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1.发明授权公开(公告)号：US09862892B2
公开(公告)日：2018-01-09
申请号：US14464635
申请日：2014-08-20
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： James J. Strohm , Benjamin Q. Roberts , Tricia D. Smurthwaite , Theresa M. Bergsman , Mark D. Bearden
CPC classification number: C10G15/08 , B01J19/0093 , B01J19/088 , B01J19/126 , B01J2219/00792 , B01J2219/00822 , B01J2219/00826 , B01J2219/00835 , B01J2219/0086 , B01J2219/00941 , B01J2219/0894 , B01J2219/1215 , B01J2219/1227 , B01J2219/1239 , B01J2219/1245 , B01J2219/1269 , B01J2219/1272 , C10G1/002 , C10G29/205 , C10G2300/1033 , C10G2400/02 , C10G2400/04 , C10G2400/08 , H05H1/46 , H05H2001/4622
Abstract: Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RF) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.
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2.发明申请公开(公告)号：US20150165413A1
公开(公告)日：2015-06-18
申请号：US14132262
申请日：2013-12-18
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： James J. Strohm , Benjamin Q. Roberts , Kayte M. Denslow
CPC classification number: C10G45/02 , B01J19/10 , C10G15/08 , C10G31/00 , C10G45/22 , C10G47/02 , C10G47/32 , C10G2300/202
Abstract: Hydroprocessing can be performed at low pressure using acoustic energy. For example, hydroprocessing a feedstock having one or more hydrocarbon compounds carried in, or mixed with, a transport gas involves flowing the feedstock through a reaction zone in a reactor that has a bulk pressure less than 68 atm and applying acoustic energy through the reaction zone. The hydrocarbon compounds are chemically reacted with a hydrogen source in the presence of a catalyst, wherein the reacting occurs in the reaction zone.
Abstract translation: 可以使用声能在低压下进行加氢处理。 例如，加工处理具有一个或多个携带在运输气体中或与运输气体混合的烃化合物的原料包括使原料流过反应器中的反应区，该反应器的体积压力小于68atm，并且通过反应区域施加声能 。 烃化合物在催化剂存在下与氢源化学反应，其中反应发生在反应区中。
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3.发明授权公开(公告)号：US11268036B2
公开(公告)日：2022-03-08
申请号：US15860638
申请日：2018-01-02
Applicant: Battelle Memorial Institute
Inventor： James J. Strohm , Benjamin Q. Roberts , Tricia D. Smurthwaite , Theresa M. Bergsman , Mark D. Bearden
Abstract: Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RE) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.
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4.发明申请Heavy Fossil Hydrocarbon Conversion and Upgrading Using Radio-Frequency or Microwave Energy 有权使用射频或微波能量的重化石烃转化和升级公开(公告)号：US20140353207A1
公开(公告)日：2014-12-04
申请号：US14464635
申请日：2014-08-20
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： James J. Strohm , Benjamin Q. Roberts , Tricia D. Smurthwaite , Theresa M. Bergsman , Mark D. Bearden
IPC: C10G15/08
CPC classification number: C10G15/08 , B01J19/0093 , B01J19/088 , B01J19/126 , B01J2219/00792 , B01J2219/00822 , B01J2219/00826 , B01J2219/00835 , B01J2219/0086 , B01J2219/00941 , B01J2219/0894 , B01J2219/1215 , B01J2219/1227 , B01J2219/1239 , B01J2219/1245 , B01J2219/1269 , B01J2219/1272 , C10G1/002 , C10G29/205 , C10G2300/1033 , C10G2400/02 , C10G2400/04 , C10G2400/08 , H05H1/46 , H05H2001/4622
Abstract: Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RF) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.
Abstract translation: 可以使用微波（MW）和/或射频（RF）能量将重质化石碳氢化合物（HFH）转化为各种增值化学品和/或燃料。 反应物的变化，工艺参数和反应器设计可以显着影响作为产品生成的化学品和燃料的相对分布。 在一个实例中，用于HFH的闪速微波转换的系统包括在具有大于0.9atm的压力的反应区中的源集中微波或RF能量，具有HFH的连续进料和通过反应区的处理气体，HFH- 至少在反应区中与HFH接触的液体催化剂和反应区内的介质放电。 HFH和催化剂在反应区中的停留时间小于30秒。 在一些情况下，等离子体可以形成在反应区或其附近。
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5.发明申请公开(公告)号：US20160257893A1
公开(公告)日：2016-09-08
申请号：US15154870
申请日：2016-05-13
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： James J. Strohm , Benjamin Q. Roberts , Kayte M. Denslow
CPC classification number: C10G45/02 , B01J19/10 , C10G15/08 , C10G31/00 , C10G45/22 , C10G47/02 , C10G47/32 , C10G2300/202
Abstract: Hydroprocessing can be performed at low pressure using acoustic energy. For example, hydroprocessing a feedstock having one or more hydrocarbon compounds carried in, or mixed with, a transport gas involves flowing the feedstock through a reaction zone in a reactor that has a bulk pressure less than 68 atm and applying acoustic energy through the reaction zone. The hydrocarbon compounds are chemically reacted with a hydrogen source in the presence of a catalyst, wherein the reacting occurs in the reaction zone.
Abstract translation: 可以使用声能在低压下进行加氢处理。 例如，加工处理具有一个或多个携带在运输气体中或与运输气体混合的烃化合物的原料包括使原料流过反应器中的反应区，该反应器的体积压力小于68atm，并通过反应区施加声能 。 烃化合物在催化剂存在下与氢源化学反应，其中反应发生在反应区中。
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Patent Agency Ranking
6.发明授权Methods and systems for acoustically-assisted hydroprocessing at low pressure 有权在低压下进行声辅助加氢处理的方法和系统公开(公告)号：US09339785B2
公开(公告)日：2016-05-17
申请号：US14132262
申请日：2013-12-18
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： James J. Strohm , Benjamin Q. Roberts , Kayte M. Denslow
CPC classification number: C10G45/02 , B01J19/10 , C10G15/08 , C10G31/00 , C10G45/22 , C10G47/02 , C10G47/32 , C10G2300/202
Abstract: Hydroprocessing can be performed at low pressure using acoustic energy. For example, hydroprocessing a feedstock having one or more hydrocarbon compounds carried in, or mixed with, a transport gas involves flowing the feedstock through a reaction zone in a reactor that has a bulk pressure less than 68 atm and applying acoustic energy through the reaction zone. The hydrocarbon compounds are chemically reacted with a hydrogen source in the presence of a catalyst, wherein the reacting occurs in the reaction zone.
Abstract translation: 可以使用声能在低压下进行加氢处理。 例如，加工处理具有一个或多个携带在运输气体中或与运输气体混合的烃化合物的原料包括使原料流过反应器中的反应区，该反应器的体积压力小于68atm，并通过反应区施加声能 。 烃化合物在催化剂存在下与氢源化学反应，其中反应发生在反应区中。
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公开(公告)号：US10059890B2
公开(公告)日：2018-08-28
申请号：US15154870
申请日：2016-05-13
Applicant: BATTELLE MEMORIAL INSTITUTE
Inventor： James J. Strohm , Benjamin Q. Roberts , Kayte M. Denslow
CPC classification number: C10G45/02 , B01J19/10 , C10G15/08 , C10G31/00 , C10G45/22 , C10G47/02 , C10G47/32 , C10G2300/202
Abstract: Hydroprocessing can be performed at low pressure using acoustic energy. For example, hydroprocessing a feedstock having one or more hydrocarbon compounds carried in, or mixed with, a transport gas involves flowing the feedstock through a reaction zone in a reactor that has a bulk pressure less than 68 atm and applying acoustic energy through the reaction zone. The hydrocarbon compounds are chemically reacted with a hydrogen source in the presence of a catalyst, wherein the reacting occurs in the reaction zone.
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8.发明申请公开(公告)号：US20180237704A1
公开(公告)日：2018-08-23
申请号：US15860638
申请日：2018-01-02
Applicant: Battelle Memorial Institute
Inventor： James J. Strohm , Benjamin Q. Roberts , Tricia D. Smurthwaite , Theresa M. Bergsman , Mark D. Bearden
IPC: C10G15/08
CPC classification number: C10G15/08 , B01J19/0093 , B01J19/088 , B01J19/126 , B01J2219/00792 , B01J2219/00822 , B01J2219/00826 , B01J2219/00835 , B01J2219/0086 , B01J2219/00941 , B01J2219/0894 , B01J2219/1215 , B01J2219/1227 , B01J2219/1239 , B01J2219/1245 , B01J2219/1269 , B01J2219/1272 , C10G1/002 , C10G29/205 , C10G2300/1033 , C10G2400/02 , C10G2400/04 , C10G2400/08 , H05H1/46 , H05H2001/4622
Abstract: Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RE) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.
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9.发明申请公开(公告)号：US20130253227A1
公开(公告)日：2013-09-26
申请号：US13892143
申请日：2013-05-10
Applicant: Battelle Memorial Institute
Inventor： James J. Strohm , Alan H. Zacher , James F. White , Michel J. Gray , Vanessa Lebarbier
CPC classification number: C07C45/00 , B01J8/001 , B01J21/08 , B01J27/18 , B01J27/1806 , B01J27/1853 , B01J27/285 , B01J38/02 , B01J38/04 , B01J38/06 , B01J38/12 , C07C45/52 , Y02P20/584 , C07C47/22
Abstract: The present disclosure relates to facilities, systems, methods and/or catalysts for use in chemical production. In particular, the disclosure provides innovations relating to dehydration of multihydric compounds such as glycerol to form acrolein. Some of these innovations include continuous reaction systems as well as system parameters that allow for long term production.
Abstract translation: 本公开涉及用于化学生产的设备，系统，方法和/或催化剂。 特别地，本公开提供了与多羟基化合物如甘油的脱水相关的创新以形成丙烯醛。 其中一些创新包括连续反应系统以及允许长期生产的系统参数。
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公开(公告)号：US20180057755A1
公开(公告)日：2018-03-01
申请号：US15715265
申请日：2017-09-26
Applicant: H Quest Partners, LP , Battelle Memorial Institute
Inventor： George L. Skoptsov , James J. Strohm , Benjamin Q. Roberts
CPC classification number: C10G1/06 , B01J19/088 , B01J19/126 , B01J2219/0879 , B01J2219/0894 , B01J2219/1215 , B01J2219/129
Abstract: A system for converting hydrocarbon materials into a product includes a hydrocarbon feedstock source, a process gas source, an energy generator, and a cylindrical reaction chamber. The reaction chamber has a conductive inner surface that forms a resonant cavity. The resonant cavity is configured to support a standing TM010 electromagnetic wave. The reaction chamber is also configured to receive feedstock from the feedstock source, process gas from the process gas source, and convert the feedstock into a product stream in the presence of the TM010 electromagnetic wave.
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