公开(公告)号：US20230250278A1

公开(公告)日：2023-08-10

申请号：US18003102

申请日：2021-06-23

申请人： BASF SE

发明人： Tobias KALUSCHKE ,  Christian RENNER ,  Olaf JACOBMEIER ,  Sabrina KRONIG

IPC分类号： C08L75/04 ,  C08J9/14

CPC分类号： C08L75/04 ,  C08J9/144 ,  C08J9/141 ,  C08J2203/14 ,  C08L2201/02 ,  C08J2375/04 ,  C08J2203/162

摘要： Disclosed herein is a process for producing rigid polyisocyanurate foams, where (a) aromatic polyisocyanate, (b) isocyanate-reactive compounds including at least one polyetherol (b1) and/or polyesterol (b2), wherein where the number-average content of isocyanate-reactive hydrogen atoms of components (b 1) and (b2) is at least 1.7, (c) catalyst, (d) blowing agents, (e) flame retardants, (f) optionally auxiliary and additive substances and (g) optionally compounds having aliphatic hydrophobic groups and not falling under the definition of compounds (a) to (f) are mixed to afford a reaction mixture and allowed to cure to afford a rigid polyisocyanurate foam. Further disclosed herein is a rigid polyisocyanurate foam obtainable by the process.

公开(公告)号：US20140094531A1

公开(公告)日：2014-04-03

申请号：US14034745

申请日：2013-09-24

申请人： BASF SE

发明人： Gunnar KAMPF ,  Olaf JACOBMEIER ,  Tobias KALUSCHKE ,  Christian KOENIG

IPC分类号： C08G18/32 ,  C08J9/00

CPC分类号： C08G18/3206 ,  C08G18/225 ,  C08G18/482 ,  C08G18/4891 ,  C08G2101/0025 ,  C08G2101/005 ,  C08G2105/02 ,  C08J9/0038

摘要： A process for producing rigid polyurethane foams or rigid polyisocyanurate foams is provided. The process contains the reaction of polyisocyanate, fatty acid modified polyetherpolyol, polyetherpolyol, optionally flame retardant, blowing agent, catalyst, and optionally further auxiliary and/or admixture agent, wherein the polyetherpolyol is obtained by a process containing reacting orthotolylenediamine and optionally further co-starters with alkylene oxide containing ethylene oxide wherein the ethylene oxide content is more than 20 wt %, and then reacting the reaction product with alkylene oxide containing propylene oxide wherein the 1,2-propylene oxide content is more than 20 wt %, in the presence of a catalyst.

摘要翻译： 提供了用于生产刚性聚氨酯泡沫或刚性聚异氰脲酸酯泡沫的方法。 该方法包含多异氰酸酯，脂肪酸改性的聚醚多元醇，聚醚多元醇，任选的阻燃剂，发泡剂，催化剂和任选的其它辅助和/或混合剂的反应，其中所述聚醚多元醇通过含有对甲基苯二胺反应和任选进一步共 - 其中环氧乙烷含环氧乙烷的起始物，其中环氧乙烷含量大于20重量％，然后使反应产物与含环氧丙烷的环氧烷烃反应，其中1,2-环氧丙烷含量大于20重量％，在存在下 的催化剂。

公开(公告)号：US20240360268A1

公开(公告)日：2024-10-31

申请号：US18571975

申请日：2022-07-14

申请人： BASF SE

发明人： Tobias KALUSCHKE ,  Olaf JACOBMEIER ,  Sebastian KOCH

IPC分类号： C08G18/40 ,  C08G18/16 ,  C08G18/18 ,  C08G18/22 ,  C08G18/42 ,  C08G18/48 ,  C08G18/76 ,  C08J9/14 ,  C08K5/521

CPC分类号： C08G18/4018 ,  C08G18/163 ,  C08G18/1833 ,  C08G18/225 ,  C08G18/4236 ,  C08G18/4804 ,  C08G18/4825 ,  C08G18/4891 ,  C08G18/7671 ,  C08J9/141 ,  C08K5/521 ,  C08G2110/0025 ,  C08J2203/14 ,  C08J2203/182 ,  C08J2205/10 ,  C08J2375/08

摘要： Disclosed herein is a method for preparing rigid polyurethane foams, in which method (a) polyisocyanates are mixed with (b) compounds having at least two hydrogen atoms that are reactive with isocyanate groups, (c) optionally a flame retardant, (d) a blowing agent, (e) a catalyst, and (f) optionally auxiliary agents and additives, to form a reaction mixture and are cured to provide the rigid polyurethane foam. Further disclosed herein are a rigid polyurethane foam obtained by the method and a method of using the rigid polyurethane foam in the manufacture of sandwich elements.

公开(公告)号：US20240309162A1

公开(公告)日：2024-09-19

申请号：US18693252

申请日：2022-10-17

申请人： BASF SE

发明人： Tobias KALUSCHKE ,  Sebastian KOCH ,  Olaf JACOBMEIER

IPC分类号： C08J9/00 ,  C08G18/08 ,  C08G18/16 ,  C08G18/40 ,  C08G18/42 ,  C08G18/48 ,  C08G101/00 ,  C08J9/08 ,  C08J9/14

CPC分类号： C08J9/0038 ,  C08G18/14 ,  C08G18/161 ,  C08G18/4018 ,  C08G18/4213 ,  C08G18/4825 ,  C08G18/4837 ,  C08J9/0042 ,  C08J9/0061 ,  C08J9/08 ,  C08J9/141 ,  C08G2101/00 ,  C08G2110/0025 ,  C08G2330/00 ,  C08J2201/026 ,  C08J2203/02 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/184 ,  C08J2205/10 ,  C08J2375/06

摘要： The present invention relates to a process for producing rigid polyisocyanurate foams, wherein (A) polyisocyanates are mixed with (B) compounds having isocyanate-reactive hydrogen atoms, (C) flame retardants, (D) blowing agents, (E) catalyst at an isocyanate index of at least 220 to afford a reaction mixture and cured to afford the rigid polyisocyanurate foam, wherein the component (B) comprises at least one aromatic polyester polyol (b1) and at least one polyether polyol (b2), the polyester polyol (b1) has an average total functionality of ≤3.0 and ≥1.7 and the polyether polyol (b2) has a hydroxyl number of 160-350 mg KOH/g and is produced by alkoxylation of a starter or starter mixture having an average total functionality ≤3.5 and ≥1.5, wherein as the alkylene oxide for producing polyether polyol (b2) at least 80%by weight of ethylene oxide is employed and comprises at least 90% primary hydroxyl end groups and wherein the mass ratio of the component (b1) to component (b2) is ≤3 and ≥1 and the blowing agent (D) comprises chemical and physical blowing agents, wherein the chemical blowing agent is selected from the group consisting of formic acid-water mixtures and formic acid. The present invention further relates to a rigid polyisocyanurate foam obtainable by the process according to the invention.

公开(公告)号：US20160347904A1

公开(公告)日：2016-12-01

申请号：US15117960

申请日：2015-01-27

申请人： BASF SE

发明人： Tobias KALUSCHKE ,  Gunnar KAMPF

IPC分类号： C08G63/672 ,  C08G18/42 ,  C08G18/48 ,  C08J9/00 ,  C08G18/76 ,  C08G18/08 ,  C08J9/14 ,  C08G18/40 ,  C08G18/18

CPC分类号： C08G63/672 ,  C08G18/14 ,  C08G18/1833 ,  C08G18/4018 ,  C08G18/4219 ,  C08G18/4288 ,  C08G18/4825 ,  C08G18/4879 ,  C08G18/7664 ,  C08G18/7671 ,  C08G63/668 ,  C08G2101/0025 ,  C08J9/0038 ,  C08J9/141 ,  C08J2203/14 ,  C08J2375/08

摘要： The present invention relates to polyester polyols obtainable or obtained by esterification of 10 to 70 mol % of at least one compound from the group consisting of terephthalic acid (TPA), dimethyl terephthalate (DMT), polyethylene terephthalate (PET), phthalic anhydride (PA), phthalic acid and isophthalic acid, 0.1 to 30 mol % of one or more fatty acids and/or fatty acid derivatives, 10 to 70 mol % of one or more aliphatic or cycloaliphatic diols having 2 to 18 carbon atoms or alkoxylates thereof, 5 to 70 mol % of a polyether polyol prepared by alkoxylating an aromatic starter molecule having a functionality of not less than 2, and of 0 to 70 mol % of a tri- or polyol other than the polyether polyol, all based on the total amount of the components used, wherein the amounts used of the components add up to 100 mol %. The present invention further relates to a process for producing rigid polyurethane or polyisocyanurate foams which comprises reacting an isocyanate component with a polyol component (PK) comprising a polyester polyol of the present invention and further components, to the polyol component as such and also to the rigid polyurethane or polyisocyanurate foams obtainable or obtained by a process of the present invention. The present invention also relates to the method of using a polyester polyol (P1) of the present invention in the manufacture of rigid polyurethane foams or rigid polyisocyanurate foams.

摘要翻译： 本发明涉及由对苯二甲酸（TPA），对苯二甲酸二甲酯（DMT），聚对苯二甲酸乙二醇酯（PET），邻苯二甲酸酐（PA），邻苯二甲酸酐（PA）等组成的组中的10〜70摩尔％的至少一种化合物 ），邻苯二甲酸和间苯二甲酸，0.1〜30摩尔％的一种或多种脂肪酸和/或脂肪酸衍生物，10〜70摩尔％的一种或多种碳原子数2〜18的脂肪族或脂环族二醇或其烷氧基化物，5 至70摩尔％的通过使官能度不低于2的芳族起始分子和0至70摩尔％的除聚醚多元醇以外的三元醇或多元醇烷氧化而制备的聚醚多元醇，全部基于 所使用的组分，其中所用组分的添加量高达100mol％。 本发明还涉及用于生产硬质聚氨酯或聚异氰脲酸酯泡沫的方法，其包括将异氰酸酯组分与本发明的包含本发明的聚酯多元醇的多元醇组分（PK）和其它组分原样反应到多元醇组分，以及 通过本发明的方法获得或获得的硬质聚氨酯或聚异氰脲酸酯泡沫。 本发明还涉及使用本发明的聚酯多元醇（P1）制造刚性聚氨酯泡沫或刚性聚异氰脲酸酯泡沫的方法。