公开(公告)号：US07135223B2

公开(公告)日：2006-11-14

申请号：US10694753

申请日：2003-10-29

申请人： Atsushi Tofuku ,  Masaya Yukinobu

发明人： Atsushi Tofuku ,  Masaya Yukinobu

IPC分类号： B32B5/16 ,  B32B9/04

CPC分类号： C03C17/36 ,  B32B27/18 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/476 ,  C03C2217/479 ,  C03C2217/734 ,  C03C2217/76 ,  C03C2217/78 ,  C03C2217/94 ,  C03C2217/948 ,  C03C2218/113 ,  C03C2218/116 ,  Y10T428/12007 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/31663

摘要： A transparent conductive layered structure which has the functions of preventing electrostatic charging or shielding an electric field, and preventing reflection, the two-layered film of which has an excellent scratch strength, and with which a reduction in production cost is expected and a method of producing the same, and a transparent coat layer forming coating liquid used in the method of producing the same, and a display device to which the transparent conductive layered structure is applied, are provided. A transparent conductive layered structure of the present invention, comprises a transparent substrate and a transparent two-layered film being composed of a and a transparent coat layer being formed in succession on the transparent substrate, wherein the transparent conductive layer comprises, as its main components, conductive microparticles having a mean particle diameter of 1 to 100 nm and a binder matrix of silicon oxide, and wherein the transparent coat layer comprises, as its main component, a binder matrix of silicon oxide including one or more types of alkyl groups selected from long chain alkyl groups containing 7 to 30 carbon atoms.

摘要翻译： 具有防止静电充电或屏蔽电场的功能的透明导电层状结构，并且防止其双层膜具有优异的划痕强度并且预期降低生产成本的方法 制造该透明导电层叠结构体的方法中使用的透明涂层形成用涂布液，以及涂布有透明导电性层叠结构的显示装置。 本发明的透明导电层状结构包括在透明基板上依次形成由透明涂层和透明涂层构成的透明基板和透明二层膜，其中透明导电层包括作为其主要组分 ，平均粒径为1〜100nm的导电性微粒和氧化硅的粘合剂基质，并且其中所述透明涂层作为其主要成分包含氧化硅的粘合剂基质，其包含一种或多种选自以下的烷基： 含有7〜30个碳原子的长链烷基。

公开(公告)号：US06716480B2

公开(公告)日：2004-04-06

申请号：US10329573

申请日：2002-12-27

申请人： Masaya Yukinobu ,  Atsushi Tofuku ,  Kenji Kato ,  Midori Fujisaki

发明人： Masaya Yukinobu ,  Atsushi Tofuku ,  Kenji Kato ,  Midori Fujisaki

IPC分类号： B05D506

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/479 ,  H01B1/16 ,  H01J29/868 ,  H01J2229/8913 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/261

摘要： The present invention relates to a transparent conductive layered structure which comprises a transparent substrate, a transparent conductive layer and a transparent coating layer formed successively in this order on the substrate, and is used in, for instance, the front panel of displays such as CRT, etc. The transparent conductive layered structure according to the invention is characterized in that the main components of the above-mentioned transparent conductive layer are gold microparticles or gold-containing noble metal microparticles containing 5 wt % or more of gold with a mean particle diameter of 1 to 100 nm, and a binder matrix comprising at least one functional group selected from mercapto groups (—SH), sulfide groups (—S), and polysulfide groups (—Sx, X≧2). Film strength and weather resistance of the transparent conductive layer are improved because the noble metal microparticles and a binder matrix are firmly bonded via the above-mentioned functional groups.

摘要翻译： 本发明涉及一种透明导电层状结构，其包括在基板上依次依次形成的透明基板，透明导电层和透明涂层，并且用于例如CRT等显示器的前面板 等。根据本发明的透明导电层状结构的特征在于，上述透明导电层的主要成分是含有5重量％以上的平均粒径的金微粒或含金贵金属微粒 和包含至少一个选自巯基（-SH），硫化物基团（-S）和多硫化物基团（-Sx，X> = 2）的官能团的粘合剂基质。 透明导电层的膜强度和耐候性得到改善，因为贵金属微粒和粘合剂基体通过上述官能团牢固结合。

公开(公告)号：US06673142B2

公开(公告)日：2004-01-06

申请号：US09910883

申请日：2001-07-24

申请人： Atsushi Tofuku ,  Masaya Yukinobu

发明人： Atsushi Tofuku ,  Masaya Yukinobu

IPC分类号： C09D700

CPC分类号： C03C17/36 ,  B32B27/18 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/476 ,  C03C2217/479 ,  C03C2217/734 ,  C03C2217/76 ,  C03C2217/78 ,  C03C2217/94 ,  C03C2217/948 ,  C03C2218/113 ,  C03C2218/116 ,  Y10T428/12007 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/31663

摘要： A transparent conductive layered structure which has the functions of preventing electrostatic charging or shielding an electric field, and preventing reflection, the two-layered film of which has an excellent scratch strength, and with which a reduction in production cost is expected and a method of producing the same, and a transparent coat layer forming coating liquid used in the method of producing the same, and a display device to which the transparent conductive layered structure is applied, are provided. A transparent conductive layered structure of the present invention, comprises a transparent substrate and a transparent two-layered film being composed of a transparent conductive layer and a transparent coat layer being formed in succession on the transparent substrate, wherein the transparent conductive layer comprises, as its main components, conductive microparticles having a mean particle diameter of 1 to 100 nm and a binder matrix of silicon oxide, and wherein the transparent coat layer comprises, as its main component, a binder matrix of silicon oxide including one or more types of alkyl groups selected from long chain alkyl groups containing 7 to 30 carbon atoms.

摘要翻译： 具有防止静电充电或屏蔽电场的功能的透明导电层状结构，并且防止其双层膜具有优异的划痕强度并且预期降低生产成本的方法 制造该透明导电层叠结构体的方法中使用的透明涂层形成用涂布液，以及涂布有透明导电性层叠结构的显示装置。 本发明的透明导电层状结构体包括透明基板和由透明导电层和在透明基板上依次形成的透明涂层构成的透明二层膜，其中透明导电层包含： 其主要成分，平均粒径为1〜100nm的导电性微粒和氧化硅的粘合剂基质，其中，所述透明涂层作为其主要成分，包含氧化硅的粘合剂基质，其包含一种或多种类型的烷基 选自含有7至30个碳原子的长链烷基的基团。

公开(公告)号：US06569359B2

公开(公告)日：2003-05-27

申请号：US09910880

申请日：2001-07-24

申请人： Masaya Yukinobu ,  Kennichi Fujita ,  Atsushi Tofuku ,  Kenji Kato

发明人： Masaya Yukinobu ,  Kennichi Fujita ,  Atsushi Tofuku ,  Kenji Kato

IPC分类号： H01B122

CPC分类号： H01B1/16 ,  H01B1/02

摘要： The object is to provide a transparent conductive layer forming coating liquid capable of forming a transparent conductive layer having such characteristics as high transmittance, low resistance, low reflectance and high strength and with few film defects. The transparent conductive layer forming coating liquid of the present invention is characterized in that it comprises, as its main components, a solvent and noble metal microparticles with a mean particle diameter of 1 to 100 nm dispersed in the solvent, and that the above-mentioned solvent comprises 0.005 to 1.0 wt % of formamide (HCONH2). Further, using this transparent conductive layer forming coating liquid, it is possible to form a conductive layer with developed meshy structures easily so that it can form transparent conductive layers having such characteristics as high transmittance, low resistance, low reflectance and high strength and with few film defects.

公开(公告)号：US08883312B2

公开(公告)日：2014-11-11

申请号：US13369793

申请日：2012-02-09

申请人： Kayo Yabuki ,  Atsushi Tofuku

发明人： Kayo Yabuki ,  Atsushi Tofuku

IPC分类号： B32B5/16 ,  B05D7/00 ,  C01G9/02 ,  C03C17/00 ,  C09C1/04 ,  B82Y30/00

CPC分类号： C09C1/043 ,  B82Y30/00 ,  C01G9/02 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/22 ,  C01P2006/60 ,  C03C17/007 ,  C03C2217/445 ,  C03C2217/475 ,  Y10T428/24388 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/261 ,  Y10T428/269 ,  Y10T428/2995

摘要： Zinc oxide particles having high transparency in visible light and high shielding properties in a ultraviolet region, with surface treatment of inactivating photocatalytic activity applied thereto, and a dispersion thereof. A manufacturing method of surface treated zinc oxide particles, including: a first step of mixing a dispersion liquid with zinc oxide particles dispersed in a solvent, and silicone resin having polysiloxane bond with at least one or more silicon atoms having a silanol group (Si—OH) and/or alkoxy silyl group (Si—OR, wherein R is alkyl group); obtaining a mixed solution containing a surface treated zinc oxide particles precursor, with the silicone resin adsorbed on the surface of each zinc oxide particle and the solvent, and drying and solidifying the mixed solution by applying heat treatment thereto, to thereby manufacture a dried body; and a second step of pulverizing the dried body, to thereby manufacture the surface treated zinc oxide particles.

摘要翻译： 在紫外线区域具有高可见光透明度和高屏蔽性的氧化锌粒子，其中表现出对其施加的失活光催化活性的表面处理及其分散体。 一种表面处理氧化锌颗粒的制造方法，包括：将分散液与分散在溶剂中的氧化锌颗粒混合的第一步骤和具有聚硅氧烷键合的硅树脂与至少一个或多个具有硅烷醇基的硅原子（Si- OH）和/或烷氧基甲硅烷基（Si-OR，其中R是烷基）; 得到含有表面处理的氧化锌颗粒前体的混合溶液，其中硅氧烷树脂吸附在每个氧化锌颗粒和溶剂的表面上，并通过对其进行热处理来干燥和固化混合溶液，从而制造干燥体; 以及粉碎干燥体的第二步骤，从而制造表面处理的氧化锌颗粒。

公开(公告)号：US08304070B2

公开(公告)日：2012-11-06

申请号：US12734674

申请日：2008-09-30

申请人： Kayo Yabuki ,  Atsushi Tofuku

发明人： Kayo Yabuki ,  Atsushi Tofuku

IPC分类号： B32B5/16 ,  B05D7/00

CPC分类号： C09C1/043 ,  B82Y30/00 ,  C01G9/02 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/22 ,  C01P2006/60 ,  C03C17/007 ,  C03C2217/445 ,  C03C2217/475 ,  Y10T428/24388 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/261 ,  Y10T428/269 ,  Y10T428/2995

摘要： Zinc oxide particles having high transparency in visible light and high shielding properties in a ultraviolet region, with surface treatment of inactivating photocatalytic activity applied thereto, and a dispersion thereof. A manufacturing method of surface treated zinc oxide particles, including: a first step of mixing a dispersion liquid with zinc oxide particles dispersed in a solvent, and silicone resin having polysiloxane bond with at least one or more silicon atoms having a silanol group (Si—OH) and/or alkoxy silyl group (Si—OR, wherein R is alkyl group); obtaining a mixed solution containing a surface treated zinc oxide particles precursor, with the silicone resin adsorbed on the surface of each zinc oxide particle and the solvent, and drying and solidifying the mixed solution by applying heat treatment thereto, to thereby manufacture a dried body; and a second step of pulverizing the dried body, to thereby manufacture the surface treated zinc oxide particles.

摘要翻译： 在紫外线区域具有高可见光透明度和高屏蔽性的氧化锌粒子，其中表现出对其施加的失活光催化活性的表面处理及其分散体。 一种表面处理氧化锌颗粒的制造方法，包括：将分散液与分散在溶剂中的氧化锌颗粒混合的第一步骤和具有聚硅氧烷键合的硅树脂与至少一个或多个具有硅烷醇基的硅原子（Si- OH）和/或烷氧基甲硅烷基（Si-OR，其中R是烷基）; 得到含有表面处理的氧化锌颗粒前体的混合溶液，其中硅氧烷树脂吸附在每个氧化锌颗粒和溶剂的表面上，并通过对其进行热处理来干燥和固化混合溶液，从而制造干燥体; 以及粉碎干燥体的第二步骤，从而制造表面处理的氧化锌颗粒。

公开(公告)号：US08470212B2

公开(公告)日：2013-06-25

申请号：US13127192

申请日：2008-11-13

申请人： Atsushi Tofuku

发明人： Atsushi Tofuku

IPC分类号： F21V9/04 ,  F21V9/06 ,  G02B5/22 ,  G02B5/26 ,  C04B35/00 ,  B29D11/00

CPC分类号： C01G41/00 ,  B82Y30/00 ,  C01G41/02 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  C01P2002/52 ,  C01P2002/77 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/84 ,  C08K3/22 ,  C08K9/06 ,  C09C1/00 ,  C09C3/12 ,  C09D5/32 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68

摘要： There is provided infrared shielding nanoparticles having excellent water-resistant property and excellent infrared shielding property, which is the infrared shielding nanoparticles of composite tungsten oxide expressed by a general formula WyOz and/or a general formula MxWyOz, with an average primary particle size of the nanoparticle being 1 nm or more and 800 nm or less, and a surface of the nanoparticle being coated with tetrafunctional silane compound or its hydrolysis product and/or an organic metal compound.

摘要翻译： 提供了具有优异的防水性能和优异的红外屏蔽性能的红外屏蔽纳米颗粒，其是由通式W y O z和/或通式M x W y O z表示的复合氧化钨的红外屏蔽纳米颗粒，其平均初级粒径为 纳米粒子为1nm以上至800nm以下，纳米粒子的表面涂覆有四官能硅烷化合物或其水解产物和/或有机金属化合物。

公开(公告)号：US08174190B2

公开(公告)日：2012-05-08

申请号：US12289788

申请日：2008-11-04

申请人： Yosuke Ota ,  Atsushi Tofuku

发明人： Yosuke Ota ,  Atsushi Tofuku

IPC分类号： H01J17/49

CPC分类号： G02B5/24

摘要： To improve an optical property of a near-infrared-absorbing PDP filter and suppress a manufacturing cost. The present invention provides a dispersion liquid for near-infrared-absorbing adhesive-body. The dispersion liquid includes, in a solvent, one or more types of nanoparticles selected from a tungsten oxide nanoparticle and a composite tungsten oxide nanoparticle, and an acryl-based polymer dispersant is added to the dispersion liquid. The average dispersed nanoparticle diameter of the tungsten oxide nanoparticles and the composite tungsten oxide nanoparticles is equal to or smaller than 800 nm.

摘要翻译： 为了提高近红外线吸收型PDP滤光器的光学特性，抑制制造成本。 本发明提供一种用于近红外吸收粘合剂体的分散液。 分散液体在溶剂中含有选自氧化钨纳米粒子，复合钨氧化物纳米粒子的一种以上的纳米粒子和丙烯酸类聚合物分散剂。 氧化钨纳米粒子和复合钨氧化物纳米粒子的平均分散纳米粒子直径等于或小于800nm。

公开(公告)号：US20110297899A1

公开(公告)日：2011-12-08

申请号：US13127192

申请日：2008-11-13

申请人： Atsushi Tofuku

发明人： Atsushi Tofuku

IPC分类号： G02B5/26 ,  C09D5/00

CPC分类号： C01G41/00 ,  B82Y30/00 ,  C01G41/02 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  C01P2002/52 ,  C01P2002/77 ,  C01P2004/61 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/84 ,  C08K3/22 ,  C08K9/06 ,  C09C1/00 ,  C09C3/12 ,  C09D5/32 ,  C09D7/62 ,  C09D7/67 ,  C09D7/68

摘要： There is provided infrared shielding nanoparticles having excellent water-resistant property and excellent infrared shielding property, which is the infrared shielding nanoparticles of composite tungsten oxide expressed by a general formula WyOz and/or a general formula MxWyOz, with an average primary particle size of the nanoparticle being 1 nm or more and 800 nm or less, and a surface of the nanoparticle being coated with tetrafunctional silane compound or its hydrolysis product and/or an organic metal compound.

摘要翻译： 提供了具有优异的防水性能和优异的红外屏蔽性能的红外屏蔽纳米颗粒，其是由通式W y O z和/或通式M x W y O z表示的复合氧化钨的红外屏蔽纳米颗粒，其平均初级粒径为 纳米粒子为1nm以上至800nm以下，纳米粒子的表面涂覆有四官能硅烷化合物或其水解产物和/或有机金属化合物。

公开(公告)号：US20090116100A1

公开(公告)日：2009-05-07

申请号：US12289788

申请日：2008-11-04

申请人： Yosuke Ota ,  Atsushi Tofuku

发明人： Yosuke Ota ,  Atsushi Tofuku

IPC分类号： G02B5/24 ,  F21V9/04

CPC分类号： G02B5/24

摘要： To improve an optical property of a near-infrared-absorbing PDP filter and suppress a manufacturing cost. The present invention provides a dispersion liquid for near-infrared-absorbing adhesive-body. The dispersion liquid includes, in a solvent, one or more types of nanoparticles selected from a tungsten oxide nanoparticle and a composite tungsten oxide nanoparticle, and an acryl-based polymer dispersant is added to the dispersion liquid. The average dispersed nanoparticle diameter of the tungsten oxide nanoparticles and the composite tungsten oxide nanoparticles is equal to or smaller than 800 nm.

摘要翻译： 为了提高近红外线吸收型PDP滤光器的光学特性，抑制制造成本。 本发明提供一种用于近红外吸收粘合剂体的分散液。 分散液体在溶剂中含有选自氧化钨纳米粒子，复合钨氧化物纳米粒子的一种以上的纳米粒子和丙烯酸类聚合物分散剂。 氧化钨纳米粒子和复合钨氧化物纳米粒子的平均分散纳米粒子直径等于或小于800nm。