公开(公告)号：US20200024385A1

公开(公告)日：2020-01-23

申请号：US16519777

申请日：2019-07-23

申请人： BOSTIK SA

发明人： Guillaume MICHAUD ,  Frederic SIMON ,  Stephane FOUQUAY ,  Abdou Khadri DIALLO ,  Sophie GUILLAUME ,  Jean-Francois CARPENTIER

IPC分类号： C08G61/08 ,  C08F10/14 ,  C09J123/20 ,  C09J165/00 ,  C09J5/04

摘要： Hydrocarbon-based polymer of formula (1) bearing alkoxysilane end groups: in which: is a double or single bond; each of R2, R3, R4 and R5 is H, a halo, an alkoxycarbonyl or an alkyl, m and p are each from 0 to 5, each of R and R′ is an alkyl, Z is an alkylene, optionally interrupted with COO, q is 0 or 1, r is 0, 1 or 2, and n is an integer such that the number-average molar mass Mn of the polymer is from 400 to 50 000 g/mol, and its polydispersity index (PDI) is from 1.0 to 2.0. Preparation by ring-opening metathesis polymerization for 2 hours to 24 hours.Adhesive composition comprising polymer (1) and crosslinking catalyst. Bonding by assembly of two substrates using this adhesive composition.

公开(公告)号：US20210163671A1

公开(公告)日：2021-06-03

申请号：US17263475

申请日：2019-07-19

申请人： BOSTIK SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE RENNES 1

发明人： Frederic SIMON ,  Stephane FOUQUAY ,  Guillaume MICHAUD ,  Cyril CHAUVEAU ,  Jean-Francois CARPENTIER ,  Sophie GUILLAUME

IPC分类号： C08G18/76 ,  C09J175/16 ,  C08G18/81 ,  C08G18/67 ,  C08G18/48 ,  C08G18/10

摘要： Method for preparing a compound having an alkoxysilyl group of formula (I), wherein X represents —O— or —NR4— with R4═H or C1-C4alkyl; R1 is a radical having from 1 to 20 carbon atoms; R2 and R3 are a C1-C4 alkyl radical; p is an integer equal to 0, 1 or 2; comprising a cross metathesis reaction in the presence (i) of a compound having a group of acrylate type and of formula: —X(C═O)—CH═CH2, (ii) of an α-olefinic silane of formula (II): and (iii) of a metathesis catalyst chosen from GRUBBS catalysts and 2nd generation HOVEYDA-GRUBBS (HG2) catalysts. 2) Compound having said alkoxysilyl group, obtained by the method 1).

公开(公告)号：US20180022864A1

公开(公告)日：2018-01-25

申请号：US15653143

申请日：2017-07-18

申请人： BOSTIK SA ,  Universite de Rennes I ,  Centre National de la Recherche Scientifique

发明人： Guillaume MICHAUD ,  Frederic SIMON ,  Stephane FOUQUAY ,  Elise VANBIERVLIET ,  Sophie GUILLAUME ,  Jean-Francois CARPENTIER

IPC分类号： C08G61/08 ,  C07D263/42

CPC分类号： C08G61/08 ,  B01J2231/54 ,  B01J2531/821 ,  C07D263/42 ,  C08G61/12 ,  C08G69/40 ,  C08G2261/11 ,  C08G2261/12 ,  C08G2261/135 ,  C08G2261/1644 ,  C08G2261/3322 ,  C08G2261/3323 ,  C08G2261/3324 ,  C08G2261/3342 ,  C08G2261/418 ,  C08G2261/724 ,  C08G2261/74 ,  C08G2261/76 ,  C09J165/00 ,  C09J177/06

摘要： F1 is formula (IIa) and F2 is formula (IIb): g and d are 0, 1, 2 or 3; R14 and R15 are C1-C4 or a cyclohexyl radical; R1 to R12 represents hydrogen or alkyl with 1 to 22 carbon atoms; x and y are integers, x+y is 0 to 2; R13 is oxygen or sulphur or divalent —CH2— n1, n2, m, p1 and p2 are an integer or equal to 0 and such that the molecular weight Mn of the polymer of formula (I) is between 400 and 100 000 g/mol; a process for preparation of the polymer; and use as adhesive in mixture with an amino compound with at least two amine groups.

公开(公告)号：US20170088661A1

公开(公告)日：2017-03-30

申请号：US15126911

申请日：2015-03-17

申请人： BOSTIK SA

发明人： Guillaume MICHAUD ,  Marjorie PEREIRA ,  Frederic SIMON

IPC分类号： C08G18/10 ,  C09J175/04 ,  B32B37/12 ,  C08G18/76 ,  C08G18/48 ,  C09J11/04 ,  C08K3/26

摘要： 1) Specific polyurethane prepolymer (PP2) comprising at least two terminal (2-oxo-1,3-dioxolan-4-yl)methyl carbamate groups of low viscosity, its preparation process and its use in the manufacture of an adhesive composition.2) Multicomponent system comprising, as first component (A), a composition comprising at least one such polyurethane prepolymer and, as second component (B), a composition comprising at least one curing agent comprising at least two primary amine (—NH2) groups (B1).3) Process for assembling materials employing the polyurethane prepolymer (PP2) according to the invention.

公开(公告)号：US20160152765A1

公开(公告)日：2016-06-02

申请号：US14906681

申请日：2014-07-22

申请人： BOSTIK SA ,  UNIVERSITE DE RENNES 1

发明人： Guillaume MICHAUD ,  Frederic SIMON ,  Stephane FOUQUAY ,  Abdou Khadri DIALLO ,  Sophie GUILLAUME ,  Jean-Francois CARPENTIER

IPC分类号： C08G61/08 ,  C09J5/04 ,  C09J165/00

CPC分类号： C08G61/08 ,  C08F10/14 ,  C08G2261/135 ,  C08G2261/1644 ,  C08G2261/3322 ,  C08G2261/418 ,  C08G2261/72 ,  C08G2261/724 ,  C08G2261/76 ,  C09J5/04 ,  C09J123/20 ,  C09J165/00

摘要： Hydrocarbon-based polymer of formula (1) bearing alkoxysilane end groups: in which: is a double or single bond; each of R2, R3, R4 and R5 is H, a halo, an alkoxycarbonyl or an alkyl, m and p are each from 0 to 5, each of R and R′ is an alkyl, Z is an alkylene, optionally interrupted with COO, q is 0 or 1, r is 0, 1 or 2, and n is an integer such that the number-average molar mass Mn of the polymer is from 400 to 50 000 g/mol, and its polydispersity index (PDI) is from 1.0 to 2.0. Preparation by ring-opening metathesis polymerization for 2 hours to 24 hours.Adhesive composition comprising polymer (1) and crosslinking catalyst. Bonding by assembly of two substrates using this adhesive composition.

摘要翻译： 含有烷氧基硅烷端基的式（1）的烃基聚合物：其中：是双键或单键; R 2，R 3，R 4和R 5各自为H，卤素，烷氧基羰基或烷基，m和p各自为0至5，R和R'各自为烷基，Z为亚烷基，任选地被COO中断 ，q为0或1，r为0,1或2，n为聚合物的数均摩尔质量Mn为400〜50 000g / mol，多分散指数（PDI）为 从1.0到2.0。 通过开环易位聚合制备2小时至24小时。 包含聚合物（1）和交联催化剂的粘合剂组合物。 使用该粘合剂组合物通过组装两个基材进行粘合。

公开(公告)号：US20200172660A1

公开(公告)日：2020-06-04

申请号：US16615633

申请日：2018-05-22

申请人： BOSTIK SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE RENNES 1

发明人： Guillaume MICHAUD ,  Xiaolu MICHEL ,  Frederic SIMON ,  Stephane FOUQUAY ,  Sophie GUILLAUME ,  Jean-Francois CARPENTIER

IPC分类号： C08G61/02 ,  C09J119/00 ,  C08C19/28

摘要： 1) Hydrocarbon copolymer P comprising 2 alkoxysilane end groups F1 and F2 of formulae: —F1: (R′O)3-tRtSi—(CH2)g1- and F2: —(CH2)d1—SiRt(OR′)3-t; or F1: (R′O)3-tRtSi—R″—O(O)C—(CH2)g2— and F2: —(CH2)d2—C(O)O—R″—SiRt(OR″)3-t; wherein t is 0, 1 or 2; g1 and d1 are 1, 2 or 3; g2 and d2 are 0, 1, 2 or 3; R et R′ represent a C1-C4 alkyl; R″ is a C1-C4 alkylene radical; the main chain comprising motifs (I) and (II) in which R0 is in particular the methyl radical; and the number average molecular mass Mn thereof being between 400 and 100,000 g/mol. 2) Method for producing said copolymer, comprising: (i) a step of heating a statistical bipolymer A selected from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and subsequently (ii) a step of heating the formed product, in the presence of a chain transfer agent of formula (C). 3) Adhesive composition comprising said copolymer.

公开(公告)号：US20170107321A1

公开(公告)日：2017-04-20

申请号：US15127224

申请日：2015-03-17

申请人： BOSTIK SA

发明人： Guillaume MICHAUD ,  Marjorie PEREIRA ,  Frederic SIMON

IPC分类号： C08G18/78 ,  C08G18/18 ,  C08G18/28 ,  C08G18/10 ,  C09J175/04

CPC分类号： C08G18/7837 ,  C08G18/10 ,  C08G18/1808 ,  C08G18/2815 ,  C08G18/284 ,  C08G18/735 ,  C08G71/04 ,  C09J175/04 ,  C09J175/08

摘要： 1) Specific polyurethane prepolymer (PP2) comprising at least two terminal (2-oxo-1,3-dioxolan-4-yl)methyl carbamate groups of low viscosity, its preparation process and its use in the manufacture of an adhesive composition.2) Multicomponent system comprising, as first component (A), a composition comprising at least one such polyurethane prepolymer and, as second component (B), a composition comprising at least one curing agent having at least two primary amine (—NH2) groups (B1).3) Process for assembling materials employing the polyurethane prepolymer (PP2) according to the invention.

公开(公告)号：US20150299390A1

公开(公告)日：2015-10-22

申请号：US14440656

申请日：2013-10-30

申请人： BOSTIK SA

发明人： Guillaume MICHAUD ,  Frederic SIMON ,  Stephane FOUQUAY

IPC分类号： C08G65/331 ,  C08G71/04

CPC分类号： C08G65/331 ,  C08G18/10 ,  C08G18/48 ,  C08G64/30 ,  C08G65/3245 ,  C08G71/04 ,  C08G81/025

摘要： The invention relates to a polymer of formula (I): in which R is a hydrogen or an alkyl having from 1 to 4 carbon atoms; m is a number from 1 to 6; B is a monovalent, divalent, trivalent, tetravalent, pentavalent or hexavalent radical comprising from 1 to 44 carbon atoms per molecule; and n is such that the number-average molar mass Mn of the polymer of formula (I) is from 4000 to 18 000 g/mol and its polydispersity (Pd) is within a range from 1.0 to 1.4.Process for the preparation of the polymer of formula (I).Process for the preparation of polyurethanes comprising the reaction of a polymer of formula (I) with a compound comprising an amine group, and also poly-urethanes capable of being thus obtained.

摘要翻译： 本发明涉及式（I）的聚合物：其中R是氢或具有1至4个碳原子的烷基; m是从1到6的数字; B是每分子含有1至44个碳原子的一价，二价，三价，四价，五价或六价基团; n为式（I）的聚合物的数均摩尔质量Mn为4000〜18000g / mol，多分散性（Pd）为1.0〜1.4的范围。 用于制备式（I）的聚合物的方法。 包括式（I）的聚合物与包含胺基的化合物的反应的聚氨酯的制备方法，以及能够得到的聚氨酯。

公开(公告)号：US20200255587A1

公开(公告)日：2020-08-13

申请号：US16651839

申请日：2018-09-27

申请人： BOSTIK SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE RENNES 1

发明人： Guillaume MICHAUD ,  Stephane FOUQUAY ,  Frederic SIMON ,  Sophie GUILLAUME ,  Jean-Francois CARPENTIER ,  Cyril CHAUVEAU

IPC分类号： C08G61/02 ,  C08G61/12 ,  C09J11/06 ,  C09J165/04

摘要： 1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) in which R0 is notably a methyl radical;and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol.2) Process for preparing said copolymer, comprising:(i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then(ii) a step of heating the product formed, in the presence of a chain-transfer agent.3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

公开(公告)号：US20200208030A1

公开(公告)日：2020-07-02

申请号：US16615927

申请日：2018-05-22

申请人： BOSTIK SA ,  Centre National De La Recherche Scientifique ,  Universite De Rennes 1

发明人： Guillaume MICHAUD ,  Frederic SIMON ,  Stephane FOUQUAY ,  Xiaolu MICHEL ,  Jean-Francois CARPENTIER ,  Sophie GUILLAUME

IPC分类号： C09J165/00 ,  C08G61/08 ,  C08J11/16 ,  C09J5/00

摘要： Hydrocarbon copolymer P comprising 2 alkoxysilane end groups F1 and F2 of formulae: —F1 : (R′O)3-tRtSi—R″—NH—C(O)O—(CH2)g1— and F2: —(CH2)d1—OC(O)—NH—R″—SiRtOR′)3-t; or —F1: (R′O)3-tRtSi—R″—NR′″—C(O)—NH—(CH2)g1— and F2: —(CH2)d1—NH—C(O)—NR′″—R″—SiRt(OR′)3-t; or —F1: (R′O)3-tRtSi—R″—NR′″—C(O)—(CH2)g2— and F2: —(CH2)d2C(O)—NR′″—R″—SiRt(OR′)3-t; wherein t is 0, 1 or 2; g1 and d1 are 1, 2 or 3; g2 and d2 are 0, 1, 2 or 3; R and R′ represent a C1-C4 alkyl; R″ is a C1-C4 alkylene radical; R′″ is method for producing the copolymer, by heating a statistical bipolymer A: poly(butadiene-isoprene), poly(butadiene-myrcene) or poly(butadiene-farnesene); and heating the formed product, in the presence of a chain transfer agent of formula (C) and adhesive composition of the copolymer and a crosslinking catalyst.