公开(公告)号：US06673142B2

公开(公告)日：2004-01-06

申请号：US09910883

申请日：2001-07-24

申请人： Atsushi Tofuku ,  Masaya Yukinobu

发明人： Atsushi Tofuku ,  Masaya Yukinobu

IPC分类号： C09D700

CPC分类号： C03C17/36 ,  B32B27/18 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/476 ,  C03C2217/479 ,  C03C2217/734 ,  C03C2217/76 ,  C03C2217/78 ,  C03C2217/94 ,  C03C2217/948 ,  C03C2218/113 ,  C03C2218/116 ,  Y10T428/12007 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/31663

摘要： A transparent conductive layered structure which has the functions of preventing electrostatic charging or shielding an electric field, and preventing reflection, the two-layered film of which has an excellent scratch strength, and with which a reduction in production cost is expected and a method of producing the same, and a transparent coat layer forming coating liquid used in the method of producing the same, and a display device to which the transparent conductive layered structure is applied, are provided. A transparent conductive layered structure of the present invention, comprises a transparent substrate and a transparent two-layered film being composed of a transparent conductive layer and a transparent coat layer being formed in succession on the transparent substrate, wherein the transparent conductive layer comprises, as its main components, conductive microparticles having a mean particle diameter of 1 to 100 nm and a binder matrix of silicon oxide, and wherein the transparent coat layer comprises, as its main component, a binder matrix of silicon oxide including one or more types of alkyl groups selected from long chain alkyl groups containing 7 to 30 carbon atoms.

摘要翻译： 具有防止静电充电或屏蔽电场的功能的透明导电层状结构，并且防止其双层膜具有优异的划痕强度并且预期降低生产成本的方法 制造该透明导电层叠结构体的方法中使用的透明涂层形成用涂布液，以及涂布有透明导电性层叠结构的显示装置。 本发明的透明导电层状结构体包括透明基板和由透明导电层和在透明基板上依次形成的透明涂层构成的透明二层膜，其中透明导电层包含： 其主要成分，平均粒径为1〜100nm的导电性微粒和氧化硅的粘合剂基质，其中，所述透明涂层作为其主要成分，包含氧化硅的粘合剂基质，其包含一种或多种类型的烷基 选自含有7至30个碳原子的长链烷基的基团。

公开(公告)号：US07135223B2

公开(公告)日：2006-11-14

申请号：US10694753

申请日：2003-10-29

申请人： Atsushi Tofuku ,  Masaya Yukinobu

发明人： Atsushi Tofuku ,  Masaya Yukinobu

IPC分类号： B32B5/16 ,  B32B9/04

CPC分类号： C03C17/36 ,  B32B27/18 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/476 ,  C03C2217/479 ,  C03C2217/734 ,  C03C2217/76 ,  C03C2217/78 ,  C03C2217/94 ,  C03C2217/948 ,  C03C2218/113 ,  C03C2218/116 ,  Y10T428/12007 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/31663

摘要： A transparent conductive layered structure which has the functions of preventing electrostatic charging or shielding an electric field, and preventing reflection, the two-layered film of which has an excellent scratch strength, and with which a reduction in production cost is expected and a method of producing the same, and a transparent coat layer forming coating liquid used in the method of producing the same, and a display device to which the transparent conductive layered structure is applied, are provided. A transparent conductive layered structure of the present invention, comprises a transparent substrate and a transparent two-layered film being composed of a and a transparent coat layer being formed in succession on the transparent substrate, wherein the transparent conductive layer comprises, as its main components, conductive microparticles having a mean particle diameter of 1 to 100 nm and a binder matrix of silicon oxide, and wherein the transparent coat layer comprises, as its main component, a binder matrix of silicon oxide including one or more types of alkyl groups selected from long chain alkyl groups containing 7 to 30 carbon atoms.

摘要翻译： 具有防止静电充电或屏蔽电场的功能的透明导电层状结构，并且防止其双层膜具有优异的划痕强度并且预期降低生产成本的方法 制造该透明导电层叠结构体的方法中使用的透明涂层形成用涂布液，以及涂布有透明导电性层叠结构的显示装置。 本发明的透明导电层状结构包括在透明基板上依次形成由透明涂层和透明涂层构成的透明基板和透明二层膜，其中透明导电层包括作为其主要组分 ，平均粒径为1〜100nm的导电性微粒和氧化硅的粘合剂基质，并且其中所述透明涂层作为其主要成分包含氧化硅的粘合剂基质，其包含一种或多种选自以下的烷基： 含有7〜30个碳原子的长链烷基。

公开(公告)号：US06716480B2

公开(公告)日：2004-04-06

申请号：US10329573

申请日：2002-12-27

申请人： Masaya Yukinobu ,  Atsushi Tofuku ,  Kenji Kato ,  Midori Fujisaki

发明人： Masaya Yukinobu ,  Atsushi Tofuku ,  Kenji Kato ,  Midori Fujisaki

IPC分类号： B05D506

CPC分类号： C03C17/009 ,  C03C17/007 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/479 ,  H01B1/16 ,  H01J29/868 ,  H01J2229/8913 ,  Y10T428/25 ,  Y10T428/256 ,  Y10T428/261

摘要： The present invention relates to a transparent conductive layered structure which comprises a transparent substrate, a transparent conductive layer and a transparent coating layer formed successively in this order on the substrate, and is used in, for instance, the front panel of displays such as CRT, etc. The transparent conductive layered structure according to the invention is characterized in that the main components of the above-mentioned transparent conductive layer are gold microparticles or gold-containing noble metal microparticles containing 5 wt % or more of gold with a mean particle diameter of 1 to 100 nm, and a binder matrix comprising at least one functional group selected from mercapto groups (—SH), sulfide groups (—S), and polysulfide groups (—Sx, X≧2). Film strength and weather resistance of the transparent conductive layer are improved because the noble metal microparticles and a binder matrix are firmly bonded via the above-mentioned functional groups.

摘要翻译： 本发明涉及一种透明导电层状结构，其包括在基板上依次依次形成的透明基板，透明导电层和透明涂层，并且用于例如CRT等显示器的前面板 等。根据本发明的透明导电层状结构的特征在于，上述透明导电层的主要成分是含有5重量％以上的平均粒径的金微粒或含金贵金属微粒 和包含至少一个选自巯基（-SH），硫化物基团（-S）和多硫化物基团（-Sx，X> = 2）的官能团的粘合剂基质。 透明导电层的膜强度和耐候性得到改善，因为贵金属微粒和粘合剂基体通过上述官能团牢固结合。

公开(公告)号：US06569359B2

公开(公告)日：2003-05-27

申请号：US09910880

申请日：2001-07-24

申请人： Masaya Yukinobu ,  Kennichi Fujita ,  Atsushi Tofuku ,  Kenji Kato

发明人： Masaya Yukinobu ,  Kennichi Fujita ,  Atsushi Tofuku ,  Kenji Kato

IPC分类号： H01B122

CPC分类号： H01B1/16 ,  H01B1/02

摘要： The object is to provide a transparent conductive layer forming coating liquid capable of forming a transparent conductive layer having such characteristics as high transmittance, low resistance, low reflectance and high strength and with few film defects. The transparent conductive layer forming coating liquid of the present invention is characterized in that it comprises, as its main components, a solvent and noble metal microparticles with a mean particle diameter of 1 to 100 nm dispersed in the solvent, and that the above-mentioned solvent comprises 0.005 to 1.0 wt % of formamide (HCONH2). Further, using this transparent conductive layer forming coating liquid, it is possible to form a conductive layer with developed meshy structures easily so that it can form transparent conductive layers having such characteristics as high transmittance, low resistance, low reflectance and high strength and with few film defects.

公开(公告)号：US09701849B2

公开(公告)日：2017-07-11

申请号：US13579380

申请日：2011-02-15

申请人： Masaya Yukinobu ,  Takahito Nagano ,  Yoshihiro Otsuka

发明人： Masaya Yukinobu ,  Takahito Nagano ,  Yoshihiro Otsuka

IPC分类号： B05D3/06 ,  B05D3/04 ,  B05D5/06 ,  B05D5/12 ,  C09D5/24 ,  C23C18/14 ,  H01L31/18 ,  C23C18/12 ,  C09D11/101

CPC分类号： C09D5/24 ,  C09D11/101 ,  C23C18/1216 ,  C23C18/1275 ,  C23C18/1279 ,  C23C18/1295 ,  C23C18/14 ,  H01L21/02565 ,  H01L21/02628 ,  H01L31/1884 ,  Y02E10/50

摘要： By using a coating method, which is a simple method of manufacturing a transparent conductive film at low cost, a transparent conductive film formed with heating at a low temperature, in particular, lower than 300° C. with both of excellent transparency and conductivity and also with excellent film strength and a method of manufacturing this transparent conductive film are provided.

公开(公告)号：US08753987B2

公开(公告)日：2014-06-17

申请号：US13261535

申请日：2011-06-08

申请人： Masaya Yukinobu ,  Yuki Murayama ,  Takahito Nagano ,  Yoshihiro Otsuka

发明人： Masaya Yukinobu ,  Yuki Murayama ,  Takahito Nagano ,  Yoshihiro Otsuka

IPC分类号： H01L21/469

CPC分类号： C01G41/02 ,  B05D3/007 ,  C01F7/02 ,  C01F17/0043 ,  C01G23/047 ,  C01G25/02 ,  C01G27/02 ,  C01G31/02 ,  C01G33/00 ,  C01G35/00 ,  C01G39/02 ,  C03C17/006 ,  C03C2217/212 ,  C03C2217/214 ,  C03C2217/218 ,  C03C2217/219 ,  C03C2217/22 ,  C03C2217/228 ,  C03C2217/42 ,  C03C2218/116 ,  C03C2218/119 ,  H01L21/02565 ,  H01L21/02628

摘要： Provided is a method of manufacturing a metal oxide film to be formed through the following processes: a coating process of forming a coating film on a substrate by using a coating liquid for forming metal oxide film containing any of various organometallic compounds; a drying process of making the coating film into a dried coating film; and a heating process of forming an inorganic film from the dried coating film under an oxygen-containing atmosphere having a dew-point temperature equal to or lower than −10° C.

摘要翻译： 提供一种通过以下方法制造金属氧化物膜的方法：通过使用用于形成含有各种有机金属化合物的金属氧化物膜的涂布液在基板上形成涂膜的涂布方法; 使涂膜成为干燥涂膜的干燥工序; 以及在露点温度等于或低于-10℃的含氧气氛下从干燥的涂膜形成无机膜的加热方法。

公开(公告)号：US20090278440A1

公开(公告)日：2009-11-12

申请号：US12308815

申请日：2006-06-26

申请人： Masaya Yukinobu ,  Yuki Murayama ,  Hiroyuki Tanaka ,  Yasuo Tsukui

发明人： Masaya Yukinobu ,  Yuki Murayama ,  Hiroyuki Tanaka ,  Yasuo Tsukui

IPC分类号： H01J1/62 ,  B05D5/12 ,  B32B37/14

CPC分类号： H05B33/10 ,  Y10T156/10

摘要： A dispersion-type EL element formed on a thin or flexible transparent plastic film and a method for manufacturing the same are provided. The dispersion-type electroluminescent element is a dispersion-type electroluminescent element with at least a transparent conductive layer, a phosphor layer, a dielectric layer, and a rear electrode layer sequentially formed on a transparent plastic film surface, in which a thickness of the transparent plastic film is less than 50 μm, and the transparent conductive layer is formed by applying compression processing to an applied layer formed by applying a transparent conductive layer forming application liquid mainly composed of conductive oxide particles and a binder on the transparent plastic film surface and then, curing the compressed layer.

摘要翻译： 提供了形成在薄或柔性透明塑料薄膜上的分散型EL元件及其制造方法。 分散型电致发光元件是分散型电致发光元件，其具有至少透明导电层，荧光体层，电介质层和后电极层，其依次形成在透明塑料膜表面上，其中透明 塑料薄膜的面积小于50μm，透明导电层是通过在透明塑料薄膜表面上涂布主要由导电氧化物颗粒和粘合剂构成的透明导电层形成用涂敷液形成的涂布层进行压缩加工而形成的， ，固化压缩层。

公开(公告)号：US20050214522A1

公开(公告)日：2005-09-29

申请号：US11127252

申请日：2005-05-12

申请人： Masaya Yukinobu ,  Yukiko Suekane

发明人： Masaya Yukinobu ,  Yukiko Suekane

IPC分类号： C09C1/36 ,  B01J13/00 ,  B22F1/00 ,  B22F9/24 ,  C09C1/48 ,  C09C1/62 ,  C09C3/06 ,  C09D1/00 ,  C09D5/00 ,  C09D5/24 ,  H01B1/00 ,  H01B1/22 ,  H01B13/00 ,  B32B5/16

CPC分类号： B22F1/0022 ,  B01J13/0043 ,  B22F1/0096 ,  B22F2998/00 ,  B82Y30/00 ,  H01B1/22 ,  Y10T428/1086 ,  Y10T428/12889 ,  Y10T428/24917 ,  Y10T428/25 ,  Y10T428/2991

摘要： A process for producing a noble-metal type fine-particle dispersions, having the steps of an agglomeration step of add ing a hydrazine solution to a dispersion in which primary particles of noble-metal type fine particles have been made to stand monodisperse in a solvent, to destabilize the dispersibility of the noble-metal type fine particles in the dispersion and cause the plurality of primary particles in the noble-metal type fine particles to agglomerate in the form of chains to obtain a dispersion of chainlike agglomerates; and a stabilization step of adding a hydrogen peroxide solution to the dispersion of the chainlike agglomerates obtained, to decompose and remove the hydrazine to stabilize the dispersibility of the chainlike agglomerates in the dispersion.

摘要翻译： 一种贵金属型微粒分散体的制造方法，其特征在于，具有以下步骤：将肼溶液添加到已经使贵金属型微粒的一次粒子在溶剂中单分散的分散液中 为了使分散体中的贵金属型细颗粒的分散性不稳定，使贵金属型微粒中的多个一次粒子以链状的形式团聚，得到链状团聚物的分散体; 以及将过氧化氢溶液加入到获得的链状团聚物的分散体中以分解和除去肼以稳定分散体中链状团聚体的分散性的稳定步骤。

公开(公告)号：US06686249B1

公开(公告)日：2004-02-03

申请号：US09711513

申请日：2000-11-14

申请人： Masaya Yukinobu ,  Yoshihiro Ohtsuka ,  Kenji Kato ,  Yukiko Suekane ,  Midori Fujisaki

发明人： Masaya Yukinobu ,  Yoshihiro Ohtsuka ,  Kenji Kato ,  Yukiko Suekane ,  Midori Fujisaki

IPC分类号： B32B1500

CPC分类号： H01J29/868 ,  C03C17/3411 ,  C03C2217/45 ,  C03C2217/475 ,  C03C2217/479 ,  C03C2217/485 ,  C09D5/24 ,  H01J2211/446 ,  H01J2229/8632 ,  H01J2229/882 ,  H01J2329/869 ,  Y10T428/12014 ,  Y10T428/2991 ,  Y10T428/31844

摘要： The present invention pertains to a transparent conductive layered structure having a transparent substrate and a transparent 2-layer film consisting of a transparent conductive layer and a transparent coating layer formed in succession on this substrate, that is used for instance, in the front panel of displays, such as CRTs, etc. The above-mentioned transparent conductive layer has as its main components noble metal microparticles with a mean particle diameter of 1 to 100 nm composed of gold and/or platinum and silver and containing 5 to 95 wt % gold and/or platinum, colored pigment microparticles with a mean particle diameter of 5 to 200 nm, and binder matrix. The noble metal microparticles are mixed at a ratio of 1 to 40 parts by weight per 1 part by weight colored pigment microparticles. Moreover, it is characterized in that the transparent 2-layer film has a surface resistance of 10 to 5000 &OHgr;/□, reflectance of 0 to 2.5%, visible light transmittance of 40 to 75%, and standard deviation of transmittance at each wavelength in 5 nm intervals of the visible light wavelength region being 0 to 5%.

摘要翻译： 本发明涉及一种透明导电层状结构，其具有透明基板和由该基板上连续形成的透明导电层和透明涂层构成的透明2层膜，例如在前面板 显示器，例如CRT等。上述透明导电层的主要成分是由金和/或铂和银组成的平均粒径为1〜100nm的贵金属微粒，并含有5〜95重量％的金 和/或平均粒径为5〜200nm的铂色有色颜料微粒和粘合剂基质。 贵金属微粒以每1重量份有色颜料微粒1〜40重量份的比例混合。 此外，其特征在于，透明2层膜的表面电阻为10〜5000Ω/□，反射率为0〜2.5％，可见光透射率为40〜75％，各波长的透射率标准偏差 可见光波长区域的5nm间隔为0〜5％。

公开(公告)号：US06528112B2

公开(公告)日：2003-03-04

申请号：US10134476

申请日：2002-04-30

申请人： Kenji Kato ,  Masaya Yukinobu

发明人： Kenji Kato ,  Masaya Yukinobu

IPC分类号： B05D506

CPC分类号： H01J29/28 ,  C09D5/24 ,  Y10T428/12896 ,  Y10T428/2991

摘要： The present invention relates to a transparent conductive layered structure having a transparent substrate and a transparent conductive layer and transparent coating layer formed in succession on this substrate, used in, for instance, the front panel of CRT, etc., display devices. The main components of said transparent conductive layer are noble metal microparticles with a mean particle diameter of 1 to 100 nm, wherein the microparticles are made from gold and/or platinum and silver and the gold and/or platinum content is within a range exceeding 50 wt % up to 95 wt %, and a binder matrix. Moreover, the main components of the coating liquid used to form a transparent conductive layer in the production of a transparent conductive layered structure are solvent and noble metal-coated silver microparticles with a mean particle diameter of 1 to 100 nm dispersed in this solvent, wherein the surface of the silver microparticles is coated with gold or platinum only or a compound of gold and platinum and the gold and/or platinum content is within a range exceeding 50 wt % up to 95 wt %.