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9 条记录 (耗时 0.019 秒)

    Process for the preparation of homogentisic lactone
    1.
    发明授权
    Process for the preparation of homogentisic lactone 失效
    制备同基内酯的方法

    公开(公告)号：US4182720A

    公开(公告)日：1980-01-08

    申请号：US926323

    申请日：1978-07-20

    申请人： Andrew H. M. Renfrew ,  Stephen B. Bostock

    发明人： Andrew H. M. Renfrew ,  Stephen B. Bostock

    IPC分类号： C07D307/83 ,  C07D307/84

    CPC分类号： C07D307/84 ,  C07D307/83

    摘要： Process for the preparation of homogentisic lactone by reacting hydroquinone with a di(lower alkyl) chloro (or bromo) malonate and an alkali metal lower alkoxide to give an alkali metal 3-carbo(loweralkoxy)-5-hydroxy-2-oxidobenzo[b]furan which is subsequently decarboxylated by treatment with a strong mineral acid to give homogentisic lactone. The latter is readily converted into homogentisic acid by conventional means.

    摘要翻译： 通过使氢醌与二（低级烷基）氯（或溴）丙二酸酯和碱金属低级醇盐反应得到碱金属3-碳（低级烷氧基）-5-羟基-2-氧化苯并[b ]呋喃，其随后通过用强无机酸处理脱羧，得到同基内酯。 后者通过常规方法容易地转化成同基酸。

    Anthraquinone compounds
    3.
    发明授权
    Anthraquinone compounds 失效
    蒽醌化合物

    公开(公告)号：US4391754A

    公开(公告)日：1983-07-05

    申请号：US363223

    申请日：1982-03-29

    申请人： Andrew H. M. Renfrew

    发明人： Andrew H. M. Renfrew

    IPC分类号： C09B1/02 ,  C09B1/503 ,  C09B1/515 ,  C09K19/60 ,  C07C97/26 ,  C07C49/74

    CPC分类号： C09K19/603 ,  C09B1/02 ,  C09B1/503 ,  C09B1/515

    摘要： Compounds of the formula: ##STR1## wherein R.sup.1 is alkyl or aryl;X is H, NH.sub.2 or NHCH.sub.3 ;one of Y and Z is OH and the other is H, NH.sub.2 or NHCH.sub.3 ; andone of R.sup.2 and R.sup.3 is H and the one that is ortho to the OH group is a --CH.sub.2 R.sup.1 radical.The compounds include pleochroic dyes useful in liquid crystal display systems.

    摘要翻译： 下式的化合物：其中R1是烷基或芳基; X是H，NH 2或NHCH 3; Y和Z之一是OH，另一个是H，NH2或NHCH3; R2和R3中的一个是H，OH基的邻位是-CH2R1基。 该化合物包括可用于液晶显示系统的多色染料。

    Reactive dyes having a bulky linker group
    5.
    发明授权
    Reactive dyes having a bulky linker group 失效
    具有大体积连接基团的活性染料

    公开(公告)号：US5306813A

    公开(公告)日：1994-04-26

    申请号：US8084

    申请日：1993-01-22

    申请人： Andrew H. M. Renfrew ,  John A. Taylor

    发明人： Andrew H. M. Renfrew ,  John A. Taylor

    IPC分类号： C07D401/14 ,  C07C211/51 ,  C07C229/54 ,  C07C309/46 ,  C09B62/04 ,  C09B62/085 ,  D06P1/382

    CPC分类号： C07C309/46 ,  C07C211/51 ,  C07C229/54 ,  C09B62/043

    摘要： A compound which, in the free acid form, is of Formula (1): ##STR1## wherein: D is optionally substituted phenyl or optionally substituted naphthyl;K is optionally substituted phenylene or optionally substituted naphthylene;R.sup.1 and R.sup.4 are each independently H or optionally substituted alkyl;R.sup.2 and R.sup.3 are each independently H or optionally substituted alkyl, provided at least one of R.sup.2 and R.sup.3 is optionally substituted alkyl;B is H, optionally substituted alkyl or optionally substituted each A is H or a substituent; andeachA is H or a substituent; andL is an optionally substituted divalent organic radical. The compound is useful as a reactive dye for textiles.

    摘要翻译： 游离酸形式为式（1）的化合物：其中：D为任选取代的苯基或任选取代的萘基; K是任选取代的亚苯基或任选取代的亚萘基; R 1和R 4各自独立地为H或任选取代的烷基; R2和R3各自独立地为H或任选取代的烷基，其中R 2和R 3中的至少一个为任选取代的烷基; B是H，任选取代的烷基或任选取代，每个A是H或取代基; 并且每个A是H或取代基; L是任选取代的二价有机基团。 该化合物可用作纺织品的活性染料。

    Triphenodioxazine reactive dyes having sulphonate ester groups
    6.
    发明授权
    Triphenodioxazine reactive dyes having sulphonate ester groups 失效
    具有磺酸酯基的三苯并二恶嗪活性染料

    公开(公告)号：US5171852A

    公开(公告)日：1992-12-15

    申请号：US517442

    申请日：1990-04-25

    申请人： Andrew H. M. Renfrew ,  Denis R. A. Ridyard ,  Brian Lamble

    发明人： Andrew H. M. Renfrew ,  Denis R. A. Ridyard ,  Brian Lamble

    IPC分类号： C09B62/002

    CPC分类号： C09B62/0025

    摘要： Triphenodioxazine reactive dyes, useful for dyeing cellulosic fibers, of the formula: ##STR1## wherein each of T.sup.1 and T.sup.2, independently, represents H, Cl, Br, F, SO.sub.3 H or an optionally substituted alkyl or aryl radical;R.sup.1 represents H or an optionally substituted hydrocarbon or heterocyclic radical;R.sup.2 represents an optionally substituted hydrocarbon radical;A represents C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, Cl, COOH or SO.sub.3 H, andn has a value of 0 or 1,the nature of the substituents being such that the dyes contain at least two SO.sub.3 H groups and at least two fibre-reactive groups.

    摘要翻译： 用于染色纤维素纤维的三苯并二恶嗪活性染料，具有下式：其中T1和T2各自独立地表示H，Cl，Br，F，SO3H或任选取代的烷基或芳基; R1表示H或任选取代的烃或杂环基; R2表示任选取代的烃基; A表示C 1-4 - 烷基，C 1-4 - 烷氧基，Cl，COOH或SO 3 H，并且n具有0或1的值，取代基的性质使得染料含有至少两个SO 3 H基团和至少两个 纤维反应性基团。

    Triphenodioxazine acid dyes
    7.
    发明授权
    Triphenodioxazine acid dyes 失效
    三苯并二恶嗪酸染料

    公开(公告)号：US4542213A

    公开(公告)日：1985-09-17

    申请号：US590057

    申请日：1984-03-15

    申请人： Robert D. McClelland ,  Andrew H. M. Renfrew

    发明人： Robert D. McClelland ,  Andrew H. M. Renfrew

    IPC分类号： C09B19/02 ,  C07D498/04

    CPC分类号： C09B19/02

    摘要： Triphenodioxazine dyes which, in the free acid form, have the formula: ##STR1## wherein A is Cl or Br; Y is cyclopentylene, cyclohexylene or (CH.sub.2).sub.x where x is 2, 3 or 4; andZ is NRCO.sub.2 R.sup.1 or ##STR2## wherein R is H, optionally substituted alkyl or optionally substituted aryl;R.sup.1 is optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl; andR.sup.2 is --CH.dbd.CH--,--CH.dbd.CH--CH.sub.2 --,--(CH.sub.2)--.sub.2-4 or a 1,2-radical of a 5 or 6 membered carbocyclic compound;or, when Y is cyclopentylene or cyclohexylene, Z may also be H or alkyl, alkoxy, aryl, aryloxy, cycloalkyl, cycloalkoxy or amino, all of which may be optionally substituted.

    摘要翻译： 游离酸形式的三苯并二恶嗪染料具有下式：其中A为Cl或Br; Y是亚环戊基，亚环己基或（CH 2）x，其中x是2,3或4; Z为NRCO2R1或其中R为H，任意取代的烷基或任选取代的芳基; R1是任选取代的烷基，任选取代的环烷基或任选取代的芳基; 并且R 2是-CH = CH - ， - CH = CH-CH 2 - ， - （CH 2）-2-4或5或6元碳环化合物的1,2-基; 或者当Y是亚环戊基或亚环己基时，Z也可以是H或烷基，烷氧基，芳基，芳氧基，环烷基，环烷氧基或氨基，所有这些都可以被任意取代。

    Cationic triphendioxazine dyes, methods for their manufacture and their use for dyeing cellulosic substrates
    8.
    发明授权
    Cationic triphendioxazine dyes, methods for their manufacture and their use for dyeing cellulosic substrates 失效
    阳离子三苯并二恶嗪染料，其制造方法及其用于染色纤维素基质的用途

    公开(公告)号：US4512773A

    公开(公告)日：1985-04-23

    申请号：US493262

    申请日：1983-05-10

    申请人： Kenneth Anderton ,  Nigel Hall ,  Brian Parton ,  Andrew H. M. Renfrew ,  Malcolm G. Shaw

    发明人： Kenneth Anderton ,  Nigel Hall ,  Brian Parton ,  Andrew H. M. Renfrew ,  Malcolm G. Shaw

    IPC分类号： C09B19/02 ,  D06P3/58

    CPC分类号： C09B19/02 ,  Y10S8/918 ,  Y10S8/919

    摘要： A dyestuff of formula: ##STR1## wherein: the groups X.sub.1 and X.sub.2 are independently hydrogen, halogen, alkyl, aryl, alkoxy, cyano, optionally substituted amino or carboxylic acid ester groups; (R).sub.n represents n substituents R each of which is independently halogen, lower alkyl, lower alkoxy or --COOH and n is 0 or 1; R.sub.1 is hydrogen, or optionally substituted lower alkyl; Y is an optionally substituted aliphatic or optionally substituted araliphatic group; R.sub.2 is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl; R.sub.3 is hydrogen or an optionally substituted alkyl or aralkyl group; A.sup.- is an anion; a is 0 or 1; and Z is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl.The dyes are useful for the coloration of materials such as textiles, leather, inks and lacquers.

    摘要翻译： 一种下式的染料：其中：基团X 1和X 2独立地是氢，卤素，烷基，芳基，烷氧基，氰基，任选取代的氨基或羧酸酯基团; （R）n表示n个取代基R，其各自独立地为卤素，低级烷基，低级烷氧基或-COOH，n为0或1; R1是氢或任选取代的低级烷基; Y是任选取代的脂族或任选取代的芳脂族基; R 2是氢，任选取代的低级烷基，任选取代的芳基或任选取代的芳烷基; R3是氢或任选取代的烷基或芳烷基; A-是阴离子; a是0或1; 且Z为氢，任选取代的低级烷基，任选取代的芳基或任选取代的芳烷基。 染料可用于纺织品，皮革，油墨和油漆等材料着色。

    Triphendioxazine dyestuffs
    9.
    发明授权
    Triphendioxazine dyestuffs 失效
    三苯并二恶嗪染料

    公开(公告)号：US4472575A

    公开(公告)日：1984-09-18

    申请号：US452806

    申请日：1982-12-23

    申请人： Andrew H. M. Renfrew

    发明人： Andrew H. M. Renfrew

    IPC分类号： C09B19/02 ,  C07D498/04

    CPC分类号： C09B19/02

    摘要： A dyestuff of the formula: ##STR1## wherein: the groups X.sub.1 and X.sub.2 are independently hydrogen, halogen, alkyl, alkoxy or aryl;(R).sub.n represents n substituents R each of which is independently halogen, lower alkyl, lower alkoxy or COOH and n is 0 or 1;a+b is 0 to 4;A is O, S or NR.sub.2 wherein R.sub.2 is H or optionally substituted lower alkyl;B is an optionally substituted aliphatic or optionally substituted araliphatic group;R.sub.1 is hydrogen, optionally substituted lower alkyl, optionally substituted aryl or optionally substituted aralkyl; andZ is an aromatic nitrogen ring heterocycle devoid of cellulose-reactive groups.The dyestuffs are valuable for the coloration of cellulose especially in the form of paper. The resulting colored cellulose is a bright blue with good fastness properties.

    摘要翻译： 一种下式的染料：其中：基团X 1和X 2独立地是氢，卤素，烷基，烷氧基或芳基; （R）n表示各自独立地为卤素，低级烷基，低级烷氧基或COOH的n个取代基R，n为0或1; a + b为0〜4; A为O，S或NR 2，其中R 2为H或任选取代的低级烷基; B是任选取代的脂族或任选取代的芳脂族基团; R 1是氢，任选取代的低级烷基，任选取代的芳基或任选取代的芳烷基; Z是没有纤维素反应性基团的芳香族氮杂环。 该染料对于纤维素的着色特别是以纸的形式是有价值的。 所得的有色纤维素是亮蓝色，具有良好的牢度性能。