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公开(公告)号：US07368482B2
公开(公告)日：2008-05-06
申请号：US10571538
申请日：2004-09-09
Applicant: Luca Basini , Andrea Bartolini , Giancarlo Lupi , Gabriele Carlo Ettore Clerici
Inventor： Luca Basini , Andrea Bartolini , Giancarlo Lupi , Gabriele Carlo Ettore Clerici
CPC classification number: B01J37/0217 , B01J8/025 , B01J8/0278 , B01J19/0013 , B01J19/26 , B01J23/892 , B01J23/8946 , B01J27/24 , B01J37/0221 , C01B3/386 , C01B2203/0261 , C01B2203/1064 , C01B2203/1082 , C01B2203/1211 , C01B2203/1241 , C01B2203/1247 , Y02P20/52
Abstract: Partial oxidation process of liquid fuels, selected from hydrocarbon and/or oxygenated compounds, together with gaseous fuels, selected from hydrocarbon compounds, natural gas and LPG, by means of a suitable catalytic system comprising the following steps: premixing the reagents and possibly heating them to temperatures ranging from 25 to 400° C., said reagents consisting of said liquid fuels, said gaseous fuels and oxygen or air or oxygen enriched air, optionally in the presence of vapor and/or CO2; reacting the mixture of reagents in the catalytic zone, at inlet temperatures ranging from 50 to 500° C. and space velocities ranging from 1,000 to 1,000,000 Nl reagents/L cat×h, reaching temperatures ranging from 450 to 1350° C.
Abstract translation: 选自烃和/或含氧化合物的液体燃料与选自烃化合物，天然气和液化石油气的气态燃料通过合适的催化体系进行部分氧化处理，包括以下步骤：预混合试剂并可能加热它们 所述试剂由所述液体燃料，所述气体燃料和氧气或空气或富氧空气组成，任选地在蒸气和/或CO 2存在下。 使催化剂区域的混合物在入口温度范围为50至500℃，空速为1,000至1,000,000Nl试剂/ L catxh之间，达到450至1350℃的温度。
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公开(公告)号：US20070278328A1
公开(公告)日：2007-12-06
申请号：US11574773
申请日：2005-09-26
Applicant: Andrea Bartolini , Luca Basini , Giancarlo Lupi
Inventor： Andrea Bartolini , Luca Basini , Giancarlo Lupi
CPC classification number: B01J19/26 , B01B1/005 , B01J4/002 , B01J8/008 , B01J8/0264 , B01J8/0278 , B01J19/248 , B01J27/24 , B05B7/0458 , B05B7/08 , B05B7/0861 , C01B3/382 , C01B3/386 , C01B2203/0244 , C01B2203/0261 , C01B2203/0844 , C01B2203/1064 , C01B2203/1247 , C01B2203/1276 , C01B2203/142 , C01B2203/82 , Y02P20/52
Abstract: Equipment for the atomisation of a liquid stream by means of a dispersing gaseous stream and for mixing the atomised product with a further suitable gaseous stream, characterized in that it comprises: a feeding zone (A) equipped with means suitable for feeding the liquid stream, the gaseous dispersing stream and further gaseous stream; one or more two-stage atomisation zones (N) of the liquid stream by means of the gaseous dispersing stream; a distribution zone (D) of the further gaseous stream; the first stage of the atomisation zone (N1) essentially consisting of a tubular core (2), through which the liquid stream passes, equipped with an appropriate series of nozzles (5), situated at the same height, and an outer jacket (4) coaxial to said core, through which the gaseous dispersing stream passes, wherein said nozzles (5) allow the gaseous dispersing stream to enter the tubular core, perpendicularly to the axis of said tubular core (2), effecting a first atomisation of the liquid stream, the second stage of the atomisation zone (N2) essentially consisting of one or more nozzles (6) positioned at the end of the tubular core (2), parallel to the axis of said tubular core, to increase the atomisation degree, the distribution zone (D) essentially consisting of a further jacket (8), through which the further gaseous stream passes, external and coaxial to the jacket (4) of the first atomisation stage, and a series of nozzles (9) situated at the bottom of said further jacket, all positioned at the same height and parallel or inclined with an alpha angle lower than 40° with respect to the axis of the tubular core.
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3.发明授权Equipment for the atomisation of a liquid stream by means of a dispersing gaseous stream and for mixing the atomised product with a further suitable gaseous stream in equipment for effecting catalytic partial oxidations and relative catalytic partial oxidation process 有权用于通过分散气流雾化液体流并将雾化产物与设备中的另外合适的气流混合以进行催化部分氧化和相对催化部分氧化过程的设备公开(公告)号：US08088186B2
公开(公告)日：2012-01-03
申请号：US11574773
申请日：2005-09-26
Applicant: Andrea Bartolini , Luca Basini , Giancarlo Lupi
Inventor： Andrea Bartolini , Luca Basini , Giancarlo Lupi
CPC classification number: B01J19/26 , B01B1/005 , B01J4/002 , B01J8/008 , B01J8/0264 , B01J8/0278 , B01J19/248 , B01J27/24 , B05B7/0458 , B05B7/08 , B05B7/0861 , C01B3/382 , C01B3/386 , C01B2203/0244 , C01B2203/0261 , C01B2203/0844 , C01B2203/1064 , C01B2203/1247 , C01B2203/1276 , C01B2203/142 , C01B2203/82 , Y02P20/52
Abstract: Equipment for the atomization of a liquid stream by means of a dispersing gaseous stream and for mixing the atomised product with a further suitable gaseous stream, characterized in that it comprises: a feeding zone (A) equipped with means suitable for feeding the liquid stream, the gaseous dispersing stream and further gaseous stream; one or more two-stage atomization zones (N) of the liquid stream by means of the gaseous dispersing stream; a distribution zone (D) of the further gaseous stream.
Abstract translation: 用于通过分散气流雾化液体流并用于将雾化产物与另外合适的气流混合的设备，其特征在于其包括：装有适于供给液体流的装置的进料区（A） 气态分散流和另外的气流; 液态物流的一个或多个两级雾化区（N），通过气态分散物流; 进一步的气流的分配区（D）。
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公开(公告)号：US20070105962A1
公开(公告)日：2007-05-10
申请号：US10571538
申请日：2004-09-09
Applicant: Luca Basini , Andrea Bartolini , Giancarlo Lupi , Gabriele Clerici
Inventor： Luca Basini , Andrea Bartolini , Giancarlo Lupi , Gabriele Clerici
IPC: C07C27/06
CPC classification number: B01J37/0217 , B01J8/025 , B01J8/0278 , B01J19/0013 , B01J19/26 , B01J23/892 , B01J23/8946 , B01J27/24 , B01J37/0221 , C01B3/386 , C01B2203/0261 , C01B2203/1064 , C01B2203/1082 , C01B2203/1211 , C01B2203/1241 , C01B2203/1247 , Y02P20/52
Abstract: Partial oxidation process of liquid fuels, selected from hydrocarbon and/or oxygenated compounds, together with gaseous fuels, selected from hydrocarbon compounds, natural gas and LPG, by means of a suitable catalytic system comprising the following steps: premixing the reagents and possibly heating them to temperatures ranging from 25 to 400° C., said reagents consisting of said liquid fuels, said gaseous fuels and oxygen or air or oxygen enriched air, optionally in the presence of vapour and/or CO2; reacting the mixture of reagents in the catalytic zone, at inlet temperatures ranging from 50 to 500° C. and space velocities ranging from 1,000 to 1,000,000 Nl reagents/L cat×h, reaching temperatures ranging from 450 to 1350° C.
Abstract translation: 选自烃和/或含氧化合物的液体燃料与选自烃化合物，天然气和液化石油气的气态燃料通过合适的催化体系进行部分氧化处理，包括以下步骤：预混合试剂并可能加热它们 所述试剂由所述液体燃料，所述气体燃料和氧气或空气或富氧空气组成，任选地在蒸气和/或CO 2存在下。 使催化剂区域的混合物在入口温度范围为50至500℃，空速为1,000至1,000,000Nl试剂/ L catxh之间，达到450至1350℃的温度。
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公开(公告)号：US07815700B2
公开(公告)日：2010-10-19
申请号：US12090363
申请日：2006-10-18
Applicant: Andrea Bartolini , Luca Basini , Alessandra Guarinoni , Antonio Bennardo , Nicola Onorati
Inventor： Andrea Bartolini , Luca Basini , Alessandra Guarinoni , Antonio Bennardo , Nicola Onorati
CPC classification number: B01F5/0453 , B01F5/0456 , B01J8/009 , B01J8/0278 , B01J2208/00849 , B01J2219/00265 , C01B3/386 , C01B2203/0261 , C01B2203/1276 , Y02P20/52 , Y10T137/87652
Abstract: A device, system and method of mixing two fluids are described herein. A gaseous first fluid is distributed through a distribution zone to a mixing zone by a bundle of pipes parallel to an axis inside which the first fluid is uniformly distributed. A second fluid is uniformly distributed outside the pipes in the distribution zone. The mixing zone is separated from the distribution zone by a pipe-plate supporting the pipes. The pipe-plate has slits or openings to uniformly discharge the second fluid in an axial flow direction into the mixing zone. The pipes extend beyond the pipe-plate into the mixing zone to partialize an outlet flow of the first fluid. In one aspect, the pipes have different lengths to partialize the outlet flow. In another aspect, a terminal portion of the pipes partializes the outlet flow axially, radially, transversally or a combination thereof in the mixing zone.
Abstract translation: 本文描述了混合两种流体的装置，系统和方法。 气态第一流体通过平行于第一流体均匀分布的轴线的一束管道分布到分配区域到混合区域。 第二流体均匀地分布在分配区域中的管道外部。 通过支撑管道的管板将混合区与分配区分离。 管板具有狭缝或开口，以使第二流体在轴向流动方向上均匀地排放到混合区域中。 管道延伸超过管板进入混合区域以局部化第一流体的出口流。 在一个方面，管道具有不同的长度以使出口流动部分化。 在另一方面，管道的末端部分将出口流轴向，径向，横向或其混合部分在混合区中。
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Patent Agency Ranking
公开(公告)号：US20080244974A1
公开(公告)日：2008-10-09
申请号：US12090363
申请日：2006-10-18
Applicant: Andrea Bartolini , Luca Basini , Alessandra Guarinoni , Antonio Bennardo , Nicola Onorati
Inventor： Andrea Bartolini , Luca Basini , Alessandra Guarinoni , Antonio Bennardo , Nicola Onorati
IPC: C10L3/08
CPC classification number: B01F5/0453 , B01F5/0456 , B01J8/009 , B01J8/0278 , B01J2208/00849 , B01J2219/00265 , C01B3/386 , C01B2203/0261 , C01B2203/1276 , Y02P20/52 , Y10T137/87652
Abstract: A device is described for mixing two fluids, inserted in or combined with a reactor, which can also be used for catalytic partial oxidation, substantially consisting of the following zones:—a first feeding zone equipped with means for allowing a first fluid, possibly gaseous under the operating conditions, to enter in an axial direction;—an underlying distribution zone containing a bundle of pipes preferably parallel to the axis inside which said fluid is uniformly distributed;—a second feeding zone equipped with means for allowing a second fluid to enter the distribution zone containing the bundle of preferably parallel pipes and to be uniformly distributed outside said parallel pipes;—a mixing zone separated from the distribution zone by a pipe-plate supporting said parallel pipes, said pipe-plate having slits or openings in order to uniformly discharge the second fluid in an axial direction into the mixing area, and said parallel pipes extending beyond said pipe-plate into the mixing zone.
Abstract translation: 描述了一种装置，用于混合两个流体，其插入反应器中或与反应器组合，该反应器也可用于催化部分氧化，基本上由以下区域组成： - 第一进料区，其配备有用于允许第一流体 在操作条件下进入轴向方向; - 底部分配区域，其包含优选平行于所述流体均匀分布的轴线的管束; - 第二进料区域，其配备有允许第二流体进入的装置 所述分配区包含优选平行的管并且均匀地分布在所述平行管的外侧; - 通过支撑所述平行管的管板从分配区分离的混合区，所述管板具有狭缝或开口，以便 将第二流体沿轴向均匀地排放到混合区域中，并且所述平行管延伸超过所述管板进入混合物 g区。
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公开(公告)号：US07704412B2
公开(公告)日：2010-04-27
申请号：US10514843
申请日：2003-05-21
Applicant: Luca Basini , Alessandra Guarinoni
Inventor： Luca Basini , Alessandra Guarinoni
CPC classification number: B01J23/464 , B01J23/40 , B01J23/44 , B01J23/462 , B01J23/468 , B01J23/70 , B01J27/24 , B01J35/08 , B01J37/0203 , B01J37/0209 , C01B3/386 , C01B3/40 , C01B2203/0244 , C01B2203/0261 , C01B2203/0844 , C01B2203/1011 , C01B2203/1041 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1211 , C01B2203/1276 , C01B2203/143 , C01B2203/1604 , C01B2203/82 , Y02P20/52
Abstract: Partial oxidation process of liquid and/or gaseous fuels, by means of a catalytic system, preferably consisting of oxides, nitrides or oxynitrides containing one or more elements selected from Rh, Ru, Ir, Pt, Ni, Fe, Co, Cr and Cu, comprising the following steps: —premixing and, upon start-up, preheating the reagents consisting of natural gas, oxygen or air or air enriched in oxygen, optionally vapour and/or CO2, to temperatures ranging from 150 to 600° C., below the flash-point values, so that the surface rate of the reaction gases is maintained above the flame rate and the temperature of the reagent mixture in the area preceding the catalytic bed is below its flash point; —reacting the reagent mixture in the reaction zone by interaction of the catalyst, activating it at temperatures ranging from 150 to 600° C. and at space velocities ranging from 50,000 to 5,000,000 Nl reagents/L cat×h, reaching temperatures ranging from 600 to 1350° C.
Abstract translation: 通过催化体系，优选由含有一种或多种选自Rh，Ru，Ir，Pt，Ni，Fe，Co，Cr和Cu中的一种或多种元素的氧化物，氮化物或氮氧化物组成的液体和/或气体燃料的部分氧化过程 包括以下步骤： - 在启动时，将由天然气，氧气或空气或富氧氧气（任选蒸气和/或CO 2）组成的试剂预热至150至600℃的温度， 低于闪点值，使得反应气体的表面速率保持高于火焰速率，并且催化床前面的区域中的试剂混合物的温度低于其闪点; 通过催化剂的相互作用使反应区中的试剂混合物反应，在150至600℃的温度和50,000至5,000,000Nl试剂/ L cat×h的空速下活化反应区，达到600至 1350°C
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公开(公告)号：US20080139862A1
公开(公告)日：2008-06-12
申请号：US12033572
申请日：2008-02-19
Applicant: Luca Basini , Domenico Sanfilippo , Alessandra Guarinoni
Inventor： Luca Basini , Domenico Sanfilippo , Alessandra Guarinoni
CPC classification number: C07C5/48 , B01J23/62 , B01J23/626 , B01J23/8926 , B01J27/24 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2523/644 , C07C2523/652 , C07C2523/89 , C07C2527/24 , Y02P20/52 , C07C11/04 , C07C11/02
Abstract: Catalytic system for partial oxidation reactions of hydrocarbons characterized in that it contains: one or more metals belonging to the 1st, 2nd, and 3rd transition series; one or more elements of group IIIA, IVA or VA, wherein at least one of said metals or said elements is in the form of a nitride.
Abstract translation: 用于烃的部分氧化反应的催化体系，其特征在于其包含：属于第一，第二和/或第三级的一种或多种金属 >过渡系列 IIIA，IVA或VA族的一种或多种元素，其中所述金属或所述元素中的至少一种为氮化物形式。
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公开(公告)号：US20070123744A1
公开(公告)日：2007-05-31
申请号：US11561092
申请日：2006-11-17
Applicant: Luca Basini , Domenico Sanfilippo , Alessandra Guarinoni
Inventor： Luca Basini , Domenico Sanfilippo , Alessandra Guarinoni
CPC classification number: C07C5/48 , B01J23/62 , B01J23/626 , B01J23/8926 , B01J27/24 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C2523/644 , C07C2523/652 , C07C2523/89 , C07C2527/24 , Y02P20/52 , C07C11/04 , C07C11/02
Abstract: Catalytic system for partial oxidation reactions of hydro-carbons characterized in that it contains: one or more metals belonging to the 1st, 2nd, and 3rd transition series; one or more elements of group IIIA, IVA or VA, wherein at least one of said metals or said elements is in the form of a nitride.
Abstract translation: 用于部分氧化反应的碳氢化合物的催化体系，其特征在于它含有：属于第一个，第二个和第三个的一种或多种金属， / SUP>过渡系列; IIIA，IVA或VA族的一种或多种元素，其中所述金属或所述元素中的至少一种为氮化物形式。
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10.发明授权Catalytic system and process for producing synthesis gas by reforming light hydrocarbons with CO.sub.2 失效催化体系和通过用CO 2 + B重整轻烃生产合成气的方法
公开(公告)号：US5336655A
公开(公告)日：1994-08-09
申请号：US892480
申请日：1992-06-02
Applicant: Luca Basini , Mario Marchionna , Stephano Rossini , Domenico Sanfilippo
Inventor： Luca Basini , Mario Marchionna , Stephano Rossini , Domenico Sanfilippo
CPC classification number: B01J23/63 , B01J23/40 , C01B3/40 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , Y02P20/52
Abstract: A catalytic system for the production of synthesis gas by reacting light hydrocarbons, preferably methane, with CO.sub.2 is described formed from:one or more compounds of metals of the platinum group, preferably chosen from rhodium, ruthenium and iridium;a support consisting of inorganic compounds chosen from oxides and/or spinels of aluminium, magnesium, zirconium, silicon, cerium and/or lanthanum, possibly in the presence of alkali metals,in which the weight percentage of the metal or metals of the platinum group in the catalytic system is between 0.01 and 20%, and preferably between 0.1 and 5%.
Abstract translation: 通过使轻烃（优选甲烷）与CO 2反应来生产合成气的催化体系描述为：铂族金属的一种或多种化合物，优选选自铑，钌和铱; 由选自铝，镁，锆，硅，铈和/或镧的氧化物和/或尖晶石的无机化合物组成的载体，可能在碱金属的存在下，铂族金属或金属的重量百分比 在催化体系中为0.01〜20％，优选为0.1〜5％。
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