摘要:
Methods and devices for enhanced energy storage in an electrochemical cell are provided. In some embodiments, an electrode for use in a metal-air electrochemical cell can include a plurality of nanofiber (NF) structures having high porosity, tunable mass, and tunable thickness. The NF structures are particularly suited for energy storage and can provide the electrode with exceptionally high gravimetric capacity and energy density when used in an electrochemical cell.
摘要:
A self-supporting carbon electrode can include, or consist essentially of, nanostructured carbon, for example, oxygen-functionalized nanostructured carbon.
摘要:
Integrated polymeric-ceramic membrane-based oxy-fuel combustor. The combustor includes a polymer membrane structure for receiving air at an input and for delivering oxygen-enriched air at an outlet. An oxygen transport reactor including a ceramic ion transport membrane receives the oxygen-enriched air from the polymer membrane structure to generate oxygen for combustion with a fuel introduced into the oxygen transport reactor.
摘要:
The oxygen evolution reaction (OER)-catalyzing activity of transition metal perovskite oxide catalysts depends on the occupancy of the σ-bonding orbital of eg symmetry parentage of the active cation. Catalysts having preferred values of eg orbital filling can have a high intrinsic activity for catalysis of the OER.
摘要:
A self-supporting carbon electrode can include, or consist essentially of, nanostructured carbon, for example, oxygen-functionalized nanostructured carbon.
摘要:
The present invention relates to single chamber fuel cells and systems and methods associated with the same. Architectures and materials that allow for high performance, enhanced fuel utilization, mechanical robustness, and mechanical flexibility are described. In some embodiments, multiple fuel cell units are arranged in a single chamber and may be, in some cases, connected to each other (e.g., connected in series, connected in parallel, etc.). Each fuel cell unit can be defined as one or more anode(s), one or more cathode(s), and an electrolyte able to maintain electrical separation between the anode(s) and cathode(s). The multiple fuel cell units are arranged in stacks in some cases. In one set of embodiments, the stacks of fuel cell units can be shaped and/or arranged to enhance the mixing of fuel and oxidant, thus improving distribution of reactants in the reaction zone. For example, the stacks of fuel cells may be arranged as fins within the fuel cell chamber. In addition, the stacks of fuel cells may be porous in some instances. In addition, the stacks of fuel cell units may be arranged to enhance other fluid flow parameters (e.g., residence time, reactant distribution, etc.). In some cases, the enhanced fluid flow may lead to increased fuel utilization and system efficiency.
摘要:
Fiber structures that include a catalytic material are provided. The fiber structures (e.g., membranes) may be formed of interconnected carbon fibers. The catalytic material may be in the form of nanosize particles supported on the fibers. In one method of the invention, the structures are produced by electrospinning a polymeric material fiber structure that is subsequently converted to a carbon fiber structure in a heat treatment step which also causes the catalytic material particles to nucleate on the carbon fibers and grow to a desired size. The catalytic material may be uniformly distributed across the carbon fiber structure and the amount of catalytic material may be controlled. These factors may enhance catalytic performance and/or enable using less catalytic material for equivalent catalytic performance which can lead to cost savings, amongst other advantages. The fiber structures may be used in a variety of applications including electrodes in batteries and fuel cells.
摘要:
The present invention relates to single chamber fuel cells and systems and methods associated with the same. Architectures and materials that allow for high performance, enhanced fuel utilization, mechanical robustness, and mechanical flexibility are described. In some embodiments, multiple fuel cell units are arranged in a single chamber and may be, in some cases, connected to each other (e.g., connected in series, connected in parallel, etc.). Each fuel cell unit can be defined as one or more anode(s), one or more cathode(s), and an electrolyte able to maintain electrical separation between the anode(s) and cathode(s). The multiple fuel cell units are arranged in stacks in some cases. In one set of embodiments, the stacks of fuel cell units can be shaped and/or arranged to enhance the mixing of fuel and oxidant, thus improving distribution of reactants in the reaction zone. For example, the stacks of fuel cells may be arranged as fins within the fuel cell chamber. In addition, the stacks of fuel cells may be porous in some instances. In addition, the stacks of fuel cell units may be arranged to enhance other fluid flow parameters (e.g., residence time, reactant distribution, etc.). In some cases, the enhanced fluid flow may lead to increased fuel utilization and system efficiency.
摘要:
The oxygen evolution reaction (OER)-catalyzing activity of transition metal perovskite oxide catalysts depends on the occupancy of the σ-bonding orbital of eg symmetry parentage of the active cation. Catalysts having preferred values of eg orbital filling can have a high intrinsic activity for catalysis of the OER.
摘要:
Integrated polymeric-ceramic membrane-based oxy-fuel combustor. The combustor includes a polymer membrane structure for receiving air at an input and for delivering oxygen-enriched air at an outlet. An oxygen transport reactor including a ceramic ion transport membrane receives the oxygen-enriched air from the polymer membrane structure to generate oxygen for combustion with a fuel introduced into the oxygen transport reactor.