公开(公告)号：US09567451B2

公开(公告)日：2017-02-14

申请号：US13991377

申请日：2011-11-25

申请人： Masaki Satou ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Ayumi Naka ,  Keisuke Maejima

发明人： Masaki Satou ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Ayumi Naka ,  Keisuke Maejima

IPC分类号： B60C1/00 ,  C08C19/44 ,  C08L15/00 ,  C08K7/00 ,  C08C19/25 ,  C08G81/02 ,  C08K3/36 ,  C08L7/00 ,  C08L9/00

CPC分类号： C08K7/00 ,  B60C1/00 ,  B60C1/0016 ,  C08C19/25 ,  C08C19/44 ,  C08G81/02 ,  C08K3/36 ,  C08L7/00 ,  C08L9/00 ,  C08L15/00 ,  Y02T10/862

摘要： A rubber composition for use in tire treads comprises a diene rubber including not less than 40% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 66 to 110 parts by weight of a filler. The filler comprises not less than 50% by weight of silica. The modified conjugated diene polymer rubber is obtained by copolymerizing a conjugated diene monomer unit and an aromatic vinyl monomer unit in a hydrocarbon solvent using an organic active metal compound as an initiator. A resulting active conjugated diene polymer chain thereof has a terminal modified group, obtained by reacting at least one type of compound having a functional group that is reactable with the active terminal of the polymer chain. Moreover, the terminal modified group has a functional group that interacts with the silica.

摘要翻译： 用于轮胎胎面的橡胶组合物包括二烯橡胶，其包含不小于40重量％的改性共轭二烯聚合物橡胶，并且相对于每100重量份的二烯橡胶，含有66至110重量份的填料。 填料包含不少于50重量％的二氧化硅。 改性共轭二烯聚合物橡胶通过使用有机活性金属化合物作为引发剂在烃溶剂中共轭共轭二烯单体单元和芳族乙烯基单体单元而获得。 所得到的活性共轭二烯聚合物链具有末端改性基团，其通过使至少一种具有可与聚合物链的活性末端反应的官能团的化合物反应而获得。 此外，末端改性基团具有与二氧化硅相互作用的官能团。

公开(公告)号：US09416252B2

公开(公告)日：2016-08-16

申请号：US13991398

申请日：2011-11-25

申请人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou ,  Keisuke Maejima

发明人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou ,  Keisuke Maejima

IPC分类号： B60C1/00 ,  C08C19/44 ,  C08L15/00 ,  C08K7/00 ,  C08K3/36 ,  C08L9/00

CPC分类号： C08K7/00 ,  B60C1/0016 ,  C08C19/44 ,  C08K3/36 ,  C08L7/00 ,  C08L9/00 ,  C08L15/00 ,  Y02T10/862

摘要： A rubber composition comprises a diene rubber including not less than 25% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 25 to 65 parts by weight of a filler, the filler comprising not less than 50% by weight of silica. The silica has a DBP absorption number of 190 to 250 ml/100 g, an N2SA of 194 to 225 m/g, and a CTAB of 185 to 215 m2/g. A ratio of the N2SA to the CTAB is from 0.9 to 1.4. The modified conjugated diene polymer rubber has a terminal modified group including a functional group that interacts with the silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, and weight-average molecular weight is from 600,000 to 1,000,000.

摘要翻译： 橡胶组合物包括二烯橡胶，其包含不小于25重量％的改性共轭二烯聚合物橡胶，并且相对于每100重量份的二烯橡胶，25至65重量份的填料，所述填料不少于 超过50重量％的二氧化硅。 二氧化硅的DBP吸收值为190〜250ml / 100g，N 2 SA为194〜225m 2 / g，CTAB为185〜215m 2 / g。 N2SA与CTAB的比例为0.9〜1.4。 改性共轭二烯聚合物橡胶具有包含与二氧化硅相互作用的官能团的末端改性基团。 在改性共轭二烯聚合物橡胶中，芳香族乙烯基单元含量为38〜48重量％，乙烯基单元含量为20〜35重量％，重均分子量为60万〜100万。

公开(公告)号：US20140011909A1

公开(公告)日：2014-01-09

申请号：US13991377

申请日：2011-11-25

申请人： Masaki Satou ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Ayumi Naka ,  Keisuke Maejima

发明人： Masaki Satou ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Ayumi Naka ,  Keisuke Maejima

IPC分类号： C08K7/00

CPC分类号： C08K7/00 ,  B60C1/00 ,  B60C1/0016 ,  C08C19/25 ,  C08C19/44 ,  C08G81/02 ,  C08K3/36 ,  C08L7/00 ,  C08L9/00 ,  C08L15/00 ,  Y02T10/862

摘要： A rubber composition for use in tire treads comprises a diene rubber including not less than 40% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 66 to 110 parts by weight of a filler. The filler comprises not less than 50% by weight of silica. The modified conjugated diene polymer rubber is obtained by copolymerizing a conjugated diene monomer unit and an aromatic vinyl monomer unit in a hydrocarbon solvent using an organic active metal compound as an initiator. A resulting active conjugated diene polymer chain thereof has a terminal modified group, obtained by reacting at least one type of compound having a functional group that is reactable with the active terminal of the polymer chain. Moreover, the terminal modified group has a functional group that interacts with the silica.

摘要翻译： 用于轮胎胎面的橡胶组合物包括二烯橡胶，其包含不小于40重量％的改性共轭二烯聚合物橡胶，并且相对于每100重量份的二烯橡胶，含有66至110重量份的填料。 填料包含不少于50重量％的二氧化硅。 改性共轭二烯聚合物橡胶通过使用有机活性金属化合物作为引发剂在烃溶剂中共轭共轭二烯单体单元和芳族乙烯基单体单元而获得。 所得到的活性共轭二烯聚合物链具有末端改性基团，其通过使至少一种具有可与聚合物链的活性末端反应的官能团的化合物反应而获得。 此外，末端改性基团具有与二氧化硅相互作用的官能团。

公开(公告)号：US20130338255A1

公开(公告)日：2013-12-19

申请号：US13991398

申请日：2011-11-25

申请人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou ,  Keisuke Maejima

发明人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou ,  Keisuke Maejima

IPC分类号： C08K7/00

CPC分类号： C08K7/00 ,  B60C1/0016 ,  C08C19/44 ,  C08K3/36 ,  C08L7/00 ,  C08L9/00 ,  C08L15/00 ,  Y02T10/862

摘要： A rubber composition comprises a diene rubber including not less than 25% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 25 to 65 parts by weight of a filler, the filler comprising not less than 50% by weight of silica. The silica has a DBP absorption number of 190 to 250 ml/100 g, an N2SA of 194 to 225 m/g, and a CTAB of 185 to 215 m2/g. A ratio of the N2SA to the CTAB is from 0.9 to 1.4. The modified conjugated diene polymer rubber has a terminal modified group including a functional group that interacts with the silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, and weight-average molecular weight is from 600,000 to 1,000,000.

摘要翻译： 橡胶组合物包括二烯橡胶，其包含不小于25重量％的改性共轭二烯聚合物橡胶，并且相对于每100重量份的二烯橡胶，25至65重量份的填料，所述填料不少于 超过50重量％的二氧化硅。 二氧化硅的DBP吸收值为190〜250ml / 100g，N 2 SA为194〜225m 2 / g，CTAB为185〜215m 2 / g。 N2SA与CTAB的比例为0.9〜1.4。 改性共轭二烯聚合物橡胶具有包含与二氧化硅相互作用的官能团的末端改性基团。 在改性共轭二烯聚合物橡胶中，芳香族乙烯基单元含量为38〜48重量％，乙烯基单元含量为20〜35重量％，重均分子量为60万〜100万。

公开(公告)号：US10072138B2

公开(公告)日：2018-09-11

申请号：US13991414

申请日：2011-11-25

申请人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou

发明人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou

IPC分类号： C08K3/36 ,  B60C1/00 ,  C08L15/00 ,  C08C19/44 ,  C08F236/10 ,  C08L57/02 ,  C08C19/25

CPC分类号： C08L15/00 ,  B60C1/0016 ,  C08C19/25 ,  C08C19/44 ,  C08F236/10 ,  C08K3/36 ,  C08L57/02 ,  Y02T10/862

摘要： A rubber composition comprises a diene rubber including not less than 30% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 1 to 25 parts by weight of a tackifying resin, and from 25 to 80 parts by weight of a filler comprising not less than 50% by weight of silica. The modified conjugated diene polymer rubber has a terminal modified group comprising a functional group that interacts with silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, weight-average molecular weight is from 600,000 to 1,000,000, and glass transition temperature is from −22 to −32° C. A glass transition temperature of the tackifying resin is from 50 to 110° C. higher than the glass transition temperature of the modified conjugated diene polymer rubber.

公开(公告)号：US20130324638A1

公开(公告)日：2013-12-05

申请号：US13991414

申请日：2011-11-25

申请人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou

发明人： Ayumi Naka ,  Takashi Shirokawa ,  Makoto Ashiura ,  Yoshihiro Kameda ,  Masaki Satou

IPC分类号： C08L15/00

CPC分类号： C08L15/00 ,  B60C1/0016 ,  C08C19/25 ,  C08C19/44 ,  C08F236/10 ,  C08K3/36 ,  C08L57/02 ,  Y02T10/862

摘要： A rubber composition comprises a diene rubber including not less than 30% by weight of a modified conjugated diene polymer rubber and, per 100 parts by weight of the diene rubber, from 1 to 25 parts by weight of a tackifying resin, and from 25 to 80 parts by weight of a filler comprising not less than 50% by weight of silica. The modified conjugated diene polymer rubber has a terminal modified group comprising a functional group that interacts with silica. In the modified conjugated diene polymer rubber, aromatic vinyl unit content is from 38% to 48% by weight, vinyl unit content is from 20% to 35%, weight-average molecular weight is from 600,000 to 1,000,000, and glass transition temperature is from −22 to −32° C. A glass transition temperature of the tackifying resin is from 50 to 110° C. higher than the glass transition temperature of the modified conjugated diene polymer rubber.

摘要翻译： 橡胶组合物包括二烯橡胶，其包含不小于30重量％的改性共轭二烯聚合物橡胶，每100重量份二烯橡胶，1至25重量份增粘树脂和25至 80重量份包含不少于50重量％二氧化硅的填料。 改性共轭二烯聚合物橡胶具有包含与二氧化硅相互作用的官能团的末端改性基团。 在改性共轭二烯聚合物橡胶中，芳香族乙烯基单元含量为38〜48重量％，乙烯基单元含量为20〜35重量％，重均分子量为60万〜100万，玻璃化转变温度为 -22至-32℃。增粘树脂的玻璃化转变温度比改性共轭二烯聚合物橡胶的玻璃化转变温度高50至110℃。

公开(公告)号：US08148473B2

公开(公告)日：2012-04-03

申请号：US12667274

申请日：2008-06-11

申请人： Yoshihiro Kameda ,  Makoto Ashiura

发明人： Yoshihiro Kameda ,  Makoto Ashiura

IPC分类号： C08C19/20

CPC分类号： C08L9/06 ,  B60C1/0016 ,  C08C19/44 ,  C08K3/013 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L15/00 ,  C08L2666/08

摘要： Disclosed is a sulfur-containing conjugated diolefin copolymer rubber composed of a conjugated diolefin and an aromatic vinyl compound, wherein (1) the content of sulfur bound to the rubber is 0.01 mmol % or more, (2) the content of the aromatic vinyl compound polymerization unit is not less than 5 wt % and less than 45 wt % relative to the amount of the copolymer rubber, and (3) the content of a vinyl bond (a 1,2-bond) in the conjugated diolefin polymerization unit is 30 mol % or more relative to the amount of the conjugated diolefin polymerization unit. In the copolymerization between the conjugated diolefin and the aromatic vinyl compound, a sulfur-containing polymerization terminator is used to terminate the reaction of the copolymerization.

摘要翻译： 公开了由共轭二烯烃和芳族乙烯基化合物组成的含硫共轭二烯共聚物橡胶，其中（1）与橡胶结合的硫含量为0.01mmol％以上，（2）芳香族乙烯基化合物 聚合单元相对于共聚物橡胶的量不小于5重量％且小于45重量％，和（3）共轭二烯烃聚合单元中的乙烯基键（1,2-键）的含量为30 相对于共轭二烯烃聚合单元的量的摩尔％以上。 在共轭二烯烃和芳族乙烯基化合物的共聚中，使用含硫聚合终止剂来终止​​共聚反应。

公开(公告)号：US20100179280A1

公开(公告)日：2010-07-15

申请号：US12667274

申请日：2008-06-11

申请人： Yoshihiro Kameda ,  Makoto Ashiura

发明人： Yoshihiro Kameda ,  Makoto Ashiura

IPC分类号： C08K3/36 ,  C08F236/10

CPC分类号： C08L9/06 ,  B60C1/0016 ,  C08C19/44 ,  C08K3/013 ,  C08K3/04 ,  C08K3/36 ,  C08K5/548 ,  C08L15/00 ,  C08L2666/08

摘要： Disclosed is a sulfur-containing conjugated diolefin copolymer rubber composed of a conjugated diolefin and an aromatic vinyl compound, wherein (1) the content of sulfur bound to the rubber is 0.01 mmol % or more, (2) the content of the aromatic vinyl compound polymerization unit is not less than 5 wt % and less than 45 wt % relative to the amount of the copolymer rubber, and (3) the content of a vinyl bond (a 1,2-bond) in the conjugated diolefin polymerization unit is 30 mol % or more relative to the amount of the conjugated diolefin polymerization unit. In the the copolymerization between the conjugated diolefin and the aromatic vinyl compound, a specific sulfur-containing polymerization terminator is used to terminate the reaction of the copolymerization. The sulfur-containing conjugated diolefin copolymer rubber has good processability and a good balance among wear resistance, fracture properties and low hysteresis loss.

摘要翻译： 公开了由共轭二烯烃和芳族乙烯基化合物组成的含硫共轭二烯共聚物橡胶，其中（1）与橡胶结合的硫含量为0.01mmol％以上，（2）芳香族乙烯基化合物 聚合单元相对于共聚物橡胶的量不小于5重量％且小于45重量％，和（3）共轭二烯烃聚合单元中的乙烯基键（1,2-键）的含量为30 相对于共轭二烯烃聚合单元的量的摩尔％以上。 在共轭二烯烃和芳族乙烯基化合物的共聚中，使用特定的含硫聚合终止剂来终止​​共聚反应。 含硫共轭二烯烃共聚物橡胶具有良好的加工性能，耐磨性，断裂性能和低磁滞损耗之间的平衡良好。

公开(公告)号：US20090182069A1

公开(公告)日：2009-07-16

申请号：US12406188

申请日：2009-03-18

申请人： Makoto Ashiura ,  Tetsuji Kawazura ,  Fumito Yatsuyanagi

发明人： Makoto Ashiura ,  Tetsuji Kawazura ,  Fumito Yatsuyanagi

IPC分类号： C08K3/04 ,  C08K3/36

CPC分类号： B82Y30/00 ,  B60C1/00 ,  C08L19/006

摘要： A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan δ balance.

摘要翻译： 通过在分子中配合含有0.5〜100重量％的具有与其结合的富勒烯的改性共轭二烯系聚合物，重均分子量为50,000以上，优异的加工性的橡胶组合物，优异的平衡性 模量和热积累，优异的冷流动性和优异的tanδ平衡。

公开(公告)号：US20080146737A1

公开(公告)日：2008-06-19

申请号：US11955216

申请日：2007-12-12

申请人： Makoto Ashiura ,  Tetsuji Kawazura ,  Kazuo Arakawa

发明人： Makoto Ashiura ,  Tetsuji Kawazura ,  Kazuo Arakawa

IPC分类号： C08L9/00

CPC分类号： C08L23/22 ,  C08L23/10 ,  C08L2666/06

摘要： A thermoplastic elastomer composition containing a dynamically cross-linked composition of(A) 10 to 70 parts by weight of a thermoplastic resin,(B) 30 to 90 parts by weight of a modified butyl rubber composition containing a modified butyl rubber modified reacting, to butyl rubber, (a) a compound containing, in the molecule thereof, a nitroxide free radical stable at an ordinary temperature in the presence of oxygen, and (c) a bifunctional or higher functional radical polymerizable monomer, and(C) 0.01 to 15 parts by weight of a cross-linking agent.

摘要翻译： 一种热塑性弹性体组合物，其含有（A）10〜70重量份热塑性树脂的动态交联组合物，（B）30〜90重量份含有改性丁基橡胶改性反应的改性丁基橡胶组合物， 丁基橡胶，（a）在氧分子中含有在常温下在氧的存在下稳定的氮氧自由基的化合物，（c）双官能以上的官能团的可自由基聚合的单体，（C）0.01〜15 重量份的交联剂。