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19 条记录 (耗时 0.018 秒)

    Process for obtaining hydrogen and oxygen from water
    1.
    发明授权
    Process for obtaining hydrogen and oxygen from water 失效
    从水中获得氢和氧的方法

    公开(公告)号：US4544459A

    公开(公告)日：1985-10-01

    申请号：US629706

    申请日：1984-07-11

    申请人： Bernd-Dieter Struck ,  Bernd Biallas ,  Rudolf Schulten

    发明人： Bernd-Dieter Struck ,  Bernd Biallas ,  Rudolf Schulten

    IPC分类号： C25B1/02 ,  C25B1/10 ,  C25B1/22 ,  C25B1/24

    CPC分类号： C25B1/10 ,  C25B1/02 ,  C25B1/22 ,  Y02E60/366

    摘要： A process for obtaining hydrogen and oxygen from water in a two stage process including a first electrolysis stage performed in a two chamber cell wherein the chambers are separated by a membrane. Iodine is introduced into the cathodic chamber and hydrogen iodide is formed therein. Oxygen is formed in the anodic chamber and is removed as a product. The membrane conducts hydrogen ions and prevents the passage of the products HI and oxygen. In a second phase, hydrogen iodide is separated and removed from the cathodic chamber and is thermally decomposed into hydrogen and iodine. The iodine is recycled to the cathodic chamber and the hydrogen is recovered as a product.

    摘要翻译： 一种在两级方法中从水中获得氢和氧的方法，包括在两室单元中执行的第一电解阶段，其中室由膜分离。 将碘引入阴极室，并在其中形成碘化氢。 在阳极室中形成氧并作为产品除去。 膜传导氢离子并防止产物HI和氧的通过。 在第二阶段，将碘化氢从阴极室中分离并除去，并被热分解成氢和碘。 将碘循环到阴极室中，氢气作为产物回收。

    Process for obtaining hydrogen and oxygen from water
    2.
    发明授权
    Process for obtaining hydrogen and oxygen from water 失效
    从水中获取氢和氧的方法

    公开(公告)号：US4011305A

    公开(公告)日：1977-03-08

    申请号：US512797

    申请日：1974-10-04

    申请人： Rudolf Schulten ,  Karl Friedrich Knoche

    发明人： Rudolf Schulten ,  Karl Friedrich Knoche

    IPC分类号： C01B3/06 ,  C01B3/10 ,  C01B13/02 ,  C01G49/08

    CPC分类号： C01B3/105 ,  C01B13/0207 ,  C01B3/063 ,  C01G49/08 ,  Y02E60/36

    摘要： A process for the dissociation of water into hydrogen and oxygen in a multi-stage closed cycle process using a system involving at least one metallic element having multiple valency and at least one halogen, characterized in that a halide of the multiple valency metallic element is subjected to a mixture of steam and hydrogen converting the halide to a mixture of the metallic element and at least one oxide thereof, said latter mixture is subjected to steam to produce a mixed valency oxide of the metallic element accompanied by the liberation of hydrogen, and said mixed valency oxide is then subjected to a hydrogen halide to convert it back to the said metallic halide with the liberation of oxygen.

    Process for tempering the surface of a body
    3.
    发明授权
    Process for tempering the surface of a body 失效
    回火身体表面的过程

    公开(公告)号：US5318799A

    公开(公告)日：1994-06-07

    申请号：US12596

    申请日：1993-02-03

    申请人： Rudolf Schulten ,  Behzad Sahabi ,  Harald Lorson ,  Kusnanto ,  Antonio M. Hurtado

    发明人： Rudolf Schulten ,  Behzad Sahabi ,  Harald Lorson ,  Kusnanto ,  Antonio M. Hurtado

    IPC分类号： C04B41/89 ,  C04B41/45 ,  C04B41/91 ,  C23C10/28 ,  C23C10/44 ,  C23C10/48 ,  C23C10/50 ,  C23C10/52 ,  C23C10/60 ,  B05D3/02

    CPC分类号： C23C10/50 ,  C04B41/4523 ,  C23C10/52 ,  C23C10/60

    摘要： For tempering the surface of a body, the body is covered with a sheath of at least one meltable active substance and binder material and heated under vacuum or in an inert atmosphere first to a temperature whereby the sheath is transformed into a porous cover layer with outer crust. Then the temperature is raised until the meltable active substance contained in the cover layer is evaporated. On the one hand, the meltable active substance seals the outer side of the cover layer, and on the other hand, the meltable active substance produces the tempered surface of the body. After the body has cooled, the residues of the cover layer are removed. The body is provided with a pore-free resistant surface.

    摘要翻译： 为了回火身体的表面，身体被至少一种可熔化活性物质和粘合剂材料的护套覆盖，并且在真空下或在惰性气氛中首先被加热到一个温度，由此护套被转变成具有外部的多孔覆盖层 脆皮。 然后升高温度直到包含在覆盖层中的可熔融活性物质蒸发。 一方面，可熔融活性物质密封着覆盖层的外侧，另一方面，可熔融活性物质产生了本体的回火表面。 身体冷却后，覆盖层的残留物被去除。 身体设有无孔的抗磨面。

    Process for producing a shaped body of graphite
    4.
    发明授权
    Process for producing a shaped body of graphite 失效
    生产形成石墨体的方法

    公开(公告)号：US5236638A

    公开(公告)日：1993-08-17

    申请号：US931699

    申请日：1992-08-18

    申请人： Rudolf Schulten ,  Behzad Sahabi

    发明人： Rudolf Schulten ,  Behzad Sahabi

    IPC分类号： C04B41/50 ,  C04B41/87

    CPC分类号： C04B41/009 ,  C04B41/5059 ,  C04B41/87

    摘要： For the production of a shaped body of graphite with a reaction-bound Si/SiC coating it is proposed to bring the shaped body--provided with a slip layer of a homogenized mixture, heated and gassed under vacuum with gaseous silicon or impregnated with liquid silicon--to a form of predetermined dimensions. To this end the shaped body is treated after the coating by cutting or brushing or by electronically controlled laser erosion or by several of these measures.

    摘要翻译： 为了生产具有反应结合的Si / SiC涂层的成形体的石墨，建议使具有均匀化混合物的滑动层的成形体带有气态硅或真空浸渍或用液态硅浸渍 到预定尺寸的形式。 为此，通过切割或刷涂或通过电子控制的激光侵蚀或通过这些措施中的几种来对被成形体进行处理。

    Diffusion membrane and process for separating hydrogen from gas mixture
    5.
    发明授权
    Diffusion membrane and process for separating hydrogen from gas mixture 失效
    扩散膜和从气体混合物中分离氢气的方法

    公开(公告)号：US4496373A

    公开(公告)日：1985-01-29

    申请号：US617831

    申请日：1984-06-06

    申请人： Friedrich Behr ,  Rudolf Schulten ,  Walter Weirich

    发明人： Friedrich Behr ,  Rudolf Schulten ,  Walter Weirich

    IPC分类号： B01D53/22 ,  B01D59/14 ,  C01B3/50

    CPC分类号： B01D59/14 ,  B01D53/22 ,  B01D71/022 ,  C01B3/505

    摘要： For separation of hydrogen and its isotopes by diffusion through a membraneirtually impermeable to other gases, a non-porous hydrogen-permeable metallic membrane is provided on the gas access side with a coating of an alloy of palladium with at least 45 atomic % Cu or at least 50 atomic percent Ag or at least 7 atomic % Y, the membrane itself containing Cu, Ag or Y respectively in a concentration at least equilibrated with the coating at operation temperature. Preferably the membrane consists of a metal of niobium and/or tantalum bases especially of an alloy containing from 10 to 30 % Ti, 3 to 10 % V, 0 to 25 % Nb and at least 30 % Ta, all by weight, and preferably it is of a composition of 20 to 25 % Ti, 5 to 7,5 % V, 0 to 25 Nb, and at least 50 % Ta, being saturated with copper and or silver, while a copper and/or silver palladium alloy coating is used. Such inherently oxidation sensitive membranes can be stabilized by provision of an internal intermediate layer in the form of a melt forming or containing an alkaline metal hydride and/or an alkaline earth metal hydride. A melt containing alkaline metal and/or alkaline earth metal which forms a hydride, brought into contact on the secondary side of a membrane in accordance with the invention, provides a hydrogen sink on the secondary side and inhibits internal hydride formation and secondary side oxidation of the membrane.

    摘要翻译： 为了通过扩散通过实际上不可渗透到其它气体的膜来分离氢及其同位素，在气体存取侧上提供具有至少45原子％Cu的钯合金涂层的无孔氢可渗透金属膜，或 至少50原子％Ag或至少7原子％Y，膜本身分别含有在操作温度下至少与涂层平衡的浓度的Cu，Ag或Y。 优选地，该膜由铌和/或钽基的金属组成，特别是含有10至30％Ti，3至10％V，0至25％Nb和至少30％Ta的合金，全部重量，优选 其组成为20至25％Ti，5至7.5％V，0至25Nb，以及至少50％的Ta，被铜或银饱和，而铜和/或银钯合金涂层 用来。 这种固有的氧化敏感膜可以通过提供形成熔体或含有碱金属氢化物和/或碱土金属氢化物形式的内部中间层来稳定化。 包含碱金属和/或碱土金属的熔体，其形成根据本发明的膜的次级侧上接触的氢化物，其在次级侧上提供氢吸收剂，并且抑制内部氢化物形成和二次侧氧化 膜。

    Thermoelectric generator with nuclear heat source
    7.
    发明授权
    Thermoelectric generator with nuclear heat source 失效
    具有核热源的热电发生器

    公开(公告)号：US4830817A

    公开(公告)日：1989-05-16

    申请号：US113282

    申请日：1987-08-04

    申请人： Rudolf Schulten

    发明人： Rudolf Schulten

    IPC分类号： G21D7/04

    CPC分类号： G21D7/04

    摘要： A thermoelectric generator has a cylindrical high temperature reactor as a heat source. A carbon-fiber reinforced graphite lattice structure supports a multiplicity of thermoelectric units which surround and receive heat from the core of the reactor. The reactor core is composed of fuel rods made of graphite in which nuclear fuel particles are embedded. The central portion of the core contains reflector elements. Power regulation is provided by control rods that are insertable into the core in openings among the fuel rods.

    摘要翻译： PCT No.PCT / DE86 / 00496 Sec。 371日期1987年8月4日 102（e）日期1987年8月4日PCT提交1986年12月4日PCT公布。 公开号WO87 / 03733 日期：1987年6月18日。热电发生器具有圆柱形高温反应器作为热源。 碳纤维增强石墨晶格结构支持多个热电单元，其围绕并接收来自反应器芯的热量。 反应堆堆芯由埋入核燃料颗粒的石墨燃料棒组成。 芯的中心部分包​​含反射器元件。 功率调节由控制棒提供，该控制杆可插入到燃料棒之间的开口中的芯中。

    Process for the preparation of sulfuric acid from sulphur dioxide
    9.
    发明授权
    Process for the preparation of sulfuric acid from sulphur dioxide 失效
    从二氧化硫制备硫酸的方法

    公开(公告)号：US4059496A

    公开(公告)日：1977-11-22

    申请号：US724290

    申请日：1976-09-20

    申请人： Rudolf Schulten ,  Friedrich Behr

    发明人： Rudolf Schulten ,  Friedrich Behr

    IPC分类号： C01B17/74 ,  C25B1/22 ,  C25B1/02

    CPC分类号： C25B1/22 ,  C01B17/74 ,  Y02P20/132

    摘要： In a process for the electrolytic production of sulfuric acid by oxidation of sulfur dioxide in the presence of water in an anode compartment of an electrolysis cell and of hydrogen in the cathode compartment of the cell, the cathode compartment containing aqueous sulfuric acid as catholyte and being separated from the anode compartment by a hydrogen-ion transfer permitting membrane, the improvement which comprises introducing sulfur dioxide, water and hydrogen iodide or iodine, removing a mixture of aqueous sulfuric acid and hydrogen iodide from the anode compartment, separating the sulfuric acid from the mixture, and removing from the cathode compartment the hydrogen set free therein. The process gives a substantially lower overvoltage than prior art processes.

    摘要翻译： 在电解池的阳极室中的水存在下通过二氧化硫的氧化和电池的阴极室中的氢的电解生产硫酸的方法中，阴极室含有硫酸水溶液作为阴极电解液， 通过氢离子转移允许膜与阳极室分离，其改进包括引入二氧化硫，水和碘化氢或碘，从阳极室除去硫酸和碘化氢的混合物，将硫酸从 混合物，并从阴极室除去其中没有的氢。 该方法给出比现有技术方法显着更低的过电压。