公开(公告)号：US20190083962A1

公开(公告)日：2019-03-21

申请号：US16189564

申请日：2018-11-13

Applicant: California Institute Of Technology

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang

IPC: B01J29/04 ,  C07D301/12 ,  B01J35/00 ,  C10G29/20 ,  C10G35/06 ,  C10G45/04 ,  C10G45/60 ,  C10G45/68 ,  C10G50/00 ,  C10G3/00 ,  C10G11/02 ,  C01B39/08 ,  C07C1/20 ,  C07C6/12 ,  C01B39/00 ,  B01J20/10 ,  B01J20/30 ,  C10G2/00 ,  C10G47/04 ,  C07C7/13 ,  C07C2/10 ,  C07C2/66 ,  C07C5/22 ,  C07C5/41

Abstract: The present disclosure is directed to the use of novel crystalline germanosilicate compositions in affecting a range of organic transformations. In particular, the crystalline germanosilicate compositions are extra-large-pore compositions, designated CIT-13 possessing 10- and 14-membered rings.

公开(公告)号：US20190247835A1

公开(公告)日：2019-08-15

申请号：US16395912

申请日：2019-04-26

Applicant: California Institute Of Technology

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang

IPC: B01J29/04 ,  B01J20/18 ,  B01J20/30 ,  B01J37/00 ,  B01J37/08 ,  C01B39/00

Abstract: The present disclosure is directed to novel crystalline germanosilicate compositions and methods of producing the same. In particular, the crystalline germanosilicate compositions are extra-large-pore compositions, designated CIT-13 possessing 10- and 14-membered rings. The disclosure describes methods of preparing these compositions using substituted benzyl-imidazolium organic structure-directing agents (OSDAs). Also disclosed are methods of using these crystalline compositions.

公开(公告)号：US09821297B2

公开(公告)日：2017-11-21

申请号：US15063867

申请日：2016-03-08

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Ben W. Boal ,  Mark E. Davis ,  Joel E. Schmidt

IPC: C01B39/14 ,  C01B37/02 ,  B01J29/70 ,  B01J29/85 ,  B01J29/89 ,  B01J29/04 ,  C01B37/00 ,  C07C1/20 ,  C07D301/12 ,  B01J35/00 ,  B01J35/02 ,  B01D53/94

CPC classification number: B01J29/047 ,  B01D53/9413 ,  B01D2255/20707 ,  B01D2255/50 ,  B01J29/70 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/85 ,  B01J29/89 ,  B01J35/002 ,  B01J35/023 ,  C01B37/005 ,  C01B37/02 ,  C01B39/145 ,  C07C1/20 ,  C07C2523/08 ,  C07C2529/70 ,  C07C2529/89 ,  C07D301/12 ,  Y02P20/52 ,  Y02P30/42 ,  C07C11/02 ,  C07C11/04 ,  C07C11/08

Abstract: The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I): where substituents R1 to R9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H2O2.

公开(公告)号：US20210154649A1

公开(公告)日：2021-05-27

申请号：US17147911

申请日：2021-01-13

Applicant: California Institute Of Technology

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang

IPC: B01J29/04 ,  B01J29/70 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  B01J35/00 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  C01B39/02 ,  C01B39/46

Abstract: The present disclosure is directed to novel phyllosilicate compositions designated CIT-13P and methods of producing and using the same.

公开(公告)号：US20210154648A1

公开(公告)日：2021-05-27

申请号：US17147866

申请日：2021-01-13

Applicant: California Institute Of Technology

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang

IPC: B01J29/04 ,  B01J29/70 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  B01J35/00 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  C01B39/02 ,  C01B39/46

Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing the same. In particular, this disclosure describes new silica-rich compositions of the germanosilicate designated CIT-13, with and without added metal oxides. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.

公开(公告)号：US10913053B2

公开(公告)日：2021-02-09

申请号：US15449317

申请日：2017-03-03

Applicant: California Institute of Technology ,  Chevron U.S.A., Inc.

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang ,  Dan Xie

IPC: C01B39/02 ,  C01B39/48 ,  B01J29/70 ,  B01J29/04 ,  C01B39/06 ,  C01B39/08 ,  B01J35/00 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  C01B39/46

Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing the same. In particular, this disclosure describes an array of transformations originating from the extra-large-pore crystalline germanosilicate compositions, designated CIT-13, possessing 10- and 14-membered rings. Included among the new materials are the new phyllosilicate compositions, designated CIT-13P, new crystalline microporous germanosilicates including high silica versions of CIT-5 and CIT-13, with and without added metal oxides, and new germanosilicate compounds designated CIT-14 and CIT-15. The disclosure also describes methods of preparing these new germanosilicate compositions as well as the compositions themselves.

公开(公告)号：US11213807B2

公开(公告)日：2022-01-04

申请号：US17147866

申请日：2021-01-13

Applicant: California Institute Of Technology

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang

IPC: C01B39/02 ,  B01J29/70 ,  B01J29/04 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  B01J35/00 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  C01B39/46

Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing the same. In particular, this disclosure describes new silica-rich compositions of the germanosilicate designated CIT-13, with and without added metal oxides. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.

公开(公告)号：US20210129120A1

公开(公告)日：2021-05-06

申请号：US17147936

申请日：2021-01-13

Applicant: California Institute Of Technology ,  Chevron U.S.A., Inc.

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang ,  Dan Xie

IPC: B01J29/04 ,  B01J29/70 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  B01J35/00 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  C01B39/02 ,  C01B39/46

Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing and using the same. In particular, this disclosure describes new germanosilicates of CIT-14 topology. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.

公开(公告)号：US10293330B2

公开(公告)日：2019-05-21

申请号：US15169816

申请日：2016-06-01

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang

IPC: B01J29/04 ,  C01B39/00 ,  B01J20/10 ,  B01J20/30 ,  C07C5/41 ,  C07C5/22 ,  C07C2/66 ,  C07C2/10 ,  C07C7/13 ,  C10G47/04 ,  C10G2/00 ,  C07D301/12 ,  C10G29/20 ,  C10G35/06 ,  C10G45/04 ,  C10G45/60 ,  C10G45/68 ,  C10G50/00 ,  C10G3/00 ,  C10G11/02 ,  C07C1/20 ,  C07C6/12 ,  B01J35/00 ,  B01D53/94

Abstract: The present disclosure is directed to novel crystalline germanosilicate compositions and methods of producing the same. In particular, the crystalline germanosilicate compositions are extra-large-pore compositions, designated CIT-13 possessing 10- and 14-membered rings. The disclosure describes methods of preparing these compositions using substituted benzyl-imidazolium organic structure-directing agents (OSDAs). Also disclosed are methods of using these crystalline compositions.

公开(公告)号：US11213809B2

公开(公告)日：2022-01-04

申请号：US17147936

申请日：2021-01-13

Applicant: California Institute Of Technology ,  Chevron U.S.A., Inc.

Inventor： Joel E. Schmidt ,  Mark E. Davis ,  Ben W. Boal ,  Jong Hun Kang ,  Dan Xie

IPC: C01B39/02 ,  B01J29/70 ,  B01J29/04 ,  C01B39/06 ,  C01B39/08 ,  C01B39/48 ,  B01J35/00 ,  B01J37/08 ,  B01J37/10 ,  B01J37/30 ,  C01B39/46

Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing and using the same. In particular, this disclosure describes new germanosilicates of CIT-14 topology. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.