摘要:
The present invention relates to a process for the preparation of polyurethane ureas from relatively high molecular weight polyols, diisocyanates, water as chain lengthening agent and optionally short chain glycols in a multishaft extruder equipped with kneading elements.
摘要:
The instant invention is directed to a continuous process for the production of thermoplastic polyurethanes by reactingA. one or more substantially linear polyols having molecular weights in the range from 400 to 10,000,B. one or more organic diisocyanates andC. a hydroxyl-group-containing chain extender having a molecular weight below 250,the ratio of the NCO-groups in component (B) to the Zerewitinoff-active groups in components (A) and (C) lying between 0.90 and 1.2, in extruders, characterized in that the chain extender (C) used is a mixture of at least two different glycols, of which one is present in a quantity of from 50 to 99% by weight, based on the total amount of component (C), and a second in a quantity of from 1 to 50% by weight, based on the total amount of component (C).
摘要:
The instant invention is directed to a continuous process for the production of thermoplastic materials, comprising:I. introducing 4 to 65 parts by weight of thermoplastic polymer into an extruder at a first inlet, wherein the temperature within said extruder is such that said thermoplastic polymer melts;II. adding to said thermoplastic polymer through a second inlet 35 to 96 parts by weight of the following polyurethane forming components, such that the total parts by weight of thermoplastic polymer and polyurethane components is 100:(A) organic polyisocyanate; and(B) chain lengthening agent with a molecular weight below 400 containing a hydroxyl group and/or amine group;wherein the ratio of isocyanate groups of component (A) to Zerewitinoff active groups of component (B) is in the range of from 0.90:1 to 1.2:1; andIII. discharging from the extruder the product of the process when the reaction of said polyurethane components (A) and (B) is substantially complete.
摘要:
The present invention is directed to a process for the production of matte, non-blocking, thin-walled molded articles, films or tubes from polyurethane elastomers prepared from high molecular weight polyols which contain dispersed polyadducts based on polyisocyanate polyaddition products. The use of these high molecular weight polyols contained dispersed polyadducts allows for the preparation of thin-walled, molded articles which have reduced surface tackiness. The present invention is additionally directed to the molded articles produced by this process and to their use for forming polyurethane foam composites.
摘要:
The invention is directed to a process extruding or melt roll calendering thermoplastic polyurethanes wherein the polyurethanes used are synthesized from p1 (a) one or more relatively high molecular weight substantially linear polyols having molecular weights in the range from 400 to 10,000(b) diphenyl methane and/or hexamethylene diisocyanate and(c) a mixture of 85 to 99% by weight of 1,4-butane diol and 1 to 15% by weight of at least one co-extender selected from the group consisting of ethylene glycol, diethylene glycol, triethylene glycol, diethylene 1,2-propane diol, 1,3-butane diol, 1,6-hexane diol, 2-ethyl-1,3-hexane diol, 2,2-dimethyl-1,3-propane diol, 1,4-bis-hydroxymethyl cyclohexane, hydroquinone-bis-hydroxyethyl ether, and mixtures thereof, the equivalent ratio of NCO groups in component (B) to the Zerewitinoff-active hydrogen atoms in components (A) and (C) being from 0.9:1 to 1.2:1 and the molar ratio of component (A) to (C) being from 1:20 to 5:1.
摘要:
The instant invention is directed to a process for the modification of a thermoplastic polymer comprising:I. introducing 70 to 98 parts by weight of thermoplastic polymer into an extruder at a first inlet;II. adding to said thermoplastic polymer through a second inlet 2 to 30 parts by weight of the following polyurethane forming components, such that the total parts by weight of the thermoplastic polymer and polyurethane components is 100:(A) organic polyisocyanate; and(B) chain lengthening agent with a molecular weight below 400 containing at least one hydroxyl group and/or amino group; wherein the ratio of isocyanate groups of component (A) to Zerewitinoff active groups of component (B) is in the range of from 0.90:1 to 1.2:1; andIII. discharging from the extruder the product of the process.
摘要:
The present invention relates to an improved continuous process for the preparation of polyurethane elastomers which are distinguished from the products produced by known processes by increased elasticity, reduced shrinkage, higher rigidity (limit bending stress), improved cold notched bar impact resistance and good thermal stability.
摘要:
The present disclosure is concerned with an improved method of reverse coating textile sheets with storage stable polyurethane top and adhesive coats which are formulated to have improved resistance to deformation under heat and pressure. At least one of the coats is formulated from a diisocyanate, a high molecular weight dihydroxy compound and a mixture of at least one low molecular weight diol with a low molecular weight monoalkanolamine. The coatings are applied in the usual reverse coating manner, i.e. the top coat is applied to a release substrate from solution; dried; the adhesive coat is applied from solution onto the dried top coat; and the textile substrate is laminated to the adhesive coat.
摘要:
A process for the continuous glycolytic cleavage of polyurethane plastics waste in multi-shaft screw machines by the addition of optionally preheated diols, at a degradation temperature of 250.degree. C., while maintaining a pressure at least such that the polyurethane-diol mixture is in the liquid phase, by the discharge of the glycolysate mixture after short residence times of from 2 to 30 minutes in the reaction screw, and by rapid cooling of the glycolysate mixture.
摘要:
The instant invention is directed to a process for the separation of polyurethane hydrolysates into polyamines and polyols which can be used again for the production of polyurethanes, comprising introducing gaseous hydrogen chloride into the hydrolysate mixture which has optionally been diluted with an inert solvent, and removing the precipitated amine salt by filtration, characterized in that(a) gaseous hydrogen chloride is optionally first introduced into the hydrolysate in a quantity of from 0.02 to 0.07 mol per amine equivalent, the reaction mixture is filtered and the filter residue is discarded, then(b) from 0.20 to 0.47 mol of gaseous hydrogen chloride per mol of amine equivalents still present is introduced into the filtrate and the precipitated amine salt is filtered off, then(c) stage (b) is repeated one or more times until the amine group content in the filtrate is below 1% by weight, based on the solvent-free filtrate, and finally(d) precipitation of the amine is completed by the introduction of from 0.5 to 1.0 mol of gaseous hydrogen chloride, based on the amine equivalents remaining in the filtrate.