公开(公告)号：US10537886B2

公开(公告)日：2020-01-21

申请号：US15754261

申请日：2016-08-23

Applicant: BASF CORPORATION

Inventor： Rostam Jal Madon ,  Peter Nagel ,  Keenan Lee Deutsch ,  Deepak S. Thakur

IPC: B01J23/72 ,  B01J37/12 ,  B01J38/00 ,  B01J37/00 ,  C07C29/42 ,  B01J23/843 ,  B01J35/02 ,  B01J21/04 ,  B01J21/08 ,  B01J21/16 ,  B01J21/18 ,  B01J27/232 ,  B01J37/08 ,  C07C33/046

Abstract: A process of forming an ethynylation catalyst includes providing a slurry including water, a copper-containing material, a bismuth-containing material, a structural material, and a binder; spray-drying the slurry to form particles; and calcining the particles to form the ethynylation catalyst.

公开(公告)号：US20160228854A1

公开(公告)日：2016-08-11

申请号：US15134778

申请日：2016-04-21

Applicant: BASF Corporation

Inventor： Rostam Jai Madon ,  Peter Nagel ,  Deepak S. Thakur

IPC: B01J23/80 ,  B01J37/04

CPC classification number: B01J23/80 ,  B01J21/04 ,  B01J21/066 ,  B01J23/72 ,  B01J35/0053 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/1019 ,  B01J37/031 ,  B01J37/04 ,  C07C67/00 ,  C07C67/40 ,  C07C69/14

Abstract: Catalysts and methods for their manufacture and use for the dehydrogenation of alcohols are disclosed. The catalysts and methods utilize a highly dispersible alumina, for example, boehmite or pseudoboehmite, to form catalysts that exhibit high dehydrogenation activities. Specifically, the catalysts include Cu that is highly dispersed by reaction of an alumina formed by peptizing of boehmite or pseudoboehmite and precursors of ZrO2, ZnO and CuO.

Abstract translation: 公开了用于制备和用于醇脱氢的催化剂及其方法。 催化剂和方法利用高度分散的氧化铝，例如勃姆石或假勃姆石来形成表现出高脱氢活性的催化剂。 具体地，催化剂包括通过由勃姆石或假勃姆石胶溶而形成的氧化铝与ZrO 2，ZnO和CuO的前体反应而高度分散的Cu。

公开(公告)号：US20150105568A1

公开(公告)日：2015-04-16

申请号：US14550316

申请日：2014-11-21

Applicant: BASF Corporation

Inventor： Rostam Jal Madon ,  Rolf Pinkos ,  Olga Osetska ,  Deepak S. Thakur ,  Ron Jagta

IPC: C07D307/08 ,  B01J21/04 ,  B01J23/72 ,  B01J21/12

CPC classification number: B01J23/72 ,  B01J21/04 ,  B01J21/12 ,  B01J29/46 ,  B01J35/002 ,  B01J37/0201 ,  B01J37/16 ,  B01J37/18 ,  B01J2229/186 ,  B01J2229/42 ,  C07D307/08

Abstract: Provided are catalysts suitable for the production of tetrahydrofuran from 1,4-butanediol. Also provided are methods of use of these catalyst, as well as catalyst systems. The catalysts described herein contain only Lewis acidity, but not Broønsted acidity, which results in decreased production of ether byproducts.

Abstract translation: 提供适合于从1,4-丁二醇生产四氢呋喃的催化剂。 还提供了这些催化剂以及催化剂体系的使用方法。 本文所述的催化剂仅含有路易斯酸度，但不包括布朗斯台德酸度，这导致醚副产物的产生减少。

公开(公告)号：US20150231607A1

公开(公告)日：2015-08-20

申请号：US14705613

申请日：2015-05-06

Applicant: BASF Corporation

Inventor： Rostam Jal Madon ,  Rolf Pinkos ,  Olga Osetska ,  Deepak S. Thakur ,  Ronald L. Jagta

IPC: B01J23/72 ,  B01J21/04 ,  C07D307/08

CPC classification number: B01J23/72 ,  B01J21/04 ,  B01J21/12 ,  B01J29/46 ,  B01J35/002 ,  B01J37/0201 ,  B01J37/16 ,  B01J37/18 ,  B01J2229/186 ,  B01J2229/42 ,  C07D307/08

Abstract: Provided are catalysts suitable for the production of tetrahydrofuran from 1,4-butanediol. Also provided are methods of use of these catalyst, as well as catalyst systems. The catalysts described herein contain only Lewis acidity, but not Brønsted acidity, which results in decreased production of ether byproducts.

Abstract translation: 提供适合于从1,4-丁二醇生产四氢呋喃的催化剂。 还提供了这些催化剂以及催化剂体系的使用方法。 本文所述的催化剂仅含有路易斯酸度，但不包括布朗斯台德酸度，其导致醚副产物的产生减少。

公开(公告)号：US20190336944A1

公开(公告)日：2019-11-07

申请号：US16511289

申请日：2019-07-15

Applicant: BASF Corporation

Inventor： Deepak S. Thakur ,  William O. Tuttle ,  Arunabha Kundu ,  Keenan Lee Deutsch ,  Jeffrey Baciak

IPC: B01J23/00 ,  B01J37/00 ,  B01J37/04 ,  B01J23/889 ,  B01J23/80 ,  B01J35/00 ,  B01J35/10 ,  B01J37/08 ,  C07C29/149 ,  B01J21/14 ,  B01J23/72

Abstract: A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids.

公开(公告)号：US20130296585A1

公开(公告)日：2013-11-07

申请号：US13851562

申请日：2013-03-27

Applicant: BASF CORPORATION

Inventor： Rostam Jal Madon ,  Rolf Pinkos ,  Olga Osetska ,  Deepak S. Thakur ,  Ron Jagta

IPC: B01J23/72 ,  C07D307/08

Abstract: Provided are catalysts suitable for the production of tetrahydrofuran from 1,4-butanediol. Also provided are methods of use of these catalyst, as well as catalyst systems. The catalysts described herein contain only Lewis acidity, but not Brønsted acidity, which results in decreased production of ether byproducts.

Abstract translation: 提供适合于从1,4-丁二醇生产四氢呋喃的催化剂。 还提供了这些催化剂以及催化剂体系的使用方法。 本文所述的催化剂仅含有路易斯酸度，但不包括布朗斯台德酸度，其导致醚副产物的产生减少。

公开(公告)号：US09371266B2

公开(公告)日：2016-06-21

申请号：US14242065

申请日：2014-04-01

Applicant: BASF Corporation

Inventor： Rostam Jai Madon ,  Peter Nagel ,  Deepak S. Thakur

IPC: C07C67/00 ,  B01J37/03 ,  C07C67/40 ,  B01J21/04 ,  B01J21/06 ,  B01J23/80 ,  B01J35/00 ,  B01J35/10 ,  B01J23/72

CPC classification number: B01J23/80 ,  B01J21/04 ,  B01J21/066 ,  B01J23/72 ,  B01J35/0053 ,  B01J35/006 ,  B01J35/0066 ,  B01J35/1019 ,  B01J37/031 ,  B01J37/04 ,  C07C67/00 ,  C07C67/40 ,  C07C69/14

Abstract: Catalysts and methods for their manufacture and use for the dehydrogenation of alcohols are disclosed. The catalysts and methods utilize a highly dispersible alumina, for example, boehmite or pseudoboehmite, to form catalysts that exhibit high dehydrogenation activities. Specifically, the catalysts include Cu that is highly dispersed by reaction of an alumina formed by peptizing of boehmite or pseudoboehmite and precursors of ZrO2, ZnO and CuO.

Abstract translation: 公开了用于制备和用于醇脱氢的催化剂及其方法。 催化剂和方法利用高度分散的氧化铝，例如勃姆石或假勃姆石来形成表现出高脱氢活性的催化剂。 具体地，催化剂包括通过由勃姆石或假勃姆石胶溶而形成的氧化铝与ZrO 2，ZnO和CuO的前体反应而高度分散的Cu。

公开(公告)号：US20160038917A1

公开(公告)日：2016-02-11

申请号：US14822291

申请日：2015-08-10

Applicant: BASF Corporation

Inventor： Deepak S. Thakur ,  William J. Carrick

IPC: B01J21/16 ,  C07C209/36 ,  B01J37/00 ,  C07C29/145 ,  B01J35/10 ,  B01J37/04

CPC classification number: B01J21/16 ,  B01J23/06 ,  B01J23/34 ,  B01J23/78 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  B01J37/04 ,  B01J37/08 ,  C07C29/145 ,  C07C209/36 ,  C07C211/46 ,  C07C33/22

Abstract: Catalysts for hydrogenation comprise a catalytic material and an inorganic matrix component, wherein the catalytic material comprises: at least one metal component comprising a metal selected from the group consisting of copper, manganese, zinc, nickel, cobalt, and iron; and an alkali metal component or an alkaline earth metal component; wherein the inorganic matrix component based on at least a silica sol component and a clay material; wherein the catalytic material and the inorganic matrix component are processed together to form the catalyst; and wherein the catalyst has a mesopore volume in the range of 50-90 by weight % of an overall pore volume. Catalysts are effective for converting acetophenone to methylphenyl carbinol and/or for converting nitrobenzene to aniline.

Abstract translation: 用于氢化的催化剂包括催化材料和无机基质组分，其中催化材料包括：至少一种金属组分，其包含选自铜，锰，锌，镍，钴和铁的金属; 和碱金属组分或碱土金属组分; 其中所述无机基质组分至少基于硅溶胶组分和粘土材料; 其中催化材料和无机基质组分一起加工以形成催化剂; 并且其中所述催化剂的中孔体积在总孔体积的50-90重量％的范围内。 催化剂对于将苯乙酮转化为甲基苯基甲醇和/或将硝基苯转化为苯胺是有效的。

公开(公告)号：US11077428B2

公开(公告)日：2021-08-03

申请号：US16511289

申请日：2019-07-15

Applicant: BASF Corporation

Inventor： Deepak S. Thakur ,  William O. Tuttle ,  Arunabha Kundu ,  Keenan Lee Deutsch ,  Jeffrey Baciak

IPC: B01J21/04 ,  B01J21/08 ,  B01J21/12 ,  B01J23/00 ,  B01J23/72 ,  B01J23/78 ,  B01J23/80 ,  B01J23/88 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  C07C29/149 ,  B01J23/889 ,  B01J35/00 ,  B01J21/14 ,  B01J23/70

Abstract: A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids.

公开(公告)号：US10350577B2

公开(公告)日：2019-07-16

申请号：US15561220

申请日：2016-03-25

Applicant: BASF Corporation

Inventor： Deepak S. Thakur ,  William O. Tuttle ,  Arunabha Kundu ,  Keenan Lee Deutsch ,  Jeffrey Baciak

IPC: C07C29/149 ,  B01J21/12 ,  B01J23/00 ,  B01J23/72 ,  B01J23/78 ,  B01J23/80 ,  B01J23/889 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  B01J21/14 ,  B01J23/70

Abstract: A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids.