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    Highly Scratch-Resistant and Highly Elastic Coating Agents Based on Alkoxysilane Functional Components
    1.
    发明申请
    Highly Scratch-Resistant and Highly Elastic Coating Agents Based on Alkoxysilane Functional Components 失效
    基于烷氧基硅烷功能组分的高耐刮擦和高弹性涂料

    公开(公告)号：US20080047469A1

    公开(公告)日：2008-02-28

    申请号：US11575979

    申请日：2005-09-03

    申请人： Andreas Poppe ,  Gunter Klein ,  Andre Brosseit ,  Karin Wermelt ,  Martina Mollers

    发明人： Andreas Poppe ,  Gunter Klein ,  Andre Brosseit ,  Karin Wermelt ,  Martina Mollers

    IPC分类号： C08G18/62

    CPC分类号： C08G18/284 ,  C08G18/631 ,  C08G18/706 ,  C08L2666/02 ,  C09D175/06 ,  C09J133/04 ,  Y10T428/31663

    摘要： A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR″x(OR″)3-x   (I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m   (II) (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.

    摘要翻译： 一种热固性涂料，其包含（A）至少50重量％，基于组合物（A1）和（A1）的总成分（A1）中（A1）的涂料中的非挥发性物质的量为0重量％至50重量％ A2），含有基于共聚物（A1）中共聚单体总共的50重量％以上的含有至少一个式I的反应性基团的可自由基聚合的烯属不饱和化合物（a1）的聚甲基丙烯酸酯共聚物 <？in-line-formula description =“In-line Formulas”end =“lead”？> X-SiR“x”（OR“）3-x C（O）-N-（X-SiR“x”（OR'）3-x N）（X'-SiR' ' y m（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>（ B）用于交联-Si（OR'）3-x 单元的催化剂，和（C）非质子溶剂或非质子传递溶剂的混合物。

    High scratch-resistance and high elasticity coating materials based on alkoxysilane functional components
    2.
    发明授权
    High scratch-resistance and high elasticity coating materials based on alkoxysilane functional components 失效
    基于烷氧基硅烷功能组分的高抗刮性和高弹性涂料

    公开(公告)号：US07772320B2

    公开(公告)日：2010-08-10

    申请号：US11575979

    申请日：2005-09-03

    申请人： Andreas Poppe ,  Guenter Klein ,  Andre Brosseit ,  Karin Wermelt ,  Martina Mollers

    发明人： Andreas Poppe ,  Guenter Klein ,  Andre Brosseit ,  Karin Wermelt ,  Martina Mollers

    IPC分类号： C08L83/00

    CPC分类号： C08G18/284 ,  C08G18/631 ,  C08G18/706 ,  C08L2666/02 ,  C09D175/06 ,  C09J133/04 ,  Y10T428/31663

    摘要： A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR″x(OR′)3-x  (I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m  (II) (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.

    摘要翻译： 一种热固性涂料，其包含（A）至少50重量％，基于组合物（A1）和（A1）的总成分（A1）中（A1）的涂料中的非挥发性物质的量为0重量％至50重量％ A2），含有基于共聚物（A1）中共聚单体总共的50重量％以上的含有至少一个式I的反应性基团的可自由基聚合的烯属不饱和化合物（a1）的聚甲基丙烯酸酯共聚物 -X-SiR“x（OR'）3-x（I）和（A2）以组分（A1）和（A2）为基础的50％至100％重量的多异氰酸酯和烷氧基硅烷 ，（A2）含有至少一个式II的反应性基团：-NR-C（O）-N-（X-SiR“x（OR'）3-x）n（X'-SiR”y ）3-y）m（II）（B）用于交联-Si（OR'）3-x单元的催化剂，和（C）非质子溶剂或非质子溶剂的混合物。

    Coating Agents Containing Adducts Having an Alkoxysilane Functionality
    3.
    发明申请
    Coating Agents Containing Adducts Having an Alkoxysilane Functionality 审中-公开
    含有具有烷氧基硅烷功能的加合物的涂层剂

    公开(公告)号：US20080220173A1

    公开(公告)日：2008-09-11

    申请号：US11575766

    申请日：2005-09-03

    申请人： Andreas Poppe ,  Elke Westhoff ,  Wilfried Stuebbe ,  Manuela Niemeier ,  Dunja Mikolajetz ,  Simone Hesener ,  Andre Brosseit ,  Karin Wermelt ,  Guenter Klein ,  Martina Moellers

    发明人： Andreas Poppe ,  Elke Westhoff ,  Wilfried Stuebbe ,  Manuela Niemeier ,  Dunja Mikolajetz ,  Simone Hesener ,  Andre Brosseit ,  Karin Wermelt ,  Guenter Klein ,  Martina Moellers

    IPC分类号： C09D175/04 ,  C08G18/80 ,  B05D1/36

    CPC分类号： C08G18/792 ,  C08G18/222 ,  C08G18/809 ,  C09D175/00

    摘要： The invention relates to a coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material, of at least one compound (A1) containing at least one reactive group of the formula(I) —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m   (I) where R=hydrogen, alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, with Ra=alkyl, cycloalkyl, aryl or aralkyl, R′=hydrogen, alkyl or cycloalkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, X, X′=linear and/or branched alkylene or cycloalkylene radical of 2 to 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, (B) a catalyst for the crosslinking of the —Si(OR′)3-X(y) units, and (C) an aprotic solvent or a mixture of aprotic solvents.

    摘要翻译： 本发明涉及一种涂料，其包含（A）至少一种含至少一种式（I）的反应性基团的化合物（A1）至少50重量％，基于涂料中不挥发物质的量， - NR-C（O）-N-（X-SiR“'X'（OR'） （X'-SiR“'Y'（OR'）3-y）m（I）＆lt; 3-x） line-formula description =“In-line Formulas”end =“tail”？>其中R =氢，烷基，环烷基，芳基或芳烷基，碳链不间断或不相邻的氧，硫或NRa基团中断，其中Ra = 烷基，芳基或芳烷基，R'=氢，烷基或环烷基，碳链不间断或不相邻的氧，硫或NR a基团，X，X'=线性和/或支链亚烷基或亚环烷基， 20个碳原子，R“=烷基，环烷基，芳基或芳烷基，碳链不间断或不相邻的氧，硫 或NR a基团，n = 0〜2，m = 0〜2，m + n = 2，x，y = 0〜2，（B）-Si（OR' 3-X（y）单元，和（C）非质子溶剂或非质子溶剂的混合物。

    COATING COMPOSITIONS COMPRISING ADDUCTS WITH SILANE FUNCTIONALITY, AND HIGH SCRATCH RESISTANCE COATINGS WITH IMPROVED CRACK RESISTANCE PRODUCED FROM THEM
    6.
    发明申请
    COATING COMPOSITIONS COMPRISING ADDUCTS WITH SILANE FUNCTIONALITY, AND HIGH SCRATCH RESISTANCE COATINGS WITH IMPROVED CRACK RESISTANCE PRODUCED FROM THEM 有权
    包含硅烷功能助剂的涂料组合物和具有改进的抗裂纹性的高耐蚀涂层

    公开(公告)号：US20100062168A1

    公开(公告)日：2010-03-11

    申请号：US12531342

    申请日：2008-01-22

    申请人： Andreas Poppe ,  Egon Wegner ,  Gunter Klein

    发明人： Andreas Poppe ,  Egon Wegner ,  Gunter Klein

    IPC分类号： B05D3/02 ,  C08L83/06

    CPC分类号： C09D5/29 ,  C08G18/289 ,  C08G18/61 ,  C08G18/6254 ,  C08G18/792 ,  C08G18/809 ,  C08L75/12 ,  C09D143/04 ,  C09D175/04 ,  C08L2666/20 ,  C08L2666/16

    摘要： Disclosed are coating compositions comprising film-forming material with at least one reactive functional group G″′, catalyst for the crosslinking of the silane groups, aprotic solvents, and at least one adduct with silane functionality which is prepared by an addition reaction of (a) at least one silane (S1) which has at least one functional group G′ which is reactive with the complementary functional groups G″ of the compound (O), and (b) at least one compound (O) which has at least one complementary functional group G″ and at least one surface-active radical. Also disclosed are multicoat paint systems in which the transparent coating has been produced from these coating compositions, methods of making and use, as well as methods of improving the hardness and/or the scratch resistance of coatings.

    摘要翻译： 公开了包含具有至少一个反应性官能团G“'的成膜材料，用于硅烷基团交联的催化剂，非质子溶剂和至少一种与硅烷官能团的加合物的涂料组合物，其通过（a ）至少一种具有至少一个与化合物（O）的互补官能团G“反应的官能团G'的硅烷（S1），和（b）至少一种具有至少一个 互补官能团G“和至少一个表面活性基团。 还公开了多层涂料体系，其中由这些涂料组合物制备透明涂料，制备和使用方法，以及提高涂层硬度和/或耐划伤性的方法。

    COATING COMPOSITIONS WITH HIGH SCRATCH RESISTANCE AND WEATHERING STABILITY
    10.
    发明申请
    COATING COMPOSITIONS WITH HIGH SCRATCH RESISTANCE AND WEATHERING STABILITY 审中-公开
    具有高耐蚀性和耐候性的涂料组合物

    公开(公告)号：US20100015344A1

    公开(公告)日：2010-01-21

    申请号：US12519466

    申请日：2007-12-19

    申请人： Matthijs Groenewolt ,  Andreas Poppe ,  Gunter Klein ,  Manuela Niemeier ,  Elke Westhoff ,  Wilfried Stubbe ,  Simone Hesener

    发明人： Matthijs Groenewolt ,  Andreas Poppe ,  Gunter Klein ,  Manuela Niemeier ,  Elke Westhoff ,  Wilfried Stubbe ,  Simone Hesener

    IPC分类号： B05D1/36 ,  C09D175/00

    CPC分类号： C09D175/14 ,  C08G18/289 ,  C08G18/6254 ,  C08G18/778 ,  C08G18/809 ,  C09D175/04

    摘要： Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having free and/or blocked isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, where (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (iii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network. The finally cured coating obtained from the coating composition has a post-crosslinking index (PCI) of less than 2, wherein (PCI) is defined as the ratio of the storage modulus E′(200) at 200° C. to the minimum of the storage modulus E′(min) at a temperature above the measured glass transition temperature Tg.

    摘要翻译： 公开了包含（a）至少一种含羟基的化合物（A），（b）至少一种具有游离和/或封闭的异氰酸酯基团的化合物（B）的涂料组合物，和（c）至少一种用于 硅烷基团的交联，其中（i）涂料组合物中的一种或多种组分含有可水解的硅烷基团，和（iii）涂料组合物可最终固化成具有统计分布的Si-O-Si网络区域的涂层。 从涂料组合物得到的最终固化涂层具有小于2的后交联指数（PCI），其中（PCI）定义为200℃下的储能模量E'（200）与最低 在高于测量的玻璃化转变温度Tg的温度下的储能模量E'（min）。