公开(公告)号：US4980050A

公开(公告)日：1990-12-25

申请号：US206241

申请日：1988-06-10

申请人： Billy K. Huh ,  Tsoung Y. Yan

发明人： Billy K. Huh ,  Tsoung Y. Yan

IPC分类号： C10G11/05 ,  C10G11/18

CPC分类号： C10G11/05 ,  C10G11/18

摘要： A catalytic cracking process for converting heavy, metals laden feed to lighter products is disclosed. The catalyst regenerator is operated under relatively reducing conditions, to produce a flue gas containing at least 1 mole % carbon monoxide. An additive, preferably alumina, is added to the circulating catalyst inventory to selectively sorb metal contaminants in the feed. The reducing conditions in the catalyst regenerator minimize formation of highly oxidized forms of vanadium, permitting higher vanadium levels to be tolerated on the cracking catalyst. The additive material has a greater affinity for vanadium than the cracking catalyst, and absorbs a disproportionate amount of metals in the feed. Preferably a soft, friable, alumina additive is used which results in the production of alumina fines rich in vanadium, which are discharged from the unit with catalyst fines. The process works especially well in fluidized catalytic cracking processes, with removal of vanadium laden alumina fines from the FCC regenerator with the regenerator flue gas.

摘要翻译： 公开了一种将重金属负载物转化为轻质产品的催化裂化方法。 催化剂再生器在相对减少的条件下运行，以产生含有至少1摩尔％一氧化碳的烟道气。 将添加剂，优选氧化铝加入到循环催化剂库存中，以选择性地吸附进料中的金属污染物。 催化剂再生器中的还原条件最小化高度氧化形式的钒的形成，允许在裂化催化剂上耐受更高的钒水平。 添加剂材料对钒的亲和力高于裂化催化剂，并且吸收进料中不成比例的金属。 优选地，使用柔软的，易碎的氧化铝添加剂，其导致富含钒的氧化铝细粉的生产，其从催化剂细粉中排出。 该方法在流化催化裂化过程中特别好，通过再生器烟气从FCC再生器中除去含钒的氧化铝细粉。

公开(公告)号：US4980049A

公开(公告)日：1990-12-25

申请号：US206237

申请日：1988-06-10

申请人： Billy K. Huh ,  Tsoung Y. Yan

发明人： Billy K. Huh ,  Tsoung Y. Yan

IPC分类号： B01J37/04 ,  C10G11/05 ,  C10G11/16 ,  C10G11/18

CPC分类号： B01J37/04 ,  C10G11/05 ,  C10G11/16 ,  C10G11/18

摘要： A catalytic cracking process operates with a getter additive present where hot catalyst meets heavy metals laden crude. The getter additive is a material which is selective for metals, and has a particle size/density such that the getter additive remains in the FCC unit for no more than 24 hours, and preferably is removed within one hour or less. Addition of 1-5 weight percent alumina having an average particle size of 10-40 microns will remove much of the metal content from the feed, and the metals laden additive will itself be rapidly removed from the FCC unit preventing migration of metal or degradation of the cracking operation due to the presence of metal. Preferably the additive is fine particles which are mixed with the hydrocarbon feed to the unit.

摘要翻译： 催化裂化工艺与存在的吸附剂添加剂相结合，其中热催化剂满足载有重金属的原油。 吸气剂添加剂是对金属有选择性的材料，并且具有使吸附剂添加剂保留在FCC单元中不超过24小时的粒度/密度，优选在1小时以内除去。 加入平均粒径为10-40微米的1-5重量％的氧化铝将从进料中除去大部分金属含量，并且载有金属的添加剂本身将迅速从FCC装置中除去，从而防止金属的迁移或降解 由于存在金属而导致的开裂操作。 优选地，添加剂是与烃进料混合到该单元的细颗粒。

公开(公告)号：US4828680A

公开(公告)日：1989-05-09

申请号：US145952

申请日：1988-01-20

申请人： Gary J. Green ,  Billy K. Huh ,  Tsoung Y. Yan

发明人： Gary J. Green ,  Billy K. Huh ,  Tsoung Y. Yan

IPC分类号： C10G11/18

CPC分类号： C10G11/18 ,  Y10S502/515 ,  Y10S502/516

摘要： Combustible carbonaceous particles such as particles of sponge coke or coal are incorporated with the circulating inventory of cracking catalyst in a fluid catalytic cracking unit. The carbonaceous particles selectively sorb metal contaminants in the feed, thereby extending catalyst life, and they also serve to reduce NO.sub.x emissions in certain instances. The sorbed metals values may be recovered as the carbonaceous particles are burned.

摘要翻译： 可燃的碳质颗粒如海绵焦炭或煤的颗粒与流化催化裂化装置中的裂解催化剂的循环库存结合。 碳质颗粒选择性地吸附进料中的金属污染物，从而延长催化剂寿命，并且它们还用于在某些情况下减少NOx排放。 当碳质颗粒燃烧时，可以回收吸附的金属值。

公开(公告)号：US4919792A

公开(公告)日：1990-04-24

申请号：US206238

申请日：1988-06-10

申请人： Billy K. Huh ,  Tsoung Y. Yan

发明人： Billy K. Huh ,  Tsoung Y. Yan

IPC分类号： C10G11/18 ,  C10G55/02

CPC分类号： C10G55/02 ,  C10G11/18

摘要： A process for removing catalyst fines from slurry oil is disclosed. A settling reagent, such as coal, alumina, or coke, is added to a fines containing heavy oil bottoms product from a fractionator downstream of a catalytic cracking unit. The settling reagent promotes rapid settling and removal of fines from heavy oil product. Settling may be performed in a slurry settler, or a centrifuge. A catalytic cracking process for heavy, metals laden oil is also disclosed using a settling reagent to clarify slurry oil, then recycling settled settling reagent to contact the heavy oil in the catalytic cracking process.

摘要翻译： 公开了一种从浆料油中除去催化剂细粉的方法。 将沉降试剂如煤，氧化铝或焦炭加入到含有重油底部产物的细粉中，其中催化裂化装置下游的分馏塔。 沉降试剂促进重油产品的细粉快速沉降和清除。 沉降可以在淤浆沉降器或离心机中进行。 还公开了一种重金属负载油的催化裂化方法，使用沉降试剂来澄清淤浆油，然后再循环沉降的沉降试剂以在催化裂化过程中与重油接触。

公开(公告)号：US4982033A

公开(公告)日：1991-01-01

申请号：US469651

申请日：1990-01-24

申请人： Cynthia T-W. Chu ,  Thomas F. Degnan ,  Billy K. Huh

发明人： Cynthia T-W. Chu ,  Thomas F. Degnan ,  Billy K. Huh

IPC分类号： B01J29/04 ,  C07C2/12 ,  C07C5/41

CPC分类号： C07C2/12 ,  B01J29/04 ,  C07C5/41 ,  C07C2529/04 ,  C07C2529/70

摘要： Aliphatic C.sub.2 to C.sub.12 hydrocarbons are converted in the presence of a particular zeolite catalyst to a mixture of aromatics, optionally containing olefins.

摘要翻译： 在特定的沸石催化剂存在下将脂肪族C 2 -C 12烃转化成任选含有烯烃的芳族化合物的混合物。

公开(公告)号：US4895636A

公开(公告)日：1990-01-23

申请号：US206240

申请日：1988-06-10

申请人： Nai Y. Chen ,  Billy K. Huh ,  Thomas F. Degnan

发明人： Nai Y. Chen ,  Billy K. Huh ,  Thomas F. Degnan

IPC分类号： C10G11/18

CPC分类号： C10G11/18

摘要： An FCC or fluidized catalytic cracking process and apparatus for converting heavy metals laden crudes is disclosed. The heavy feed, conventional catalyst and an additive or vanadium getter contact the feed in a riser reactor. The additive is segregated from conventional FCC catalyst upstream of the conventional FCC regenerator. An elutriating, upflow riser reactor may be used with a coarse, rapidly settling getter. A fine, slowly settling getter may be used, with getter segregation achieved by using an elutriating cyclone on the riser outlet, an elutriating catalyst stripper, a sieve, or the like. The spent getter may be used once through, regenerated in a separate getter regenerator, or used as a source of fuel. Alumina and sponge coke are preferred getters.

摘要翻译： 公开了一种FCC或流化催化裂化方法和用于转化重金属负载原油的装置。 重料，常规催化剂和添加剂或钒吸附剂在提升管反应器中接触进料。 该添加剂与常规FCC再生器上游的常规FCC催化剂分离。 淘汰式上升式提升管式反应器可与粗，快速沉降的吸气剂一起使用。 可以使用细的缓慢沉降的吸气剂，通过在提升管出口，淘洗催化剂汽提器，筛子等上使用淘洗旋风来实现吸气剂分离。 废吸气剂可以一次使用，在单独的吸气剂再生器中再生，或用作燃料来源。 氧化铝和海绵焦炭是优选的吸气剂。

公开(公告)号：US4871444A

公开(公告)日：1989-10-03

申请号：US271398

申请日：1988-11-10

申请人： Nai Y. Chen ,  Billy K. Huh ,  Anil B. Ketkar ,  Chaya Venkat

发明人： Nai Y. Chen ,  Billy K. Huh ,  Anil B. Ketkar ,  Chaya Venkat

IPC分类号： C10G29/20 ,  C10G57/00 ,  C10L1/08 ,  F02B3/06

CPC分类号： C10L1/08 ,  C10G29/205 ,  C10G57/005 ,  F02B3/06

摘要： A method for improving the cetane number of an aromatic hydrocarbon oil such as FCC light cycle oil and thereby increase its value as a blending stock for diesel fuel or heating oil. In one embodiment, the FCC light cycle oil is alkylated in the presence of a solid acidic catalyst and with a linear mono-olefin having a chain length of at least five carbon atoms. In another embodiment, the light cycle oil is alkylated with an olefin having three to nine carbon atoms or a mixture thereof and with ZSM-20 as catalyst to decrease the frequency of catalyst regeneration.

摘要翻译： 一种改进FCC轻质循环油等芳香族烃油的十六烷值的方法，由此增加作为柴油或加热油的混合原料的值。 在一个实施方案中，FCC轻质循环油在固体酸性催化剂和链长至少为5个碳原子的直链单烯烃的存在下烷基化。 在另一个实施方案中，光循环油用具有3-9个碳原子的烯烃或其混合物和ZSM-20作为催化剂烷基化以降低催化剂再生的频率。

公开(公告)号：US4971766A

公开(公告)日：1990-11-20

申请号：US437064

申请日：1989-11-16

申请人： Nai Y. Chen ,  Billy K. Huh ,  Thomas E. Degnan

发明人： Nai Y. Chen ,  Billy K. Huh ,  Thomas E. Degnan

IPC分类号： C10G11/18

CPC分类号： C10G11/18

摘要： An FCC or fluidized catalytic cracking process and apparatus for converting heavy metals laden crudes is disclosed. The heavy feed, conventional catalyst and an additive or vanadium getter contact the feed in a riser reactor. The additive is segregated from conventional FCC catalyst upstream of the conventional FCC regenerator. An elutriating, upflow riser reactor may be used with a coarse, rapidly settling getter. A fine, slowly settling getter may be used, with getter segregation achieved by using an elutriating cyclone on the riser outlet, an elutriating catalyst stripper, a sieve, or the like. The spent getter may be used once through, regenerated in a separate getter regenerator, or used as a source of fuel. Alumina and sponge coke are preferred getters.

摘要翻译： 公开了一种FCC或流化催化裂化方法和用于转化重金属负载原油的装置。 重料，常规催化剂和添加剂或钒吸附剂在提升管反应器中接触进料。 该添加剂与常规FCC再生器上游的常规FCC催化剂分离。 淘汰式上升式提升管式反应器可与粗，快速沉降的吸气剂一起使用。 可以使用细的缓慢沉降的吸气剂，通过在提升管出口，淘洗催化剂汽提器，筛子等上使用淘洗旋风来实现吸气剂分离。 废吸气剂可以一次使用，在单独的吸气剂再生器中再生，或用作燃料来源。 氧化铝和海绵焦炭是优选的吸气剂。

公开(公告)号：US4938863A

公开(公告)日：1990-07-03

申请号：US206242

申请日：1988-06-10

申请人： Thomas F. Degnan ,  Billy K. Huh

发明人： Thomas F. Degnan ,  Billy K. Huh

IPC分类号： C10G11/05

CPC分类号： C10G11/05

摘要： A catalytic cracking catalyst and process which tolerates high levels of vanadium and coke precursors in the feed is disclosed. A zeolite in an alumina free binder or coating, preferably silica, is used as the cracking catalyst. RE-USY in silica is especially preferred as it has a low affinity for vanadium, low coking characteristics and high stability. Preferably a vanadium getter additive is present as separate particles to act as a vanadium sink. The catalyst and process may be used in fluidized bed catalytic cracking (FCC) or in moving bed catalytic cracking units. A method of making a coated catalyst, by adding a layer of an alumina free material to a core of alumina containing cracking catalyst is also disclosed.

摘要翻译： 公开了一种催化裂化催化剂和方法，其耐受饲料中高含量的钒和焦炭前体。 使用不含氧化铝的粘合剂或涂层中的沸石，优选二氧化硅作为裂化催化剂。 二氧化硅中的RE-USY是特别优选的，因为它对钒的低亲和力，低焦化特性和高稳定性。 优选地，钒吸附剂添加剂作为单独的颗粒存在以充当钒槽。 催化剂和方法可用于流化床催化裂化（FCC）或移动床催化裂化装置。 还公开了通过向含氧化铝的裂化催化剂的核心添加无氧化铝材料层来制备涂覆的催化剂的方法。