said catalyst having an apparent particle density of about 0.9 to 1.6 g/cm.sup.3 and a size range of about 1 to 150 microns, and average catalyst particles size of about 20 to 100 microns containing about 10 to 25 weight percent of fine particles having a particle size less than 32 microns; passing hot feedstock vapor upwardly through the fluidized catalyst bed under turbulent flow conditions; maintaining turbulent fluidized bed conditions through the reactor bed between transition velocity and transport velocity at a superficial fluid velocity of about 0.3 to 2 meters per second; and recovering hydrocarbon product containing a major amount of C.sub.5.sup.+ hydrocarbons and containing C.sub.3 -C.sub.5 alkanes and alkenes in the ratio of about 0.2:1 to 5:1.
摘要翻译： 一种用于转化含有乙烯的轻质烯烃气体原料以产生富含C5 +液体的烃的流化床催化方法，包括以下步骤：将沸石催化剂颗粒的流化床在约315℃至510℃的温度下保持在湍流反应器床中 所述催化剂具有约0.9至1.6g / cm 3的表观颗粒密度和约1至150微米的尺寸范围，以及约20至100微米的平均催化剂颗粒尺寸，其含有约10至25重量％的具有 粒度小于32微米; 在湍流条件下将热原料蒸气向上通过流化催化剂床; 保持湍流流化床条件通过反应器床在过渡速度和运输速度之间以约0.3至2米/秒的表面流体速度; 并以约0.2:1至5:1的比例回收含有大量C 5+烃并含有C 3 -C 5烷烃和烯烃的烃产物。
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公开(公告)号：US4751338A
公开(公告)日：1988-06-14
申请号：US6399
申请日：1987-01-23
申请人： Samuel A. Tabak , Amos A. Avidan , Fritz A. Smith
发明人： Samuel A. Tabak , Amos A. Avidan , Fritz A. Smith
CPC分类号： C07C15/00 , C07C2/00 , C07C2529/40 , Y02P20/584
摘要： A technique for continuous conversion of diene-containing aliphatic hydrocarbon feedstock to heavier hydrocarbon products wherein the feedstock is contacted at elevated temperature under endothermic high severity reaction conditions with a fluidized bed of acidic zeolite fine catalyst particles, comprising methods and means for:maintaining the fluidized catalyst bed in a vertical reactor having a turbulent reaction zone by passing vapor upwardly through the reaction zone at a velocity greater than dense bed transition velocity to a turbulent regime and less than transport velocity for the average catalyst particle;feeding a continuous stream of feedstock into the reaction zone, said feedstream comprising sufficient C.sub.3.sup.+ alkanes to require net endothermic reaction conditions;withdrawing a portion of coked catalyst from the reaction zone, oxidatively regenerating the withdrawn catalyst, heating the catalyst substantially above process temperature in the fluidized bed reactor, and returning hot regenerated catalyst to the reaction zone at a rate to control catalyst activity and reaction temperature under conditions of reaction severity to effect feedstock conversion to an aromatics-rich hydrocarbon effluent stream; andseparating an aromatics-rich product from the fluidized bed effluent stream.Aromatics yield is increased by recovering a recycle stream comprising C.sub.5.sup.+ aliphatic hydrocarbons from the fluidized bed effluent stream for further conversion in the fluidized bed to increase aromatics product yield.
摘要翻译： 一种用于将含二烯烃的脂族烃原料连续转化为较重烃产物的技术，其中原料在吸热高度苛刻度的反应条件下在升高的温度下与酸性沸石细催化剂颗粒的流化床接触，包括以下步骤： 催化剂床在具有湍流反应区的立式反应器中，通过使蒸气向上通过反应区，速度大于致密床转变速度至湍流状态且小于平均催化剂颗粒的输送速度; 将连续的原料流送入反应区，所述进料流包含足够的C3 +烷烃以需要净吸热反应条件; 将一部分焦化催化剂从反应区中取出，氧化再生催化剂，在流化床反应器中将催化剂加热至高于工艺温度，并将热再生催化剂返回到反应区，以控制催化剂活性和反应温度 使原料转化成富含芳烃的烃流出物流的反应条件; 以及从流化床流出物流中分离富含芳烃的产物。 通过从流化床流出物流中回收包含C5 +脂族烃的再循环料流以在流化床中进一步转化以提高芳族化合物产物产率来提高芳族化合物产率。
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公开(公告)号：US4855521A
公开(公告)日：1989-08-08
申请号：US186526
申请日：1988-04-27
申请人： Amos A. Avidan , Fritz A. Smith , Samuel A. Tabak
发明人： Amos A. Avidan , Fritz A. Smith , Samuel A. Tabak
IPC分类号： C07C2/00
CPC分类号： C07C2/00 , C07C2529/40
摘要： An improved fluidized bed process for upgrading olefinic hydrocarbon feedstock by contacting the feedstock with acidic siliceous zeolite conversion catalyst particles at elevated temperature under exothermic conditions to produce heavier hydrocarbons including gasoline range hydrocarbons. The improvement comprises maintaining a turbulent fluidized bed of catalyst particles by flowing hydrocarbon-containing vapor upwardly through said bed at less than transport velocity; and introducing liquid olefinic feedstock comprising at least one C.sub.4 -C.sub.6 diene component into the fluidized catalyst bed in a lower portion thereof by rapidly atomizing and vaporizing the liquid feedstock, thus converting feedstock to heavier hydrocarbon without substantial thermal diene degradation thereof prior to contacting conversion catalyst particles in the fluidized bed. A predominantly liquid product is recovered containing C.sub.4 -C.sub.9 hydrocarbons rich in olefins and aromatics.
摘要翻译： 改进的流化床方法，用于通过使原料与酸性硅沸石转化催化剂颗粒在升高的温度下在放热条件下接触以产生包含汽油范围烃的较重的烃来提纯烯烃原料。 改进包括通过以低于运输速度将含烃蒸汽向上流动穿过所述床来维持催化剂颗粒的湍流流化床; 并且通过使液体原料快速雾化并使其加热，将包含至少一种C 4 -C 6二烯组分的液体烯烃原料引入到其下部的流化催化剂床中，从而将原料转化为较重的烃，而在转化催化剂 流化床中的颗粒。 回收含有富含烯烃和芳族化合物的C4-C9烃的主要液体产物。
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公开(公告)号：US4778661A
公开(公告)日：1988-10-18
申请号：US6408
申请日：1987-01-23
申请人： Amos A. Avidan , Fritz A. Smith , Samuel A. Tabak
发明人： Amos A. Avidan , Fritz A. Smith , Samuel A. Tabak
CPC分类号： C07C2/00 , C07C2529/40
摘要： An improved fluidized bed process for upgrading olefinic hydrocarbon feedstock by contacting the feedstock with acidic siliceous zeolite conversion catalyst particles at elevated temperature under exothermic conditions to produce heavier hydrocarbons including gasoline range hydrocarbons. The improvement comprises maintaining a turbulent fluidized bed of catalyst particles by flowing hydrocarbon-containing vapor upwardly through said bed at less than transport velocity; and introducing liquid olefinic feedstock comprising at least one C.sub.4 -C.sub.6 diene component into the fluidized catalyst bed in a lower portion thereof by rapidly atomizing and vaporizing the liquid feedstock, thus converting feedstock to heavier hydrocarbon without substantial thermal diene degradation thereof prior to contacting conversion catalyst particles in the fluidized bed. Reaction severity conditions may be maintained by controlling catalyst acidity, reaction temperature and reactant contact time to produce reaction efluent containing propane and propene in the ratio of about 0.2:1 to 200:1. A predominantly liquid product is recovered containing C.sub.4 -C.sub.9 hydrocarbons rich in olefins and aromatics.
摘要翻译： 改进的流化床方法，用于通过使原料与酸性硅沸石转化催化剂颗粒在升高的温度下在放热条件下接触以产生包含汽油范围烃的较重烃来提纯烯烃原料。 改进包括通过以低于运输速度将含烃蒸汽向上流动穿过所述床来维持催化剂颗粒的湍流流化床; 并通过快速雾化和蒸发液体原料将包含至少一种C 4 -C 6二烯组分的液体烯烃原料引入到其下部的流化催化剂床中，从而在接触转化催化剂之前将原料转化成较重的烃，而不会发生相当的热二烯降解 流化床中的颗粒。 可以通过控制催化剂酸度，反应温度和反应物接触时间来维持反应强度条件，以产生约0.2:1至200:1的丙烷和丙烯的反应液。 回收含有富含烯烃和芳族化合物的C4-C9烃的主要液体产物。
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公开(公告)号：US4746761A
公开(公告)日：1988-05-24
申请号：US65775
申请日：1987-07-02
CPC分类号： C07C41/06 , C07C1/20 , C07C9/16 , C10G29/205 , C10G3/49 , C10L1/023 , C07C2529/40 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10G2400/22 , Y02P20/52 , Y02P30/20 , Y02P30/42
摘要： A multistage process for producing isoalkyl ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in contact with zeolite catalyst to predominantly C.sub.2 -C.sub.7 lower olefins comprising isobutylene and isoamylene, by-product water and a minor amount of C.sub.8.sup.+ hydrocarbons, followed by fractionation of the C.sub.2 -C.sub.7 olefins to recover a C.sub.2 -C.sub.3 -rich recycle stream for further catalytic conversion in the primary stage. C.sub.4 -C.sub.7 olefins are passed to a second catalytic etherification stage for reaction of isoalkenes with methanol to produce methyl tertiary-butyl ether, methyl isoamylether and higher isoalkyl ethers. The second stage effluent may be fractionated to recover an ether product, C.sub.5.sup.+ hydrocarbon liquid product, and unreacted butenes. Advantageously, the unreacted butenes are further reacted with isoparaffin in a third catalytic stage under acid catalysis alkylation conditions, and fractionated to recover C.sub.6.sup.+ alkylate liquid, liquid hydrocarbon product. The ethers may be blended with at least one C.sub.6.sup.+ hydrocarbon to produce high octane gasoline.
摘要翻译： 用于从低级脂族含氧化合物原料如甲醇生产异烷基醚的多阶段方法。 原料在初级催化剂阶段在升高的温度下与沸石催化剂催化转化成主要是包含异丁烯和异戊烯，副产物水和少量C 8+烃的C 2 -C 7低级烯烃，然后分馏C2-C7烯烃 以回收在初级阶段进一步催化转化的富含C2-3的再循环物流。 将C4-C7烯烃通入第二催化醚化阶段，以使异烯烃与甲醇反应，生成甲基叔丁基醚，甲基异戊醚和高级异烷基醚。 第二级流出物可以分馏以回收醚产物，C5 +烃液体产物和未反应的丁烯。 有利地，在酸催化烷基化条件下，在第三催化阶段中，未反应的丁烯进一步与异链烷烃反应，并分馏以回收C6 +烷基化液体液体烃产物。 醚可以与至少一种C6 +烃混合以产生高辛烷值汽油。
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6.发明授权Process for converting methanol to alkyl ethers, gasoline, distillate and alkylate liquid hydrocarbons 失效将甲醇转化为烷基醚，汽油，馏出物和烷基化液体烃的方法
公开(公告)号：US4684757A
公开(公告)日：1987-08-04
申请号：US886996
申请日：1986-07-18
摘要： A multistage process for producing ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in contact with zeolite catalyst to predominantly C.sub.2 -C.sub.5 lower olefins comprising isobutylene and isoamylene, by-product water and a minor amount of C.sub.6.sup.+ hydrocarbons, followed by fractionation of the C.sub.2 -C.sub.5 olefins to recover a C.sub.2 -C.sub.3 -rich recycle stream for further catalytic conversion in the primary stage. C.sub.4 -C.sub.5 olefins are passed to a second catalytic etherification stage for reaction of isoalkenes with methanol to produce methyl tertiary-butyl ether and methyl isoamylether. The second stage effluent may be fractionated to recover an ether product, C.sub.5.sup.+ hydrocarbon liquid product, and unreacted butenes. Advantageously, the unreacted butenes are further reacted wtih isoparaffin in a third catalytic stage under acid catalysis alkylation conditions, and fractionated to recover C.sub.6.sup.+ alkylate liquid, liquid hydrocarbon product. The ethers may be blended with at least one C.sub.6.sup.+ hydrocarbon to produce high octane gasoline.
摘要翻译： 用于从低级脂肪族含氧化合物原料如甲醇生产醚的多阶段方法。 原料在初级催化剂阶段在升高的温度下与沸石催化剂催化转化成主要是包含异丁烯和异戊烯，副产物水和少量C 6 +烃的C 2 -C 5低级烯烃，然后分馏C2-C5烯烃 以回收在初级阶段进一步催化转化的富含C2-3的再循环物流。 将C4-C5烯烃通入第二催化醚化阶段，以使异烯烃与甲醇反应生成甲基叔丁基醚和甲基异戊醚。 第二级流出物可以分馏以回收醚产物，C5 +烃液体产物和未反应的丁烯。 有利地，未反应的丁烯在酸性催化烷基化条件下在第三催化阶段进一步与异链烷烃反应，并分馏以回收C6 +烷基化物液体液体烃产物。 醚可以与至少一种C6 +烃混合以产生高辛烷值汽油。
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公开(公告)号：US4956518A
公开(公告)日：1990-09-11
申请号：US377993
申请日：1989-07-11
申请人： Jonathan E. Child , Tai-Sheng Chou , Albin Huss, Jr. , Clinton R. Kennedy , Francis P. Ragonese , Samuel A. Tabak
发明人： Jonathan E. Child , Tai-Sheng Chou , Albin Huss, Jr. , Clinton R. Kennedy , Francis P. Ragonese , Samuel A. Tabak
IPC分类号： B01D3/00 , B01J20060101 , B01J27/08 , B01J27/12 , B60P1/00 , C07C2/60 , C07C9/14 , C07C9/22 , C10G20060101
CPC分类号： C10G29/205 , B01J27/08 , B01J27/12 , C07C2/60 , B01J21/08 , C07C2521/04 , C07C2521/08 , C07C2527/10 , C07C2527/1213 , C07C2527/126 , C07C2527/133
摘要： An improved continuous process for alkylation of isoparaffins with olefins to yield a product which includes a large proportion of highly branced paraffins for making gasoline having improved octane is taught. The improved process comprises contacting isoparaffins and olefins with a composite catalyst comprising a Lewis acid and a non-zeolitic inorganic oxide in the presence of a controlled amount of water. The process results in reduced catalyst aging and obviates environmental problems associated with prior art processes.
摘要翻译： 教导了改进的用烯烃烷基化异链烷烃的连续方法，以产生包含大量高度分支的链烷烃的产物，用于制备具有改进的辛烷值的汽油。 改进的方法包括在受控量的水的存在下使异链烷烃和烯烃与包含路易斯酸和非沸石无机氧化物的复合催化剂接触。 该方法导致催化剂老化减少并且消除与现有技术方法相关的环境问题。
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8.发明授权
公开(公告)号：US4849186A
公开(公告)日：1989-07-18
申请号：US935374
申请日：1986-11-26
CPC分类号： C07C2/12 , C10G29/16 , C07C2529/40 , F02B3/06 , Y10S203/06
摘要： An oligomerization system is provided for upgrading lower olefins to distillate hydrocarbons, especially useful as high quality jet or diesel fuels. Thye olefinic feedstock is reacted over a shape selective acid zeolite, such as ZSM-5, to oligomerize feedstock olefins and further convert recycled hydrocarbons. Reactor effluent is fractionated to recover a light-middle distillate range product stream and to obtain gasoline and heavy hydrocarbon streams for recycle.
摘要翻译： 提供了一种低聚体系，用于将低级烯烃升级成馏分烃，特别适用于高质量的喷气或柴油燃料。 烯烃原料在形状选择性酸性沸石（如ZSM-5）上反应，使原料烯烃低聚并进一步转化回收的烃。 将反应器流出物分馏以回收轻 - 中馏分范围的产物流并获得用于再循环的汽油和重烃流。
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公开(公告)号：US4634798A
公开(公告)日：1987-01-06
申请号：US779369
申请日：1985-09-23
申请人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
发明人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
CPC分类号： C07C2/62 , C07C1/20 , C10G3/49 , C10L1/06 , C07C2527/1206 , C07C2529/06 , C07C2529/40 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/20 , Y02P30/42
摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins.The improved technique comprises fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3 + components; reacting C.sub.3 + olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.4 + isoparaffin for recycle to the sorption zone as lean sorbent; and recovering C.sub.7 + alkylate product from the process.
摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用C 3 -C 4烯烃烷基化。 改进的技术包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应生成C7 +烷基化烃; 分馏烷基化反应器流出物以提供富含C 4 +异链烷烃的液体烃馏分，作为贫吸附剂再循环至吸附区; 并从该过程中回收C7 +烷基化产物。
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公开(公告)号：US4633028A
公开(公告)日：1986-12-30
申请号：US779367
申请日：1985-09-23
申请人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
发明人： Hartley Owen , Samuel A. Tabak , Bernard S. Wright
CPC分类号： C10L1/06 , C07C9/16 , C10G3/49 , C07C2527/1206 , C07C2529/06 , C07C2529/40 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/20
摘要： Alkylate is produced by catalytically converting oxygenate feedstock, such as methanol, to lower olefins comprising C.sub.2 -C.sub.4 olefins. Ethene is separated by interstage sorption of C.sub.3 + components and an isoparaffin is alkylated with C.sub.3 -C.sub.4 olefins derived from sorbate.The improved technique comprises fractionating an olefinic feedstream containing ethene and C.sub.3 + olefinic components by contacting the olefinic feedstream in a sorption zone with a liquid hydrocarbon sorbent to selectively sorb C.sub.3 + components; reacting C.sub.3 + olefins with excess isoparaffin in a catalytic alkylation reactor to produce C.sub.7 + alkylate hydrocarbons; fractionating the alkylation reactor effluent to provide a liquid hydrocarbon fraction rich in C.sub.7 +, alkylate for recycle to the sorption zone as lean sorbent; and recovering C.sub.7 + alkylate product and C.sub.5 + gasoline from the process.
摘要翻译： 烷基化物通过将含氧化合物原料如甲醇催化转化成包含C 2 -C 4烯烃的低级烯烃来制备。 乙烯通过C3 +组分的级间吸附分离，异链烷烃用来自山梨酸酯的C3-C4烯烃烷基化。 改进的技术包括通过使吸附区中的烯烃进料流与液体烃吸附剂接触以选择性吸附C3 +组分来分馏含有乙烯和C3 +烯烃组分的烯烃进料流; 在催化烷基化反应器中使C3 +烯烃与过量的异链烷烃反应生成C7 +烷基化烃; 分馏烷基化反应器流出物以提供富含C 7+的烷烃馏分，作为贫吸附剂再循环到吸附区; 并从该过程中回收C7 +烷基化物产物和C5 +汽油。
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