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公开(公告)号:US20160152536A1
公开(公告)日:2016-06-02
申请号:US14903627
申请日:2014-07-08
Applicant: ARKEMA INC.
Inventor: Maher Y. ELSHEIKH , John A. WISMER , Sri R. SESHADRI
IPC: C07C17/38
CPC classification number: C07C17/38 , B01D53/226 , B01D53/228 , B01D53/229 , B01D53/68 , B01D53/70 , B01D2053/224 , B01D2251/306 , B01D2251/604 , B01D2256/26 , B01D2257/102 , B01D2257/104 , B01D2257/2025 , B01D2257/2045 , B01D2257/2047 , B01D2257/2064 , B01D2257/2066 , B01D2257/404 , B01D2257/502 , B01D2257/504 , B01D2257/80 , Y02C10/10 , Y02P20/152 , Y02P20/154 , C07C21/18 , C07C19/08
Abstract: A method of separating a composition containing at least one organofluorine compound from at least one inorganic compound by contacts the composition with a semipermeable membrane. Other methods separate a organofluorine compound from a composition containing at least one other organofluorine compound or chlorocarbon. Methods also include isolating a single organofluorine compound from a composition comprising a mixture of organofluorine compounds, chlorocarbons, and/or inorganic compounds.
Abstract translation: 将含有至少一种有机氟化合物的组合物与至少一种无机化合物通过与半透膜接触的方法。 其他方法将有机氟化合物与含有至少一种其它有机氟化合物或氯化碳的组合物分离。 方法还包括从包含有机氟化合物,氯代烃和/或无机化合物的混合物的组合物中分离单一有机氟化合物。
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公开(公告)号:US20210261716A1
公开(公告)日:2021-08-26
申请号:US17215066
申请日:2021-03-29
Applicant: Arkema Inc.
Inventor: Benjamin Bin CHEN , Joseph S. COSTA , Laurent T. ABBAS , Haiming LIU , Sri R. SESHADRI , William D. HONNICK
Abstract: A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N′-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba)
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公开(公告)号:US20230126554A1
公开(公告)日:2023-04-27
申请号:US17972664
申请日:2022-10-25
Applicant: Arkema Inc.
Inventor: Benjamin Bin CHEN , Joseph S. COSTA , Sri R. SESHADRI , Laurent ABBAS
Abstract: A polyol pre-mix containing at least one halogenated hydroolefin blowing agent and having improved shelf life stability is provided, wherein each polyol combined with the halogenated hydroolefin blowing agent has an apparent pH of between 3 and 11.4. Controlling the apparent pH of the polyol(s) enables the polyol pre-mix to be stored for extended periods of time and then used in combination with organic polyisocyanate to produce foam formulations having gel times and tack free times not significantly different from those exhibited when freshly prepared polyol pre-mix is used.
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公开(公告)号:US20190177465A1
公开(公告)日:2019-06-13
申请号:US16321052
申请日:2017-07-20
Applicant: Arkema Inc.
Inventor: Benjamin Bin CHEN , Joseph S. COSTA , Laurent T. ABBAS , Sri R. SESHADRI
Abstract: Incorporating a cycloaliphatic epoxide such as cyclohexene oxide into a polyol pre-mix containing an amine catalyst and a halogenated hydroolefin blowing agent such as HCFO-1233zd helps to improve the storage-stability of the pre-mix and to ensure that a thermoset foam prepared therefrom is of satisfactory quality.
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公开(公告)号:US20150360218A1
公开(公告)日:2015-12-17
申请号:US14763874
申请日:2014-01-20
Applicant: Arkema Inc.
Inventor: Robert G. SYVRET , Patrick K. JANNEY , Sri R. SESHADRI
IPC: B01J38/46 , C07C17/20 , B01J37/26 , B01J27/138 , B01J27/32
CPC classification number: B01J38/46 , B01J23/26 , B01J23/34 , B01J23/86 , B01J23/90 , B01J23/92 , B01J27/132 , B01J27/138 , B01J27/32 , B01J37/26 , C07C17/202 , C07C17/206 , C07C17/21 , Y02P20/584 , C07C21/18 , C07C19/08
Abstract: A fluorination catalyst such as a chromium oxide-based fluorination catalyst may be activated or reactivated by contacting the catalyst. with a source of reactive fluorine, for example nitrogen trifluoride (NF3) or fluorine (F2). Fluorinated compounds may be prepared by the gas phase reaction of hydrogen fluoride (HF) with various substrates such as chlorinated compounds. A number of metal oxide-based catalysts have been developed for this purpose.
Abstract translation: 可以通过使催化剂接触来活化或再活化诸如氧化铬基氟化催化剂的氟化催化剂。 具有活性氟源,例如三氟化氮(NF 3)或氟(F 2)。 氟化合物可以通过氟化氢(HF)与各种底物如氯化化合物的气相反应来制备。 为此目的已经开发了许多金属氧化物基催化剂。
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公开(公告)号:US20190248946A1
公开(公告)日:2019-08-15
申请号:US16397028
申请日:2019-04-29
Applicant: Arkema Inc.
Inventor: Benjamin Bin Chen , Joseph S. COSTA , Laurent T. ABBAS , Haiming LIU , Sri R. SESHADRI
CPC classification number: C08G18/06 , C08G18/1808 , C08G18/1816 , C08G18/1825 , C08G18/1833 , C08G18/4018 , C08G18/482 , C08G18/5033 , C08G18/7664 , C08G2101/005
Abstract: A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N′-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba)
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公开(公告)号:US20190233605A1
公开(公告)日:2019-08-01
申请号:US16381093
申请日:2019-04-11
Applicant: Arkema Inc.
Inventor: Benjamin Bin Chen , Joseph S. COSTA , Laurent T. ABBAS , Sri R. SESHADRI , Gary S. SMITH
IPC: C08J9/14 , C08G18/42 , C08G18/66 , C08G18/48 , C08G18/18 , C08G18/40 , C08G18/72 , C08J9/00 , C08G18/08
CPC classification number: C08J9/144 , C08G18/14 , C08G18/1808 , C08G18/1816 , C08G18/1833 , C08G18/4018 , C08G18/4208 , C08G18/4829 , C08G18/6674 , C08G18/72 , C08G2101/0025 , C08J9/0023 , C08J9/0061 , C08J2203/162 , C08J2375/08 , C08J2383/12
Abstract: A polyol pre-mix composition includes a blowing agent having a halogenated hydroolefin, a polyol, a catalyst composition, and an antioxidant. The antioxidant may be, for example, a benzene diol or a benzene triol or other polyhydroxy-substituted aromatic compound, which is optionally substituted with one or more substituents such as alkyl groups. A two-part system for producing a thermosetting foam blend includes (a) a polyisocyanate and, optionally, one or more isocyanate compatible raw materials; and (b) the polyol pre-mix composition. A method for producing a thermosetting foam blend includes combining: (a) a polyisocyanate; and (b) the polyol pre-mix composition.
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公开(公告)号:US20170081491A1
公开(公告)日:2017-03-23
申请号:US15164925
申请日:2016-05-26
Applicant: Arkema Inc.
Inventor: Benjamin Bin CHEN , Joseph S. COSTA , Sri R. SESHADRI , Laurent ABBAS
IPC: C08J9/14
CPC classification number: C08J9/144 , C08G18/092 , C08G18/1808 , C08G18/1816 , C08G18/4018 , C08G18/42 , C08G18/4208 , C08G18/4812 , C08G18/4825 , C08G18/4829 , C08G18/7664 , C08G2101/0025 , C08G2101/005 , C08J2201/022 , C08J2203/142 , C08J2205/052 , C08J2205/06 , C08J2205/10 , C08J2375/06 , C08J2375/08
Abstract: A polyol pre-mix containing at least one halogenated hydroolefin blowing agent and having improved shelf life stability is provided, wherein each polyol combined with the halogenated hydroolefin blowing agent has an apparent pH of between 3 and 11.4. Controlling the apparent pH of the polyol(s) enables the polyol pre-mix to be stored for extended periods of time and then used in combination with organic polyisocyanate to produce foam formulations having gel times and tack free times not significantly different from those exhibited when freshly prepared polyol pre-mix is used.
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