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公开(公告)号：US20240344785A1
公开(公告)日：2024-10-17
申请号：US18682842
申请日：2022-08-10
Applicant: Basell Polyolefine GMBH
Inventor： Antonio Ling , Andrei Gonioukh
CPC classification number: F28F19/06 , C10G9/002 , C10G9/16 , C10G9/18 , C23C4/06 , F28D21/00 , F28F9/18 , F28D2021/0022 , F28D2021/0059 , F28D2021/0075 , F28F2265/16
Abstract: The present disclosure refers to transfer line exchangers with improved cooling capacity, equipped with a thermal spray coating in crackers and a method for the maintenance of transfer line exchangers with the help of a thermal spray coating. In some embodiments, the thermal spray coating is obtained from a spray material formed of Cr3C2 and a NiCr alloy. Preferably, the spray coating material comprises at least 60 wt.-%, preferably at least 70 wt.-% of Cr3C2, based on the total weight of the spray material.
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公开(公告)号：US10472428B2
公开(公告)日：2019-11-12
申请号：US16300177
申请日：2017-05-09
Applicant: Basell Polyolefine GmbH
Inventor： Andrei Gonioukh , Thomas Herrmann , Dieter Littmann , Andre-Armand Finette , Siegfried Mischok
Abstract: A process for polymerizing or copolymerizing ethylenically unsaturated monomers at pressures in the range of from 110 MPa to 500 MPa in a production line comprising a continuously operated polymerization reactor which is installed within a protective enclosure, wherein the production line is monitored with respect to an occurrence of a leakage of monomers or of reaction mixture and a water based deluge system, which provides droplets of a diameter in a range from 25 μm to 20 mm to the enclosed area, is automatically started with a minimum flow rate of 10 L/min per m2 of enclosed area when a leakage of monomers or of reaction mixture is detected.
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公开(公告)号：US10308738B2
公开(公告)日：2019-06-04
申请号：US15579882
申请日：2016-06-14
Applicant: Basell Polyolefine GmbH
Inventor： Christoph Wolf , Andre-Armand Finette , Andrei Gonioukh , Dieter Littmann , Thomas Herrmann , Georg Groos
IPC: C08F110/02 , C08F2/04 , B01J19/24
Abstract: The present disclosure relates to a plant for performing polymerization, such as the polymerization of ethylene, having a recycle connection with two or more cooling channels arranged in parallel, a process for polymerization and downstream processes, and a plant for polymerization, comprising the following plant components in fluid communication: a) A reactor with an inlet side and an outlet side; b) A recycle connection positioned in fluid communication between the outlet side of the reactor and the inlet side of the reactor; wherein the recycle connection comprises two or more cooling channels arranged in parallel.
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公开(公告)号：US20170218103A1
公开(公告)日：2017-08-03
申请号：US15514788
申请日：2015-09-09
Applicant: BASELL POLYOLEFINE GMBH
Inventor： Sabastian Weiand , Andrei Gonioukh , Stephan Schmitz , Andre-Armand Finette , Guido Bürger , Guido Küpper , Thomas Herrmann , Iakovos Vittorias , Dieter Lilge , Gerd Mannebach
IPC: C08F210/02 , C09D123/08 , B05D1/26
CPC classification number: C08F210/02 , B05D1/265 , B32B27/10 , B32B27/306 , B32B27/308 , B32B27/32 , B32B2270/00 , B32B2307/72 , C08F2500/08 , C09D123/08 , C08F110/02 , C08F2500/04 , C08F2500/09 , C08F2500/12 , C08F2500/26 , C08F4/28 , C08F2/38
Abstract: The present disclosure provides a low density polyethylene (LDPE) having (A) a density from 0.910 to 0.924 g/cm3, determined according to ISO 1183 at 23° C.; (B) an elongational hardening of at least 4.2, at 150° C. at an elongational rate of 1 s−1; (C) a ratio Mw/Mn of at least 18, where (i) Mw is the weight average molar mass, measured by a MALLS detector coupled to a GPC, and (ii) Mn is the number average molar mass, measured by GPC (Gel Permeation Chromatography); and (D) a Mw of at least 230,000 g/mol. The present disclosure also provides an article of manufacture made from or containing (A) a substrate and (B) a coating layer made from or containing the disclosed LDPE. The present disclosure further provides a polymerization process occurring (A) in the presence of oxygen as the only radical initiating agent and (B) in the absence of solvents.
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公开(公告)号：US09908950B2
公开(公告)日：2018-03-06
申请号：US15550256
申请日：2016-02-22
Applicant: Basell Polyolefine GmbH
Inventor： Sven Wolfram , Andre-Armand Finette , Udo Backes , Andrei Gonioukh , Hicran Cabuk
CPC classification number: C08F2/01 , B01J19/0006 , B01J19/2415 , B01J2219/00051 , B01J2219/00065 , B01J2219/00211 , B01J2219/00337 , C08F210/02 , G01L19/0092
Abstract: A process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out at temperatures from 100° C. to 350° C. and pressures in the range of from 110 MPa to 500 MPa in a continuously operated polymerization reactor which is controlled by a pressure control valve at the outlet of the polymerization reactor, the process comprising continuously monitoring the pressure within the polymerization reactor, feeding a pressure signal to a controller for controlling the control valve and having the controller altering the opening of the pressure control valve to control the pressure within the polymerization reactor, wherein the controller starts an emergency shutdown program when the pressure control valve closes more than a preset threshold value and the pressure within the polymerization reactor decreases below a preset pressure threshold.
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Patent Agency Ranking
公开(公告)号：US20180030160A1
公开(公告)日：2018-02-01
申请号：US15550256
申请日：2016-02-22
Applicant: Basell Polyolefine GmbH
Inventor： Sven Wolfram , Andre-Armand Finette , Udo Backes , Andrei Gonioukh , Hicran Cabuk
IPC: C08F2/01 , G01L19/00 , B01J19/00 , C08F210/02 , B01J19/24
CPC classification number: C08F2/01 , B01J19/0006 , B01J19/2415 , B01J2219/00051 , B01J2219/00065 , B01J2219/00211 , B01J2219/00337 , C08F210/02 , G01L19/0092
Abstract: A process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out at temperatures from 100° C. to 350° C. and pressures in the range of from 110 MPa to 500 MPa in a continuously operated polymerization reactor which is controlled by a pressure control valve at the outlet of the polymerization reactor, the process comprising continuously monitoring the pressure within the polymerization reactor, feeding a pressure signal to a controller for controlling the control valve and having the controller altering the opening of the pressure control valve to control the pressure within the polymerization reactor, wherein the controller starts an emergency shutdown program when the pressure control valve closes more than a preset threshold value and the pressure within the polymerization reactor decreases below a preset pressure threshold.
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公开(公告)号：US10364306B2
公开(公告)日：2019-07-30
申请号：US15514788
申请日：2015-09-09
Applicant: Basell Polyolefine GmbH
Inventor： Sebastian Weiand , Andrei Gonioukh , Stephan Schmitz , Andre-Armand Finette , Guido Bürger , Guido Küpper , Thomas Herrmann , Iakovos Vittorias , Dieter Lilge , Gerd Mannebach
IPC: C08L23/06 , C08F210/02 , B05D1/26 , B32B27/32 , B32B27/10 , B32B27/30 , C09D123/08
Abstract: The present disclosure provides a low density polyethylene (LDPE) having (A) a density from 0.910 to 0.924 g/cm3, determined according to ISO 1183 at 23° C.; (B) an elongational hardening of at least 4.2, at 150° C. at an elongational rate of 1 s−1; (C) a ratio Mw/Mn of at least 18, where (i) Mw is the weight average molar mass, measured by a MALLS detector coupled to a GPC, and (ii) Mn is the number average molar mass, measured by GPC (Gel Permeation Chromatography); and (D) a Mw of at least 230,000 g/mol. The present disclosure also provides an article of manufacture made from or containing (A) a substrate and (B) a coating layer made from or containing the disclosed LDPE. The present disclosure further provides a polymerization process occurring (A) in the presence of oxygen as the only radical initiating agent and (B) in the absence of solvents.
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公开(公告)号：US10358510B2
公开(公告)日：2019-07-23
申请号：US16300147
申请日：2017-05-09
Applicant: Basell Polyolefine GmbH
Inventor： Andrei Gonioukh , Thomas Herrmann , Dieter Littmann , Andre-Armand Finette , Sven Wolfram
Abstract: A process for polymerizing or copolymerizing ethylenically unsaturated monomers at pressures in the range of from 110 MPa to 500 MPa in a production line comprising a continuously operated polymerization reactor, wherein at least one of a pre-heater or pre-cooler, a polymerization reactor or a post reactor cooler is composed of tubes of a length from 5 m to 25 m which are flanged together, either directly or via bends, and the flanges are covered by a chimney construction, and wherein air is conveyed through the chimney construction and the air exiting the chimney construction is monitored with respect to the hydrocarbons concentration.
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公开(公告)号：US20190177447A1
公开(公告)日：2019-06-13
申请号：US16300147
申请日：2017-05-09
Applicant: Basell Polyolefine GmbH
Inventor： Andrei Gonioukh , Thomas Herrmann , Dieter Littmann , Andre-Armand Finette , Sven Wolfram
CPC classification number: C08F10/02 , B01J19/0013 , B01J19/002 , B01J19/06 , B01J19/2415 , B01J2219/00033 , B01J2219/00092 , B01J2219/00256 , C08F2/01 , C08F2/34
Abstract: A process for polymerizing or copolymerizing ethylenically unsaturated monomers at pressures in the range of from 110 MPa to 500 MPa in a production line comprising a continuously operated polymerization reactor, wherein at least one of a pre-heater or pre-cooler, a polymerization reactor or a post reactor cooler is composed of tubes of a length from 5 m to 25 m which are flanged together, either directly or via bends, and the flanges are covered by a chimney construction, and wherein air is conveyed through the chimney construction and the air exiting the chimney construction is monitored with respect to the hydrocarbons concentration.
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公开(公告)号：US20190169318A1
公开(公告)日：2019-06-06
申请号：US16300177
申请日：2017-05-09
Applicant: Basell Polyolefine GmbH
Inventor： Andrei Gonioukh , Thomas Herrmann , Dieter Littmann , Andre-Armand Finette , Siegfried Mischok
Abstract: A process for polymerizing or copolymerizing ethylenically unsaturated monomers at pressures in the range of from 110 MPa to 500 MPa in a production line comprising a continuously operated polymerization reactor which is installed within a protective enclosure, wherein the production line is monitored with respect to an occurrence of a leakage of monomers or of reaction mixture and a water based deluge system, which provides droplets of a diameter in a range from 25 μm to 20 mm to the enclosed area, is automatically started with a minimum flow rate of 10 L/min per m2 of enclosed area when a leakage of monomers or of reaction mixture is detected.
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