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    Fluoropolymer-based conductive composition
    1.
    发明授权
    Fluoropolymer-based conductive composition 失效
    基于含氟聚合物的导电组合物

    公开(公告)号：US06762245B2

    公开(公告)日：2004-07-13

    申请号：US09998932

    申请日：2001-12-03

    申请人： Anthony Bonnet ,  Francois Court ,  Ludwik Leibler

    发明人： Anthony Bonnet ,  Francois Court ,  Ludwik Leibler

    IPC分类号： C08L5300

    CPC分类号： C08L27/16 ,  C08L53/02 ,  Y10S977/753 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L2666/24

    摘要： The present invention relates to a conductive composition comprising (i) a fluoropolymer, (ii) an electrically conductive product and (iii) a triblock copolymer ABC, the three blocks A, B and C being linked together in this order, each block being either a homopolymer or a copolymer obtained from two or more monomers, block A being linked to block B and block B to block C by means of a covalent bond or an intermediate molecule linked to one of these blocks via a covalent bond and to the other block via another covalent bond, and such that: block A is compatible with the fluoropolymer, block B is incompatible with the fluoropolymer and is incompatible with block A, block C is incompatible with the fluoropolymer, block A and block B. The invention also relates to the components manufactured with the above composition. These components may be plates, films, tubes, rods, centrifugal pump components and containers.

    摘要翻译： 本发明涉及导电组合物，其包含（i）含氟聚合物，（ii）导电产物和（iii）三嵌段共聚物ABC，三个嵌段A，B和C依次连接在一起，每个嵌段是 由两种或更多种单体获得的均聚物或共聚物，嵌段A通过共价键连接至嵌段B和嵌段B以通过共价键或与其中一个嵌段相连的中间分子与另一嵌段 并且使得：块A与含氟聚合物相容，嵌段B与含氟聚合物不相容并且与嵌段A不相容，嵌段C与氟聚合物，嵌段A和嵌段B不相容。本发明还涉及 用上述成分制造的部件。 这些部件可以是板，膜，管，杆，离心泵部件和容器。

    Thermoset materials with improved impact resistance
    3.
    发明授权
    Thermoset materials with improved impact resistance 有权
    具有改善耐冲击性的热固性材料

    公开(公告)号：US06894113B2

    公开(公告)日：2005-05-17

    申请号：US10296714

    申请日：2001-05-17

    申请人： Francois Court ,  Ludwik Leibler ,  Jean-Pierre Pascault ,  Sophie Ritzenthaler

    发明人： Francois Court ,  Ludwik Leibler ,  Jean-Pierre Pascault ,  Sophie Ritzenthaler

    IPC分类号： C08L101/00 ,  C08L53/00 ,  C08L63/00

    CPC分类号： C08L53/00 ,  C08L63/00 ,  C08L2666/14 ,  C08L2666/04 ,  C08L2666/02

    摘要： The present invention relates to a thermoset material with improved impact resistance comprising: 99 to 20% of a thermoset resin, and 1 to 80% of an impact modifier comprising at least one copolymer comprising S-B-M, B-M and M-B-M blocks, wherein: each block is connected to the other by means of a covalent bond or of an intermediate molecule connected to one of the blocks via a covalent bond and to the other block via another covalent bond, M is a PMMA homopolymer or a copolymer comprising at least 50% by weight of methyl methacrylate, B is incompatible with the thermoset resin and with the M block and its glass transition temperature Tg is less than the operating temperature of the thermoset material, and S is incompatible with the thermoset resin, the B block and the M block and its Tg or its melting temperature is greater than the Tg of B. S is advantageously polystyrene and B polybutadiene. The thermoset resin advantageously originates from the reaction of a thermosetting epoxy resin and of a hardener.

    摘要翻译： 本发明涉及具有改善的抗冲击性的热固性材料，其包含：99-20％的热固性树脂和1至80％的抗冲改性剂，其包含至少一种包含SBM，BM和MBM嵌段的共聚物，其中：每个嵌段是 通过共价键或通过共价键连接到其中一个嵌段的中间分子连接另一个，另一个通过另一个共价键连接到另一个嵌段，M是PMMA均聚物或包含至少50重量％ 的甲基丙烯酸甲酯，B与热固性树脂和M嵌段不相容，并且其玻璃化转变温度Tg小于热固性材料的操作温度，并且S与热固性树脂，B嵌段和M嵌段不相容，以及 其Tg或其熔融温度大于B的Tg。有利地，S是聚苯乙烯和B聚丁二烯。 热固性树脂有利地来源于热固性环氧树脂和硬化剂的反应。

    Compositions based on semicrystalline thermoplastic resins and block copolymers, resulting materials and methods for obtaining same
    4.
    发明授权
    Compositions based on semicrystalline thermoplastic resins and block copolymers, resulting materials and methods for obtaining same 失效
    基于半结晶热塑性树脂和嵌段共聚物的组合物，得到的材料和获得其的方法

    公开(公告)号：US07144952B1

    公开(公告)日：2006-12-05

    申请号：US09555672

    申请日：1998-12-07

    申请人： Francois Court ,  Ludwik Leibler ,  Ahmed Mourran ,  Christophe Navarro ,  Vincent Royackkers

    发明人： Francois Court ,  Ludwik Leibler ,  Ahmed Mourran ,  Christophe Navarro ,  Vincent Royackkers

    IPC分类号： C08L53/02

    CPC分类号： C08L27/06 ,  C08F297/02 ,  C08L27/24 ,  C08L53/02 ,  C08L2666/24

    摘要： These compositions based on semi-crystalline thermoplastic resin and on ABC block copolymers result in materials or in items which exhibit an impact strength, an elongation at break, a resistance to cracking and to deformation under stress, and a thermal behavior which are improved with respect to semi-crystalline resin or resins alone or mixed with conventional impact additives, while retaining a high modulus and thus a degree of stiffness. They are generally suitable for the preparation of items or articles, such as sheets, films, pipe sheathings, tubings, pipes, yarns, strands, cable sheathings, bracing wires, leaktight sheathings, sleeve tubes, both mono- and multilayer, shaped components, molded panels, thermoformed articles, sections, bottles or powders for coating substrates. The materials or items obtained from these compositions exhibit a characteristic morphology visible in electron microscopy.

    摘要翻译： 这些基于半结晶热塑性树脂和ABC嵌段共聚物的组合物产生材料或物品，其表现出冲击强度，断裂伸长率，耐开裂性和在应力下的变形以及相对于 单独使用半结晶树脂或树脂或与常规冲击添加剂混合，同时保持高模量并因此保持刚度。 它们通常适用于物品或制品的制备，例如片材，薄膜，管道护套，管道，管道，纱线，股线，电缆护套，支撑线，密封护套，套筒管，单层和多层形状构件， 模制板，热成型制品，截面，瓶或用于涂覆基材的粉末。 从这些组合物获得的材料或物品表现出在电子显微镜中可见的特征形态。

    HOT-FORMABLE AND RECYCLABLE EPOXY ANHYDRIDE THERMOSETTING RESINS AND THERMOSETTING COMPOSITES
    9.
    发明申请
    HOT-FORMABLE AND RECYCLABLE EPOXY ANHYDRIDE THERMOSETTING RESINS AND THERMOSETTING COMPOSITES 有权
    热塑性环氧树脂和可回热的环氧树脂热固性树脂和热固性复合材料

    公开(公告)号：US20130300020A1

    公开(公告)日：2013-11-14

    申请号：US13981401

    申请日：2012-01-23

    申请人： Ludwik Leibler ,  Francois Tournilhac ,  Damien Montarnal ,  Mathieu Capelot

    发明人： Ludwik Leibler ,  Francois Tournilhac ,  Damien Montarnal ,  Mathieu Capelot

    IPC分类号： C08G59/68

    CPC分类号： C08G59/685 ,  B29B17/0042 ,  B29B17/0404 ,  B29K2101/10 ,  C08G59/42 ,  C08L63/00 ,  C08L63/04 ,  Y02W30/62 ,  Y02W30/625

    摘要： Thermosetting resins and thermosetting composites comprising the thermosetting resins are hot-formable. The compositions result from contacting at least one thermosetting resin precursor with at least one hardener selected from acid anhydrides in the presence of at least one transesterification catalyst. The thermosetting resin precursor includes hydroxyl functions and/or epoxy groups, and optionally ester functions, and the total molar quantity of the transesterification catalyst is between 5 and 25% of the total molar quantity of hydroxyl and epoxy contained in the thermosetting resin precursor. Methods for manufacturing articles comprising the thermosetting resins and methods for recycling the thermosetting resins are also disclosed.

    摘要翻译： 包含热固性树脂的热固性树脂和热固性复合材料是可热成型的。 组合物是由至少一种热固性树脂前体与至少一种选自酸酐的硬化剂在至少一种酯交换催化剂存在下接触而得到的。 热固性树脂前体包括羟基官能团和/或环氧基团以及任选的酯官能团，并且酯交换催化剂的总摩尔量在热固性树脂前体中所含的羟基和环氧化物的总摩尔量的5至25％之间。 还公开了制造包含热固性树脂的制品的方法和再循环热固性树脂的方法。

    THERMOREVERSIBLY CROSS-LINKED GRAFT POLYMERS
    10.
    发明申请
    THERMOREVERSIBLY CROSS-LINKED GRAFT POLYMERS 审中-公开
    热熔交联聚合物

    公开(公告)号：US20130237646A1

    公开(公告)日：2013-09-12

    申请号：US13884831

    申请日：2011-11-08

    申请人： Sylvia Harders ,  Ludwik Leibler ,  Ilias Iliopoulos ,  Julie Prevost

    发明人： Sylvia Harders ,  Ludwik Leibler ,  Ilias Iliopoulos ,  Julie Prevost

    IPC分类号： C08F36/06 ,  C08L95/00 ,  C08F8/34

    CPC分类号： C08F36/06 ,  C08C19/20 ,  C08C19/22 ,  C08C19/30 ,  C08F8/34 ,  C08L9/00 ,  C08L53/025 ,  C08L95/00 ,  E01C7/18 ,  C08L51/08

    摘要： A graft polymer PG includes a polymer backbone P and at least one side graft G linked to the polymer backbone, the graft G having the general formula (1): in which R1 and R2 represent, separately from one another, straight or branched, unsaturated or saturated hydrocarbon groups, such that the total number of carbon atoms in groups R1 and R2 is between 2 and 110; X represents an amide, amino-acid, urea or urethane function, the graft G being linked to the polymer backbone P via the sulphur atom. The graft polymer PG is a polymer that allows thermoreversible cross-linking and can be used in many fields such as coatings, paints, thermoplastics, adhesives, lubricants, fuels, inks, cements, construction materials, rubbers and bitumens. The graft polymer PG can be used in particular for thermoreversibly cross-linking bitumen/polymer compositions and thus for reducing coating, spreading and/or compaction temperatures during the production of bituminous coated materials.

    摘要翻译： 接枝聚合物PG包括聚合物骨架P和连接到聚合物主链的至少一个侧接枝G，具有通式（1）的接枝G：其中R 1和R 2彼此分别表示直链或支链不饱和的 或饱和烃基，使得基团R1和R2中的碳原子总数在2和110之间; X表示酰胺，氨基酸，脲或氨基甲酸酯官能团，接枝G通过硫原子与聚合物骨架P连接。 接枝聚合物PG是允许热可逆交联并可用于许多领域的聚合物，例如涂料，油漆，热塑性塑料，粘合剂，润滑剂，燃料，油墨，水泥，建筑材料，橡胶和沥青。 接枝聚合物PG特别可用于热可逆地交联沥青/聚合物组合物，因此用于在生产沥青涂层材料期间减少涂层，铺展和/或压实温度。