公开(公告)号：US20160207776A1

公开(公告)日：2016-07-21

申请号：US14914558

申请日：2014-08-25

Applicant: BASF SE

Inventor： Tobias Hintermann ,  Matthias Georg Schwab ,  Kitty Chih-Pei Cha ,  Thomas Weitz ,  Ansgar Schäfer ,  Imke Britta Müller

IPC: C01B31/04 ,  H01L29/16 ,  H01L29/78 ,  H01L29/06

CPC classification number: H01L29/78 ,  C01B32/196 ,  C01B2204/06 ,  H01L29/0669 ,  H01L29/0673 ,  H01L29/1606 ,  H01L29/66037 ,  H01L29/66045 ,  H01L29/7781

Abstract: In a process for purifying graphene nanoribbons, a composition comprising graphene nanoribbons GNR1 and at least one contaminant is brought into contact with a liquid medium that includes a dispersant. The graphene nanoribbons GNR1 are dispersed in the liquid medium so as to obtain a liquid dispersion of the graphene nanoribbons GNR1. The liquid dispersion of the graphene nanoribbons GNR1 is subjected to a separation treatment so as to at least partly remove the at least one contaminant, thereby obtaining a liquid dispersion of purified graphene nanoribbons GNR1.

Abstract translation: 在用于纯化石墨烯纳米带的方法中，包含石墨烯纳米带GNR1和至少一种污染物的组合物与包括分散剂的液体介质接触。 将石墨烯纳米带GNR1分散在液体介质中，以获得石墨烯纳米带GNR1的液体分散体。 将石墨烯纳米带GNR1的液体分散体进行分离处理，以至少部分除去至少一种污染物，从而获得纯化的石墨烯纳米带GNR1的液体分散体。

公开(公告)号：US20150030968A1

公开(公告)日：2015-01-29

申请号：US14384095

申请日：2013-02-26

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Zhong-Shuai Wu

IPC: H01G11/24 ,  H01M4/96 ,  H01M4/90 ,  H01G11/32 ,  H01G11/56

CPC classification number: H01G11/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/192 ,  H01G11/32 ,  H01G11/36 ,  H01G11/56 ,  H01M4/90 ,  H01M4/96 ,  Y02E60/13

Abstract: The present invention relates to an aerogel based on doped graphene, a method for producing said aerogel and the use of said aerogel, for example, as an electrode or a catalyst. Furthermore, the present invention relates to electrodes, all solid-state supercapacitors (ASSS) or catalysts based on said aerogel. The present invention also relates to doped graphene, which can be obtained as an intermediate in the production of the aerogel based on doped graphene using graphene oxide as starting material.

Abstract translation: 本发明涉及一种基于掺杂石墨烯的气凝胶，一种制备所述气凝胶的方法和所述气凝胶的使用，例如电极或催化剂。 此外，本发明涉及电极，所有固态超级电容器（ASSS）或基于所述气凝胶的催化剂。 本发明还涉及掺杂石墨烯，其可以在使用氧化石墨烯作为起始材料的基于掺杂石墨烯的气凝胶生产中作为中间体获得。

公开(公告)号：US20140353554A1

公开(公告)日：2014-12-04

申请号：US14367041

申请日：2012-12-17

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Akimitsu Narita ,  Xinliang Feng ,  Klaus Muellen

IPC: C01B31/04 ,  C08F138/00 ,  H01B1/04 ,  C07C49/683

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C07C49/683 ,  C08F2/00 ,  C08F138/00 ,  C08G61/10 ,  C08G2261/1412 ,  C08G2261/312 ,  C08G2261/364 ,  C08G2261/46 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  H01B1/04 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

Abstract: An oligophenylene monomer of general formula (I) wherein R1 and R2 are independently of each other H, halogene, —OH, —NH2, —CN, —NO2 or a linear or branched, saturated or unsaturated C1-C40 hydrocarbon residue, which can be substituted 1- to 5-fold with halogene (F, Cl, Br, I), —OH, —NH2, —CN and/or —NO2, and wherein one or more CH2-groups can be replaced by —O— or —S—, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; and m represents 0, 1 or 2.

Abstract translation: 通式（I）的低聚苯乙烯单体，其中R 1和R 2彼此独立地为H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以 用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 基团可以被-O-或 -S-或任选取代的芳基，烷基芳基或烷氧基芳基; m表示0,1或2。

公开(公告)号：US10329378B2

公开(公告)日：2019-06-25

申请号：US15118796

申请日：2015-02-09

Applicant: BASF SE ,  EMPA-Eidgenoessische Materialpruefungs- und Forschungsanstalt ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Bo Yang ,  Tim Dumslaff ,  Roman Fasel ,  Pascal Ruffieux ,  Jia Liu ,  Jinming Cai ,  Carlos Sanchez-Sanchez ,  Junzhi Liu

IPC: C07C25/22 ,  C08G61/10 ,  C07C15/20 ,  C01B32/184

Abstract: Provided are graphene nanoribbons with controlled zig-zag edge and cove edge configuration and methods for preparing such graphene nanoribbons. The nanoribbons are selected from the following formulae.

公开(公告)号：US10266662B2

公开(公告)日：2019-04-23

申请号：US15301842

申请日：2015-03-26

Applicant: BASF SE

Inventor： Lucia Jimenez Garcia ,  Kathrin Michl ,  Ingolf Hennig ,  Kitty Chih-Pei Cha ,  Matthias Georg Schwab

IPC: C08J5/02 ,  C08J5/04 ,  C08J5/10 ,  C08F220/18 ,  C08L33/08

Abstract: Disclosed are electrically conducting shaped articles and also a process for producing same from granular and/or fibrous substrates.

公开(公告)号：US20140301936A1

公开(公告)日：2014-10-09

申请号：US14354430

申请日：2012-10-24

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Lukas Doessel

IPC: C01B31/04 ,  C07C17/30 ,  C07C25/18 ,  C08G61/10

CPC classification number: C08G61/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07C15/14 ,  C07C17/30 ,  C07C25/18 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  C08G2261/412 ,  H01L51/0045 ,  H01L51/0558 ,  H01L51/102

Abstract: Provided are graphene nanoribbon precursors comprising repeated units of the general formula (I) in which R1, R2 are each H, halogen, —OH, —NH2, —CN, —NO2 or a hydrocarbyl radical which has 1 to 40 carbon atoms and may be linear or branched, saturated or unsaturated and mono- or poly-substituted by halogen (F, Cl, Br, I), —OH, —NH2, —CN, and/or —NO2, where one or more CH2 groups may also be replaced by —O—, —S—, —C(O)O—, —O—C(O)—, —C(O)—, —NH— or —NR—, in which R is an optionally substituted C1C40-hydrocarbyl radical, or an optionally substituted aryl, alkylaryl or alkoxyaryl radical.

Abstract translation: 提供了包含通式（I）的重复单元的石墨烯纳米纤维前体，其中R 1，R 2各自为H，卤素，-OH，-NH 2，-CN，-NO 2或具有1至40个碳原子的烃基， 是直链或支链的，饱和或不饱和的，被卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2单取代或多取代，其中一个或多个CH 2基团也可以 被-O - ， - S - ， - C（O）O-，-O-C（O） - ， - C（O） - ， - NH-或-NR-取代，其中R是任选取代的 C 1 -C 40 - 烃基或任选取代的芳基，烷基芳基或烷氧基芳基。

公开(公告)号：US11547981B2

公开(公告)日：2023-01-10

申请号：US15733841

申请日：2019-05-28

Applicant: BASF SE

Inventor： Matthias Georg Schwab ,  Esther Groeneveld ,  Peter Berben ,  Harry Bouwman ,  Willem Dijkstra ,  Bart Michielsen ,  Jasper Lefevere

IPC: B01J21/04 ,  B33Y10/00 ,  B29C64/106 ,  B01J35/00 ,  B01J35/04 ,  B01J35/06 ,  B01J35/10 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08 ,  B28B1/00 ,  B28B11/24 ,  C07C1/24 ,  C07C5/27 ,  B33Y70/00 ,  B33Y80/00 ,  B29K509/02

Abstract: A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising:
a) Preparing a paste in a liquid diluent of hydroxide precursor particles and/or oxyhydroxide precursor particles of transition alumina particles, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 μm,
b) extruding the paste nozzle(s) to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor,
c) drying the precursor to remove the liquid diluent,
d) performing a temperature treatment of the dried porous catalyst monolith precursor to form the transition alumina catalyst monolith,
wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000° C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface.

公开(公告)号：US20140301935A1

公开(公告)日：2014-10-09

申请号：US14354329

申请日：2012-10-24

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Sorin Ivanovici ,  Matthias Georg Schwab ,  Xinliang Feng ,  Klaus Muellen

IPC: C01B31/04 ,  C08G61/10 ,  C07C17/30 ,  C07C25/18

CPC classification number: C07C25/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/182 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07C17/093 ,  C07C17/263 ,  C07C17/30 ,  C07C17/361 ,  C07C2603/42 ,  C07C2603/54 ,  C08G61/10 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/412 ,  Y10S977/734 ,  Y10S977/842 ,  C07C25/22 ,  C07C25/24

Abstract: Oligophenylene monomers for the synthesis of polymeric precursors for the preparation of graphene nanoribbons, the polymeric precursors, and methods for preparing them, as well as methods for preparing the graphene nanoribbons from the polymeric precursors and the monomers are provided.

Abstract translation: 提供用于合成制备石墨烯纳米带的聚合物前体的亚乙基单体，聚合物前体及其制备方法，以及从聚合物前体和单体制备石墨烯纳米带的方法。

公开(公告)号：US09550678B2

公开(公告)日：2017-01-24

申请号：US14367041

申请日：2012-12-17

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e. V.

Inventor： Matthias Georg Schwab ,  Akimitsu Narita ,  Xinliang Feng ,  Klaus Muellen

IPC: C01B31/04 ,  C07C49/683 ,  C08F138/00 ,  H01B1/04 ,  C08F2/00 ,  B82Y30/00 ,  B82Y40/00 ,  C08G61/10 ,  C08L65/00

CPC classification number: C01B31/0446 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C07C49/683 ,  C08F2/00 ,  C08F138/00 ,  C08G61/10 ,  C08G2261/1412 ,  C08G2261/312 ,  C08G2261/364 ,  C08G2261/46 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  C08L65/00 ,  H01B1/04 ,  Y10S977/734 ,  Y10S977/842 ,  Y10S977/932

Abstract: An oligophenylene monomer of general formula (I) wherein R1 and R2 are independently of each other H, halogene, —OH, —NH2, —CN, —NO2 or a linear or branched, saturated or unsaturated C1-C40 hydrocarbon residue, which can be substituted 1-to 5-fold with halogene (F, Cl, Br, I), —OH, —NH2, —CN and/or —NO2, and wherein one or more CH2-groups can be replaced by —O— or —S—, or an optionally substituted aryl, alkylaryl or alkoxyaryl residue; and m represents 0, 1 or 2.

Abstract translation: 通式（I）的低聚苯乙烯单体，其中R 1和R 2彼此独立地为H，卤素，-OH，-NH 2，-CN，-NO 2或直链或支链，饱和或不饱和的C 1 -C 40烃残基，其可以 用卤素（F，Cl，Br，I），-OH，-NH 2，-CN和/或-NO 2取代1至5倍，并且其中一个或多个CH 2 - 基团可以被-O-或 -S-或任选取代的芳基，烷基芳基或烷氧基芳基; m表示0,1或2。

公开(公告)号：US09434619B2

公开(公告)日：2016-09-06

申请号：US14354430

申请日：2012-10-24

Applicant: BASF SE ,  Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.

Inventor： Matthias Georg Schwab ,  Klaus Muellen ,  Xinliang Feng ,  Lukas Doessel

IPC: C01B31/02 ,  C01B31/04 ,  B82Y40/00 ,  C07C17/30 ,  C07C25/18 ,  C08G61/10 ,  B82Y30/00

CPC classification number: C08G61/10 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/184 ,  C01B2204/06 ,  C01B2204/065 ,  C07C15/14 ,  C07C17/30 ,  C07C25/18 ,  C08G2261/1412 ,  C08G2261/148 ,  C08G2261/312 ,  C08G2261/314 ,  C08G2261/412 ,  H01L51/0045 ,  H01L51/0558 ,  H01L51/102

Abstract: Provided are graphene nanoribbon precursors comprising repeated units of the general formula (I) in which R1, R2 are each H, halogen, —OH, —NH2, —CN, —NO2 or a hydrocarbyl radical which has 1 to 40 carbon atoms and may be linear or branched, saturated or unsaturated and mono- or poly-substituted by halogen (F, Cl, Br, I), —OH, —NH2, —CN, and/or —NO2, where one or more CH2 groups may also be replaced by —O—, —S—, —C(O)O—, —O—C(O)—, —C(O)—, —NH— or —NR—, in which R is an optionally substituted C1C40-hydrocarbyl radical, or an optionally substituted aryl, alkylaryl or alkoxyaryl radical.