公开(公告)号：US10995246B2

公开(公告)日：2021-05-04

申请号：US16310054

申请日：2017-06-05

申请人： BOSTIK SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  UNIVERSITE DE RENNES I

发明人： Boris Colin ,  Guillaume Michaud ,  Frederic Simon ,  Olivier Lavastre

IPC分类号： C09J175/08 ,  C08G18/18 ,  C08G18/22 ,  C08G18/28 ,  C08G18/48 ,  C08G18/71 ,  C09J171/02 ,  C09J183/08 ,  C09J201/10

摘要： The present invention provides a curable adhesive composition comprising at least one curable silylated polymer and at least one curing catalyst obtained by reaction of a metal alkoxide and an oxime. The present invention also provides the use of a metal compound obtained by reaction of a metal alkoxide and an oxime as curing catalyst for silylated polymers.

公开(公告)号：US10118987B2

公开(公告)日：2018-11-06

申请号：US15677153

申请日：2017-08-15

申请人： Bostik SA ,  Universite De Rennes I ,  Centre National De La Recherche Scientifique

发明人： Guillaume Michaud ,  Frederic Simon ,  Stephane Fouquay ,  Elise Vanbiervliet ,  Sophie Guillaume ,  Jean-Francois Carpentier

IPC分类号： C08F24/00 ,  C07D327/04 ,  C08G61/08 ,  C09J165/00 ,  C09J5/00

摘要： 1) Hydrocarbon-based polymer of formula (I): in which F1 and F2 have the respective formulae (IIa) and (IIb) or (II′a) and (II′b): a process for its preparation, and use as an adhesive.

公开(公告)号：US10106645B2

公开(公告)日：2018-10-23

申请号：US15653143

申请日：2017-07-18

申请人： BOSTIK SA ,  Universite de Rennes I ,  Centre National de la Recherche Scientifique

发明人： Guillaume Michaud ,  Frederic Simon ,  Stephane Fouquay ,  Elise Vanbiervliet ,  Sophie Guillaume ,  Jean-Francois Carpentier

IPC分类号： C08F2/00 ,  C08F210/00 ,  C08G61/08 ,  C07D263/42

摘要： 1) Hydrocarbon polymer having two azlactone end groups F1 is formula (IIa) and F2 is formula (IIb): g and d are 0, 1, 2 or 3; R14 and R15 are C1-C4 or a cyclohexyl radical; R1 to R12 represents hydrogen or alkyl with 1 to 22 carbon atoms; x and y are integers, x+y is 0 to 2; R13 is oxygen or sulphur or divalent —CH2— n1, n2, m, p1 and p2 are an integer or equal to 0 and such that the molecular weight Mn of the polymer of formula (I) is between 400 and 100 000 g/mol; a process for preparation of the polymer; and use as adhesive in mixture with an amino compound with at least two amine groups.

公开(公告)号：US11414516B2

公开(公告)日：2022-08-16

申请号：US16651839

申请日：2018-09-27

申请人： BOSTIK SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE RENNES 1

发明人： Guillaume Michaud ,  Stephane Fouquay ,  Frederic Simon ,  Sophie Guillaume ,  Jean-Francois Carpentier ,  Cyril Chauveau

IPC分类号： C08G61/02 ,  C08G61/12 ,  C09J11/06 ,  C09J165/04

摘要： 1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) in which R0 is notably a methyl radical;
and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol.
2) Process for preparing said copolymer, comprising:
(i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then
(ii) a step of heating the product formed, in the presence of a chain-transfer agent.
3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

公开(公告)号：US11279786B2

公开(公告)日：2022-03-22

申请号：US16651710

申请日：2018-09-27

申请人： BOSTIK SA ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE DE RENNES 1

发明人： Guillaume Michaud ,  Stephane Fouquay ,  Frederic Simon ,  Sophie Guillaume ,  Jean-Francois Carpentier ,  Cyril Chauveau

IPC分类号： C08F236/08 ,  C08F236/22 ,  C08G61/04 ,  C09J175/14 ,  C08G71/04

摘要： 1) Hydrocarbon-based copolymer comprising two end groups preceded by an ether function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) in which R0 is notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

公开(公告)号：US10400059B2

公开(公告)日：2019-09-03

申请号：US14906681

申请日：2014-07-22

申请人： BOSTIK SA

发明人： Guillaume Michaud ,  Frederic Simon ,  Stephane Fouquay ,  Abdou Khadri Diallo ,  Sophie Guillaume ,  Jean-Francois Carpentier

IPC分类号： C08G61/08 ,  C08F10/14 ,  C09J123/20 ,  C09J165/00 ,  C09J5/04

摘要： Hydrocarbon-based polymer of formula (1) bearing alkoxysilane end groups: in which: is a double or single bond; each of R2, R3, R4 and R5 is H, a halo, an alkoxycarbonyl or an alkyl, m and p are each from 0 to 5, each of R and R′ is an alkyl, Z is an alkylene, optionally interrupted with COO, q is 0 or 1, r is 0, 1 or 2, and n is an integer such that the number-average molar mass Mn of the polymer is from 400 to 50 000 g/mol, and its polydispersity index (PDI) is from 1.0 to 2.0. Preparation by ring-opening metathesis polymerization for 2 hours to 24 hours. Adhesive composition comprising polymer (1) and crosslinking catalyst. Bonding by assembly of two substrates using this adhesive composition.

公开(公告)号：US10266638B2

公开(公告)日：2019-04-23

申请号：US15127224

申请日：2015-03-17

申请人： BOSTIK SA

发明人： Guillaume Michaud ,  Marjorie Pereira ,  Frederic Simon

IPC分类号： C08G18/78 ,  C08G18/73 ,  C08G18/28 ,  C08G71/04 ,  C09J175/04 ,  C09J175/08 ,  C08G18/10 ,  C08G18/18

摘要： 1) Specific polyurethane prepolymer (PP2) comprising at least two terminal (2-oxo-1,3-dioxolan-4-yl)methyl carbamate groups of low viscosity, its preparation process and its use in the manufacture of an adhesive composition.2) Multicomponent system comprising, as first component (A), a composition comprising at least one such polyurethane prepolymer and, as second component (B), a composition comprising at least one curing agent having at least two primary amine (—NH2) groups (B1).3) Process for assembling materials employing the polyurethane prepolymer (PP2) according to the invention.

公开(公告)号：US20150259470A1

公开(公告)日：2015-09-17

申请号：US14440804

申请日：2013-10-30

申请人： BOSTIK SA

发明人： Guillaume Michaud ,  Frederic Simon ,  Stephane Fouquay ,  Liana Annuziata ,  Sophie Guillaume ,  Jean-Francois Carpentier

IPC分类号： C08G63/91 ,  C08G71/04 ,  C08F8/00

CPC分类号： C08G63/91 ,  C08F8/00 ,  C08G71/04

摘要： A polymer of formula (I): in which P is a divalent polymeric radical other than a polyoxypropylene radical; m is a number from 1 to 6; B is a monovalent, divalent, trivalent, tetravalent, pentavalent or hexavalent radical, having from 1 to 44 carbon atoms per molecule; the divalent polymeric radical P being such that the number-average molar mass Mn of the polymer of formula (I) is in a range from 400 to 8000 g/mol and such that the polydispersity (Pd) of the polymer of formula (I) is within a range from 1.0 to 4.0.Process for preparing the polymer of formula (I).Process for preparing polyurethanes, by reaction of a polymer of formula (I) with a compound, having an amine group, and also polyurethanes that may be thus obtained.

摘要翻译： 式（I）的聚合物：其中P是除聚氧丙烯基以外的二价聚合基团; m是从1到6的数字; B是每分子具有1至44个碳原子的一价，二价，三价，四价，五价或六价基团; 二价聚合基团P使得式（I）的聚合物的数均摩尔质量Mn在400至8000g / mol的范围内，并且使得式（I）的聚合物的多分散性（Pd） 在1.0到4.0的范围内。 制备式（I）的聚合物的方法。 通过式（I）的聚合物与具有胺基的化合物反应制备聚氨酯的方法，以及由此获得的聚氨酯。

公开(公告)号：US10472453B2

公开(公告)日：2019-11-12

申请号：US15126911

申请日：2015-03-17

申请人： BOSTIK SA

发明人： Guillaume Michaud ,  Marjorie Pereira ,  Frederic Simon

IPC分类号： C08G18/10 ,  C08G18/69 ,  C08G71/04 ,  C08G18/48 ,  C09J175/08 ,  B32B37/12 ,  C08G18/76 ,  C08K3/26 ,  C09J11/04 ,  C09J175/04

摘要： 1) Specific polyurethane prepolymer (PP2) comprising at least two terminal (2-oxo-1,3-dioxolan-4-yl)methyl carbamate groups of low viscosity, its preparation process and its use in the manufacture of an adhesive composition.2) Multicomponent system comprising, as first component (A), a composition comprising at least one such polyurethane prepolymer and, as second component (B), a composition comprising at least one curing agent comprising at least two primary amine (—NH2) groups (B1).3) Process for assembling materials employing the polyurethane prepolymer (PP2) according to the invention.

公开(公告)号：US09359459B2

公开(公告)日：2016-06-07

申请号：US14651798

申请日：2013-12-13

申请人： BOSTIK SA

发明人： Guillaume Michaud ,  Frederic Simon ,  Stephane Fouquay ,  Liana Annunziata ,  Sophie Guillaume ,  Jean Francois Carpentier

IPC分类号： C08F132/04 ,  C08G61/08 ,  C08G71/04 ,  C08F8/14 ,  C08F8/04

CPC分类号： C08F132/04 ,  C08F8/14 ,  C08G61/08 ,  C08G71/04 ,  C08G2261/126 ,  C08G2261/1644 ,  C08G2261/3322 ,  C08G2261/418 ,  C08G2261/74

摘要： Process for the preparation of a hydrocarbon polymer comprising two end groups having 2-oxo-1,3-dioxolan-4-yl final parts by ring opening metathesis in the presence of a metathesis catalyst, of a chain transfer agent comprising a carbonate ring and of a compound of formula comprising at least one C6-C16 ring having a carbon-carbon double bond.Hydrocarbon polymer capable of being obtained by this process.Process for the preparation of polyurethanes by reaction of this polymer and of a compound comprising at least one amine group, and polyurethanes thus obtained.