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120 条记录 (耗时 0.021 秒)

    Catalytic cracking process with partial CO combustion
    1.
    发明授权
    Catalytic cracking process with partial CO combustion 失效
    催化裂化过程与部分CO燃烧

    公开(公告)号：US4980050A

    公开(公告)日：1990-12-25

    申请号：US206241

    申请日：1988-06-10

    申请人： Billy K. Huh ,  Tsoung Y. Yan

    发明人： Billy K. Huh ,  Tsoung Y. Yan

    IPC分类号： C10G11/05 ,  C10G11/18

    CPC分类号： C10G11/05 ,  C10G11/18

    摘要： A catalytic cracking process for converting heavy, metals laden feed to lighter products is disclosed. The catalyst regenerator is operated under relatively reducing conditions, to produce a flue gas containing at least 1 mole % carbon monoxide. An additive, preferably alumina, is added to the circulating catalyst inventory to selectively sorb metal contaminants in the feed. The reducing conditions in the catalyst regenerator minimize formation of highly oxidized forms of vanadium, permitting higher vanadium levels to be tolerated on the cracking catalyst. The additive material has a greater affinity for vanadium than the cracking catalyst, and absorbs a disproportionate amount of metals in the feed. Preferably a soft, friable, alumina additive is used which results in the production of alumina fines rich in vanadium, which are discharged from the unit with catalyst fines. The process works especially well in fluidized catalytic cracking processes, with removal of vanadium laden alumina fines from the FCC regenerator with the regenerator flue gas.

    摘要翻译： 公开了一种将重金属负载物转化为轻质产品的催化裂化方法。 催化剂再生器在相对减少的条件下运行，以产生含有至少1摩尔％一氧化碳的烟道气。 将添加剂，优选氧化铝加入到循环催化剂库存中，以选择性地吸附进料中的金属污染物。 催化剂再生器中的还原条件最小化高度氧化形式的钒的形成，允许在裂化催化剂上耐受更高的钒水平。 添加剂材料对钒的亲和力高于裂化催化剂，并且吸收进料中不成比例的金属。 优选地，使用柔软的，易碎的氧化铝添加剂，其导致富含钒的氧化铝细粉的生产，其从催化剂细粉中排出。 该方法在流化催化裂化过程中特别好，通过再生器烟气从FCC再生器中除去含钒的氧化铝细粉。

    Clarification of slurry oil
    2.
    发明授权
    Clarification of slurry oil 失效
    澄清浆液

    公开(公告)号：US4919792A

    公开(公告)日：1990-04-24

    申请号：US206238

    申请日：1988-06-10

    申请人： Billy K. Huh ,  Tsoung Y. Yan

    发明人： Billy K. Huh ,  Tsoung Y. Yan

    IPC分类号： C10G11/18 ,  C10G55/02

    CPC分类号： C10G55/02 ,  C10G11/18

    摘要： A process for removing catalyst fines from slurry oil is disclosed. A settling reagent, such as coal, alumina, or coke, is added to a fines containing heavy oil bottoms product from a fractionator downstream of a catalytic cracking unit. The settling reagent promotes rapid settling and removal of fines from heavy oil product. Settling may be performed in a slurry settler, or a centrifuge. A catalytic cracking process for heavy, metals laden oil is also disclosed using a settling reagent to clarify slurry oil, then recycling settled settling reagent to contact the heavy oil in the catalytic cracking process.

    摘要翻译： 公开了一种从浆料油中除去催化剂细粉的方法。 将沉降试剂如煤，氧化铝或焦炭加入到含有重油底部产物的细粉中，其中催化裂化装置下游的分馏塔。 沉降试剂促进重油产品的细粉快速沉降和清除。 沉降可以在淤浆沉降器或离心机中进行。 还公开了一种重金属负载油的催化裂化方法，使用沉降试剂来澄清淤浆油，然后再循环沉降的沉降试剂以在催化裂化过程中与重油接触。

    Catalytic cracking of heavy oils
    3.
    发明授权
    Catalytic cracking of heavy oils 失效
    重油催化裂化

    公开(公告)号：US4980049A

    公开(公告)日：1990-12-25

    申请号：US206237

    申请日：1988-06-10

    申请人： Billy K. Huh ,  Tsoung Y. Yan

    发明人： Billy K. Huh ,  Tsoung Y. Yan

    IPC分类号： B01J37/04 ,  C10G11/05 ,  C10G11/16 ,  C10G11/18

    CPC分类号： B01J37/04 ,  C10G11/05 ,  C10G11/16 ,  C10G11/18

    摘要： A catalytic cracking process operates with a getter additive present where hot catalyst meets heavy metals laden crude. The getter additive is a material which is selective for metals, and has a particle size/density such that the getter additive remains in the FCC unit for no more than 24 hours, and preferably is removed within one hour or less. Addition of 1-5 weight percent alumina having an average particle size of 10-40 microns will remove much of the metal content from the feed, and the metals laden additive will itself be rapidly removed from the FCC unit preventing migration of metal or degradation of the cracking operation due to the presence of metal. Preferably the additive is fine particles which are mixed with the hydrocarbon feed to the unit.

    摘要翻译： 催化裂化工艺与存在的吸附剂添加剂相结合，其中热催化剂满足载有重金属的原油。 吸气剂添加剂是对金属有选择性的材料，并且具有使吸附剂添加剂保留在FCC单元中不超过24小时的粒度/密度，优选在1小时以内除去。 加入平均粒径为10-40微米的1-5重量％的氧化铝将从进料中除去大部分金属含量，并且载有金属的添加剂本身将迅速从FCC装置中除去，从而防止金属的迁移或降解 由于存在金属而导致的开裂操作。 优选地，添加剂是与烃进料混合到该单元的细颗粒。

    Catalytic cracking of hydrocarbons
    4.
    发明授权
    Catalytic cracking of hydrocarbons 失效
    碳氢化合物的催化裂化

    公开(公告)号：US4828680A

    公开(公告)日：1989-05-09

    申请号：US145952

    申请日：1988-01-20

    申请人： Gary J. Green ,  Billy K. Huh ,  Tsoung Y. Yan

    发明人： Gary J. Green ,  Billy K. Huh ,  Tsoung Y. Yan

    IPC分类号： C10G11/18

    CPC分类号： C10G11/18 ,  Y10S502/515 ,  Y10S502/516

    摘要： Combustible carbonaceous particles such as particles of sponge coke or coal are incorporated with the circulating inventory of cracking catalyst in a fluid catalytic cracking unit. The carbonaceous particles selectively sorb metal contaminants in the feed, thereby extending catalyst life, and they also serve to reduce NO.sub.x emissions in certain instances. The sorbed metals values may be recovered as the carbonaceous particles are burned.

    摘要翻译： 可燃的碳质颗粒如海绵焦炭或煤的颗粒与流化催化裂化装置中的裂解催化剂的循环库存结合。 碳质颗粒选择性地吸附进料中的金属污染物，从而延长催化剂寿命，并且它们还用于在某些情况下减少NOx排放。 当碳质颗粒燃烧时，可以回收吸附的金属值。

    PROCESS AND APPARATUS FOR ONLINE REJUVENATION OF CONTAMINATED SULFOLANE SOLVENT
    7.
    发明申请
    PROCESS AND APPARATUS FOR ONLINE REJUVENATION OF CONTAMINATED SULFOLANE SOLVENT 审中-公开
    污染磺化溶剂在线重新使用的工艺和装置

    公开(公告)号：US20090272702A1

    公开(公告)日：2009-11-05

    申请号：US12112623

    申请日：2008-04-30

    申请人： Ping-Wen Yen ,  Yuh-Sheve Ho ,  Hung-Tzu Chiu ,  Chung-Jong Hwu ,  June-Cheng Chang ,  Tzong-Bin Lin ,  Tsoung Y. Yan ,  Cheng-Tsung Hong ,  Hung-Chung Shen

    发明人： Ping-Wen Yen ,  Yuh-Sheve Ho ,  Hung-Tzu Chiu ,  Chung-Jong Hwu ,  June-Cheng Chang ,  Tzong-Bin Lin ,  Tsoung Y. Yan ,  Cheng-Tsung Hong ,  Hung-Chung Shen

    IPC分类号： B01D35/06 ,  B01D37/00

    CPC分类号： B03C1/015 ,  B01D29/23 ,  B01D35/06 ,  B03C1/0332 ,  B03C1/286 ,  C10G21/28

    摘要： A continuous online process for rejuvenating whole stream of contaminated lean sulfolane in an extraction system is provided. In particular, a rejuvenator is installed in the solvent circulation loop to remove the contaminants continuously to keep the solvent clean, effective and less corrosive. Specifically, the rejuvenator comprises a high pressure vessel with a removable cover and a round rack with vertical stainless steel tubes fitted in the high pressure vessel. A magnetic bar is placed in each stainless steel tube. A screen cylinder is installed inside the ring of stainless steel tubes. As the contaminated sulfolane is passed through the rejuvenator, the rejuvenator picks up its contaminants. The rejuvenator can be dissembled to remove the contaminants periodically. The rejuvenator is characterized by simple in construction, reliable in operation, and low in operation and maintenance costs. With this rejuvenator, the extraction system can be operated at high efficiency and high capacity without the dreaded corrosion.

    摘要翻译： 提供了一个连续的在线过程，用于在提取系统中恢复受污染的贫环烷砜的全流。 特别地，在溶剂循环回路中安装一个振动器，以连续地去除污染物，以保持溶剂清洁，有效和较少的腐蚀性。 具体来说，复原器包括具有可拆卸盖的高压容器和安装在高压容器中的垂直不锈钢管的圆形架。 在每个不锈钢管中放置一个磁棒。 丝网筒安装在不锈钢管的环内。 当受污染的环丁砜通过振动器时，复原器会吸收其污染物。 可以拆除复原器以定期去除污染物。 振兴器的特点是施工简单，运行可靠，运行维护成本低。 通过这种振兴器，提取系统可以高效率和高容量地运行，而不会产生可怕的腐蚀。

    Production of aliphatic esters
    8.
    发明授权
    Production of aliphatic esters 失效
    生产脂肪族酯

    公开(公告)号：US06399812B1

    公开(公告)日：2002-06-04

    申请号：US09559339

    申请日：2000-04-27

    申请人： Tsoung Y. Yan ,  Jen-Ray Chang

    发明人： Tsoung Y. Yan ,  Jen-Ray Chang

    IPC分类号： C07C6902

    CPC分类号： C07C67/40 ,  C07C69/24 ,  C07C69/14

    摘要： Aliphatic esters, R'COOR are produced by reacting the corresponding alcohol, ROH having carbon numbers of the alkyl groups, R′ and R, between 0 and 9 and 1 and 10, respectively, with molecular oxygen in the presence of a dual functional catalyst comprising metal on acidic solid support. In particular, the process is used advantageously for production of ethyl acetate by conversion of ethanol. The reaction mixture from the reactor is separated through azeotropic distillation to recover the ethyl acetate as product and the by-product, acetaldehyde and acetic acid which could be recycled for further reaction. The process is characterized by high conversion of ethanol, high selectivity and high yield for ethyl acetate and low waste stream generation. The preferred catalyst is Pd on zeolites which is active, selective, stable and regenerable.

    摘要翻译： 脂肪族酯R'COOR是通过在双官能催化剂存在下使相应的醇R 1和R 10分别与0分别为0和9分子之间的烷基，R 1和R 2分别与分子氧反应的醇ROH 在酸性固体载体上包含金属。 特别地，该方法有利地用于通过乙醇转化生产乙酸乙酯。 通过共沸蒸馏分离来自反应器的反应混合物以回收作为产物的乙酸乙酯和可再循环用于进一步反应的副产物乙醛和乙酸。 该方法的特点是乙醇转化率高，乙酸乙酯选择性高，产率高，废液产生量低。 优选的催化剂是Pd活性，选择性，稳定和可再生的沸石。

    Dissolving salt for solid caustic with oil
    9.
    发明授权
    Dissolving salt for solid caustic with oil 失效
    用油溶解固体苛性碱的盐

    公开(公告)号：US5611913A

    公开(公告)日：1997-03-18

    申请号：US367412

    申请日：1994-12-30

    申请人： Tsoung Y. Yan

    发明人： Tsoung Y. Yan

    IPC分类号： C10G19/073 ,  C10G61/02 ,  C10G19/00

    CPC分类号： C10G61/02 ,  C10G19/073

    摘要： Acidic halides, especially chlorides, are removed from dry process vapor and liquid hydrocarbon streams by contact with solid caustic, such as a bed of NaOH. Salt deposits from form on the solid caustic, which are periodically removed by passing a liquid hydrocarbon continuous phase containing a minor amount of dissolved or entrained water over the solid caustic. Salts may be removed from the liquid hydrocarbon by extraction with water, which also saturates the liquid hydrocarbon so that it may be used to remove additional salt deposits.

    摘要翻译： 酸性卤化物，特别是氯化物，通过与固体苛性碱如NaOH床接触从干法蒸气和液态烃流中除去。 通过使含有少量溶解或夹带的水的液体烃连续相在固体苛性碱上定期除去，从而形成固体苛性碱上的盐沉积物。 盐可以通过用水萃取从液体烃中除去，这也使液体烃饱和，使其可用于除去附加的盐沉积物。

    Reclamation of HF and recovery of gasoline from acid-soluble oil by cracking
    10.
    发明授权
    Reclamation of HF and recovery of gasoline from acid-soluble oil by cracking 失效
    回收HF，通过开裂从酸溶性油中回收汽油

    公开(公告)号：US5476983A

    公开(公告)日：1995-12-19

    申请号：US285674

    申请日：1994-08-04

    申请人： Tsoung Y. Yan

    发明人： Tsoung Y. Yan

    IPC分类号： B01J27/32 ,  C07C2/62

    CPC分类号： C07C2/62 ,  B01J27/32 ,  C07C2527/1206 ,  Y02P20/584

    摘要： The present invention provides a method for reclaiming HF and producing valuable gasoline blending components from the conjunct polymeric byproducts (acid soluble oil or ASO) formed as a byproduct of acid-catalyzed isoparaffin-olefin alkylation comprising the steps of:(a) reacting isoparaffin and olefin in the presence of a liquid acid alkylation catalyst to form alkylate and ASO byproduct;(b) separating alkylate, unreacted isoparaffin, and a majority of said liquid acid alkylation catalyst from said ASO;(c) reacting said separated ASO of step (b) under conditions of elevated temperature and pressure to convert the hydrocarbon portion of said ASO to gasoline boiling range hydrocarbons and to liberate HF.In a preferred embodiment, the ASO is pre-mixed with hydrogen or a hydrogen donor before reaction at elevated temperature and pressure. In a particularly preferred embodiment, the elevated temperature reaction is carried out in the presence of a catalyst such as activated carbon.

    摘要翻译： 本发明提供了一种回收HF的方法，由作为酸催化的异链烷烃 - 烷基烷基化副产物形成的结合的聚合副产物（酸溶性油或ASO）制备有价值的汽油调配成分的方法，包括以下步骤：（a）使异链烷烃和 烯烃在液态酸烷基化催化剂存在下形成烷基化物和ASO副产物; （b）从所述ASO分离烷基化物，未反应的异链烷烃和大部分所述液体酸烷基化催化剂; （c）使步骤（b）的所述分离的ASO在升高的温度和压力的条件下反应，以将所述ASO的烃部分转化为汽油沸程烃并释放HF。 在优选的实施方案中，ASO在升高的温度和压力下在反应之前与氢或氢供体预混合。 在特别优选的实施方案中，升高的温度反应在催化剂如活性炭的存在下进行。