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公开(公告)号:US11015083B2
公开(公告)日:2021-05-25
申请号:US16844513
申请日:2020-04-09
发明人: Chris Fish , Jerry Kilby
IPC分类号: C09D183/16 , B05D3/02 , C08G77/60 , C08G77/62
摘要: Provided herein is a method of coating a surface. A silicon-based coating composition is coated onto a surface. The silicon-based coating composition comprises polysilazane and polysilane comprising a formula (R1R2Si)n, wherein n is greater than 1, and wherein R1 and R2 are the same or different and are chosen from alkyl, alkenyl, cycloalkyl, alkylamino, aryl, aralkyl, or alkylsilyl, which polysilane has a weight average molecular weight of more than 50,000. Also provided are silicon-based coating compositions and cured coatings from those compositions using the provided method.
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公开(公告)号:US09567488B2
公开(公告)日:2017-02-14
申请号:US13935443
申请日:2013-07-03
发明人: Chris Fish
IPC分类号: C08G77/60 , C09D183/10 , C09D183/14 , C08L83/16 , B05D5/08 , C08G77/62 , C08G77/04
CPC分类号: C09D183/16 , B05D3/007 , B05D5/08 , C08G77/04 , C08G77/60 , C08G77/62 , C08L83/16 , C09D5/00 , C09D5/08 , C09D5/24 , C09D5/32 , C09D183/00 , C09D183/04 , C09D183/10 , C09D183/14 , C08L83/00
摘要: A silicon-based coating composition for a wide range of mold surfaces, which composition is formed from a mixture of constituents comprising appropriate portions of silazane, siloxane, and silane, and optionally organic solvent. The composition, after curing, results in an extreme release product that is non-transferable to the finished part, allowing for proper adhesion of coatings or adhesives to the finished surface without additional surface preparation. The cured coatings are ultrathin, having a thickness between 0.1 μm and 3 μm, and having a hardness between about 4H and about 9H.
摘要翻译: 用于各种模具表面的硅基涂料组合物,该组合物由包含硅氮烷,硅氧烷和硅烷的适当部分的组分的混合物以及任选的有机溶剂形成。 固化后的组合物会导致不能转移到成品部件的极端释放产品,从而允许涂层或粘合剂适当粘附到成品表面,无需额外的表面处理。 固化的涂层是超薄的,厚度在0.1μm和3μm之间,硬度在约4H和约9H之间。
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公开(公告)号:US20180171177A1
公开(公告)日:2018-06-21
申请号:US15820853
申请日:2017-11-22
发明人: Chris Fish , Jerry Kilby
IPC分类号: C09D183/16 , C08L83/00 , B05D3/02 , C08G77/60 , C08G77/62
CPC分类号: C09D183/16 , B05D3/0254 , C08G77/60 , C08G77/62 , C08L83/00
摘要: Provided herein is a silicon based coating formed from a mixture of constituents. The mixture comprises from about 5% (w/w of the mixture) to about 80% (w/w of the mixture) polysilazane, from about 0% (w/w of the mixture) to about 60% (w/w of the mixture) polysiloxane, and from about 8% (w/w of the mixture) to about 80% (w/w of the mixture) polysilane of a formula (R1R2Si)n, wherein n is greater than 1, and wherein R1 and R2 are the same or different and are chosen from alkyl, alkenyl, cycloalkyl, alkylamino, aryl, aralkyl, or alkylsilyl. The coating has a thickness ranging between about 0.1 mil and about 1.5 mil, a hardness ranging between about 2H and about 9H in accordance with ASTM 3363 for film hardness by pencil test, and a kinetic coefficient of friction between about 0.03 and about 0.04.
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公开(公告)号:US10301507B2
公开(公告)日:2019-05-28
申请号:US16165557
申请日:2018-10-19
发明人: Chris Fish , Jerry Kilby
IPC分类号: C09D183/16 , B05D3/02 , C08G77/60 , C08G77/62
摘要: Provided herein is a method of coating a surface. A silicon-based coating composition is coated onto a surface. The composition comprises 5% to 80% polysilazane, 20% to 60% polysiloxane, and polysilane of a formula (R1R2Si)n, wherein n is greater than 1, and wherein R1 and R2 are the same or different and are chosen from alkyl, alkenyl, cycloalkyl, alkylamino, aryl, aralkyl, or alkylsilyl, which polysilane has a weight average molecular weight of more than 50,000, and optionally organic solvent. The coating is cured ambiently to provide a non-ceramic clear coating having a thickness ranging between 0.1 mil and 1.5 mil, a hardness ranging between 2H and 9H in accordance with ASTM 3363 for film hardness by pencil test, and a kinetic coefficient of friction between 0.03 and 0.04. Also provided are silicon-based coating compositions and cured coatings from those compositions using the provided method.
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公开(公告)号:US10138381B2
公开(公告)日:2018-11-27
申请号:US13891438
申请日:2013-05-10
发明人: Chris Fish
IPC分类号: C09D5/18 , C09D183/14 , C08G77/54 , C08G77/04
摘要: A silicon based coating composition for a wide range of surfaces, which composition is formed from a mixture of constituents comprising appropriate portions of silazane, siloxane, and silane, and optionally organic solvent and additives, and the composition results in a coating having a thickness between 0.4 mil and 1.5 mil, a hardness of 4-9H and an endurance to continuous temperature above 1600° F.
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公开(公告)号:US12122936B2
公开(公告)日:2024-10-22
申请号:US18451446
申请日:2023-08-17
发明人: Chris Fish
IPC分类号: C09D183/16 , B05D3/00 , C08L83/16 , C09D5/00 , C09D5/08 , C09D5/24 , C09D5/32 , C09D183/00 , C09D183/04 , C09D183/10 , C09D183/14 , B05D5/08 , C08G77/04 , C08G77/60 , C08G77/62
CPC分类号: C09D183/16 , B05D3/007 , C08L83/16 , C09D5/00 , C09D5/08 , C09D5/24 , C09D5/32 , C09D183/00 , C09D183/04 , C09D183/10 , C09D183/14 , B05D5/08 , C08G77/04 , C08G77/60 , C08G77/62 , C08L83/16 , C08L83/00
摘要: A silicon-based coating composition for a wide range of mold surfaces, which composition is formed from a mixture of constituents comprising appropriate portions of silazane, siloxane, and silane, and optionally organic solvent. The composition, after curing, results in an extreme release product that is non-transferable to the finished part, allowing for proper adhesion of coatings or adhesives to the finished surface without additional surface preparation. The cured coatings are ultrathin, having a thickness between 0.1 μm and 3 μm, and having a hardness between about 4H and about 9H.
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公开(公告)号:US20170107401A1
公开(公告)日:2017-04-20
申请号:US15395642
申请日:2016-12-30
发明人: Chris Fish
IPC分类号: C09D183/16 , C09D5/32 , B05D3/00 , C09D183/04 , C09D183/00 , C09D5/00 , C09D5/08 , C09D5/24
CPC分类号: C09D183/16 , B05D3/007 , B05D5/08 , C08G77/04 , C08G77/60 , C08G77/62 , C08L83/16 , C09D5/00 , C09D5/08 , C09D5/24 , C09D5/32 , C09D183/00 , C09D183/04 , C09D183/10 , C09D183/14 , C08L83/00
摘要: Provided herein is a method for coating a surface. The method comprises providing a towelette moistened with a mixture of constituents to form a non-aqueous silicon-based composition comprising 7% to 80% (w/w of the total composition) polysilazane, 1% to 10% (w/w of the total composition) polysilane, 0.2% to 1% (w/w of the total composition) polysiloxane, and 20% to 70% (w/w of the total composition) at least one organic solvent; wherein polysilazane is present in a 10:1 to 110:1 weight ratio to polysiloxane; and wherein the polysilane is of a formula (R1R2Si)n, wherein n is greater than 1, and wherein R1 and R2 are the same or different and are chosen from alkyl, alkenyl, cycloalkyl, alkylamino, aryl, aralkyl, or alkylsilyl. The mixture from the towelette to form a coating on a surface and the coating is cured ambiently without additional heat. Also provided are towelettes containing the mixture.
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公开(公告)号:US09505949B2
公开(公告)日:2016-11-29
申请号:US14641748
申请日:2015-03-09
发明人: Chris Fish
IPC分类号: C09D183/04 , C08L83/04 , B05D3/02 , C08G77/04
CPC分类号: C09D183/04 , B05D3/0254 , B29C70/34 , B29C70/462 , B29K2083/00 , B29K2105/124 , C08G77/04 , C08G77/62 , C08K3/04 , C08K3/38 , C08K2003/385 , C08L83/00 , C08L83/04 , C08L83/16 , C09D183/08 , C09D183/16 , Y10T156/1044 , Y10T428/1372 , Y10T428/25 , Y10T442/20 , Y10T442/2984
摘要: Provided herein are silicon-based compositions, which after curing is a coating composition having strong substrate adhesion and scratch resistance. The compositions are formed from a mixture of constituents comprising: from about 20% to about 90% (w/w) of a first siloxane selected from the group consisting of silsesquioxane, methylmethoxysiloxane, and combinations thereof; and from about 10% to about 80% (w/w) of one or more silicon compounds selected from the group consisting of a second siloxane, silane, and silazane. Optionally, the compositions may comprise from about 0.1% to about 5% (w/w) alkyltitanate.
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公开(公告)号:US20150099848A1
公开(公告)日:2015-04-09
申请号:US14275675
申请日:2014-05-12
发明人: Chris Fish
IPC分类号: C09D183/04 , C09D183/08 , B05D3/02
CPC分类号: C09D183/04 , B05D3/0254 , B29C70/34 , B29C70/462 , B29K2083/00 , B29K2105/124 , C08G77/04 , C08G77/62 , C08K3/04 , C08K3/38 , C08K2003/385 , C08L83/00 , C08L83/04 , C08L83/16 , C09D183/08 , C09D183/16 , Y10T156/1044 , Y10T428/1372 , Y10T428/25 , Y10T442/20 , Y10T442/2984
摘要: Provided herein are silicon-based compositions, which after curing is a coating composition having strong substrate adhesion and scratch resistance. The compositions are formed from a mixture of constituents comprising: from about 20% to about 90% (w/w) of a first siloxane selected from the group consisting of silsesquioxane, methylmethoxysiloxane, and combinations thereof; and from about 10% to about 80% (w/w) of one or more silicon compounds selected from the group consisting of a second siloxane, silane, and silazane. Optionally, the compositions may comprise from about 0.1% to about 5% (w/w) alkyltitanate.
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公开(公告)号:US11773290B2
公开(公告)日:2023-10-03
申请号:US15395642
申请日:2016-12-30
发明人: Chris Fish
IPC分类号: B05D3/00 , C09D183/16 , C09D183/10 , C09D183/14 , C08L83/16 , C09D5/00 , C09D5/08 , C09D5/24 , C09D5/32 , C09D183/00 , C09D183/04 , B05D5/08 , C08G77/60 , C08G77/62 , C08G77/04
CPC分类号: C09D183/16 , B05D3/007 , C08L83/16 , C09D5/00 , C09D5/08 , C09D5/24 , C09D5/32 , C09D183/00 , C09D183/04 , C09D183/10 , C09D183/14 , B05D5/08 , C08G77/04 , C08G77/60 , C08G77/62 , C08L83/16 , C08L83/00
摘要: Provided herein is a method for coating a surface. The method comprises providing a towelette moistened with a mixture of constituents to form a non-aqueous silicon-based composition comprising 7% to 80% (w/w of the total composition) polysilazane, 1% to 10% (w/w of the total composition) polysilane, 0.2% to 1% (w/w of the total composition) polysiloxane, and 20% to 70% (w/w of the total composition) at least one organic solvent; wherein polysilazane is present in a 10:1 to 110:1 weight ratio to polysiloxane; and wherein the polysilane is of a formula (R1R2Si)n, wherein n is greater than 1, and wherein R1 and R2 are the same or different and are chosen from alkyl, alkenyl, cycloalkyl, alkylamino, aryl, aralkyl, or alkylsilyl. The mixture from the towelette to form a coating on a surface and the coating is cured ambiently without additional heat. Also provided are towelettes containing the mixture.
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