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公开(公告)号:US20220062875A1
公开(公告)日:2022-03-03
申请号:US17523485
申请日:2021-11-10
Inventor: Mark E. Davis , Stephen Kramer Brand , Joel E. Schmidt , Michael W. Deem
IPC: B01J29/04 , B01J31/02 , C07D233/66 , B01J35/00
Abstract: This disclosure describes enantiomerically enriched chiral molecular sieves and methods of making and using the same. In some embodiments, the molecular sieves are silicates or germanosilicates of STW topology.
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2.
公开(公告)号:US20190083962A1
公开(公告)日:2019-03-21
申请号:US16189564
申请日:2018-11-13
Applicant: California Institute Of Technology
Inventor: Joel E. Schmidt , Mark E. Davis , Ben W. Boal , Jong Hun Kang
IPC: B01J29/04 , C07D301/12 , B01J35/00 , C10G29/20 , C10G35/06 , C10G45/04 , C10G45/60 , C10G45/68 , C10G50/00 , C10G3/00 , C10G11/02 , C01B39/08 , C07C1/20 , C07C6/12 , C01B39/00 , B01J20/10 , B01J20/30 , C10G2/00 , C10G47/04 , C07C7/13 , C07C2/10 , C07C2/66 , C07C5/22 , C07C5/41
Abstract: The present disclosure is directed to the use of novel crystalline germanosilicate compositions in affecting a range of organic transformations. In particular, the crystalline germanosilicate compositions are extra-large-pore compositions, designated CIT-13 possessing 10- and 14-membered rings.
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公开(公告)号:US09908783B2
公开(公告)日:2018-03-06
申请号:US14602415
申请日:2015-01-22
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor: Joel E. Schmidt , Mark E. Davis
IPC: B01J29/70 , C01B39/48 , C01B39/08 , C01B39/06 , B01J29/068 , C01B39/12 , B01J29/064 , B01J29/06 , B01J29/86 , B01J29/89 , B01J29/072 , B01J29/87 , B01J29/88 , B01J29/04 , B01J37/08 , C01B39/00 , C07C1/20 , B01D53/02 , C07C2/00 , C07C2/12 , C07C5/25 , C07C5/27 , C07C6/06 , C07C7/13 , C07C209/14 , C10G11/05 , C10G35/00 , C10G47/04 , C07C209/16 , C10G29/20 , C10G35/06 , C10G47/16 , C10G49/08 , C10G50/00 , B01J29/035 , C07C67/37 , B01J29/85
CPC classification number: C01B39/48 , B01D53/02 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/20 , B01D2256/12 , B01D2257/102 , B01D2257/404 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/70 , B01J29/7015 , B01J29/85 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , B01J37/08 , B01J37/082 , C01B39/00 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/082 , C01B39/085 , C01B39/087 , C01B39/12 , C07C1/20 , C07C2/00 , C07C2/12 , C07C5/2518 , C07C5/2737 , C07C5/2775 , C07C6/06 , C07C7/13 , C07C67/37 , C07C209/14 , C07C209/16 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/00 , C10G35/065 , C10G47/04 , C10G47/16 , C10G49/08 , C10G50/00 , Y02P30/42 , C07C211/04 , C07C69/14 , C07C11/02
Abstract: This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having RTH topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation structuring agents.
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公开(公告)号:US09861968B2
公开(公告)日:2018-01-09
申请号:US14602449
申请日:2015-01-22
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor: Joel E. Schmidt , Mark E. Davis
IPC: C01B39/46 , B01J29/70 , C01B39/48 , C01B39/08 , C01B39/06 , B01J29/068 , C01B39/12 , B01J29/064 , B01J29/06 , B01J29/86 , B01J29/89 , B01J29/072 , B01J29/87 , B01J29/88 , B01J29/04 , B01J37/08 , C01B39/00 , C07C1/20 , B01D53/02 , C07C2/00 , C07C2/12 , C07C5/25 , C07C5/27 , C07C6/06 , C07C7/13 , C07C209/14 , C10G11/05 , C10G35/00 , C10G47/04 , C07C209/16 , C10G29/20 , C10G35/06 , C10G47/16 , C10G49/08 , C10G50/00 , B01J29/035 , C07C67/37 , B01J29/85
CPC classification number: C01B39/48 , B01D53/02 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/20 , B01D2256/12 , B01D2257/102 , B01D2257/404 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/70 , B01J29/7015 , B01J29/85 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , B01J37/08 , B01J37/082 , C01B39/00 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/082 , C01B39/085 , C01B39/087 , C01B39/12 , C07C1/20 , C07C2/00 , C07C2/12 , C07C5/2518 , C07C5/2737 , C07C5/2775 , C07C6/06 , C07C7/13 , C07C67/37 , C07C209/14 , C07C209/16 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/00 , C10G35/065 , C10G47/04 , C10G47/16 , C10G49/08 , C10G50/00 , Y02P30/42 , C07C211/04 , C07C69/14 , C07C11/02
Abstract: This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having HEU topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation structuring agents.
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5.
公开(公告)号:US20190247835A1
公开(公告)日:2019-08-15
申请号:US16395912
申请日:2019-04-26
Applicant: California Institute Of Technology
Inventor: Joel E. Schmidt , Mark E. Davis , Ben W. Boal , Jong Hun Kang
Abstract: The present disclosure is directed to novel crystalline germanosilicate compositions and methods of producing the same. In particular, the crystalline germanosilicate compositions are extra-large-pore compositions, designated CIT-13 possessing 10- and 14-membered rings. The disclosure describes methods of preparing these compositions using substituted benzyl-imidazolium organic structure-directing agents (OSDAs). Also disclosed are methods of using these crystalline compositions.
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公开(公告)号:US09873113B2
公开(公告)日:2018-01-23
申请号:US14602433
申请日:2015-01-22
Applicant: California Institute of Technology
Inventor: Joel E. Schmidt , Mark E. Davis
IPC: C01B39/48 , B01J29/70 , C01B39/08 , C01B39/06 , B01J29/068 , C01B39/12 , B01J29/064 , B01J29/06 , B01J29/86 , B01J29/89 , B01J29/072 , B01J29/87 , B01J29/88 , B01J29/04 , B01J37/08 , C01B39/00 , C07C1/20 , B01D53/02 , C07C2/00 , C07C2/12 , C07C5/25 , C07C5/27 , C07C6/06 , C07C7/13 , C07C209/14 , C10G11/05 , C10G35/00 , C10G47/04 , C07C209/16 , C10G29/20 , C10G35/06 , C10G47/16 , C10G49/08 , C10G50/00 , B01J29/035 , C07C67/37 , B01J29/85
CPC classification number: C01B39/48 , B01D53/02 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/20 , B01D2256/12 , B01D2257/102 , B01D2257/404 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/70 , B01J29/7015 , B01J29/85 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , B01J37/08 , B01J37/082 , C01B39/00 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/082 , C01B39/085 , C01B39/087 , C01B39/12 , C07C1/20 , C07C2/00 , C07C2/12 , C07C5/2518 , C07C5/2737 , C07C5/2775 , C07C6/06 , C07C7/13 , C07C67/37 , C07C209/14 , C07C209/16 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/00 , C10G35/065 , C10G47/04 , C10G47/16 , C10G49/08 , C10G50/00 , Y02P30/42 , C07C211/04 , C07C69/14 , C07C11/02
Abstract: This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having CIT-7 topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation structuring agents.
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公开(公告)号:US09821297B2
公开(公告)日:2017-11-21
申请号:US15063867
申请日:2016-03-08
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor: Ben W. Boal , Mark E. Davis , Joel E. Schmidt
IPC: C01B39/14 , C01B37/02 , B01J29/70 , B01J29/85 , B01J29/89 , B01J29/04 , C01B37/00 , C07C1/20 , C07D301/12 , B01J35/00 , B01J35/02 , B01D53/94
CPC classification number: B01J29/047 , B01D53/9413 , B01D2255/20707 , B01D2255/50 , B01J29/70 , B01J29/7003 , B01J29/7007 , B01J29/7015 , B01J29/85 , B01J29/89 , B01J35/002 , B01J35/023 , C01B37/005 , C01B37/02 , C01B39/145 , C07C1/20 , C07C2523/08 , C07C2529/70 , C07C2529/89 , C07D301/12 , Y02P20/52 , Y02P30/42 , C07C11/02 , C07C11/04 , C07C11/08
Abstract: The present disclosure is directed to processing for preparing crystalline pure-silica and heteroatom-substituted LTA frameworks in fluoride media using a simple organic structure-directing agent (OSDA), having a structure of Formula (I): where substituents R1 to R9 are defined herein. Aluminosilicate LTA is an active catalyst for the methanol to olefins reaction with higher product selectivities to butenes as well as C5 and C6 products than the commercialized catalysts. Titanosilicate LTA is an active catalyst for the epoxidation of allyl alcohol using aqueous H2O2.
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公开(公告)号:US09782759B2
公开(公告)日:2017-10-10
申请号:US14602457
申请日:2015-01-22
Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventor: Joel E. Schmidt , Mark E. Davis
IPC: C01B39/48 , B01J29/70 , B01J29/04 , B01J37/08 , C01B39/00 , C07C1/20 , B01D53/02 , C07C2/00 , C07C2/12 , C07C5/25 , C07C5/27 , C07C6/06 , C07C7/13 , C07C209/14 , C10G11/05 , C10G35/00 , C10G47/04 , C07C209/16 , C10G29/20 , C10G35/06 , C10G47/16 , C10G49/08 , C10G50/00 , B01J29/035 , C07C67/37 , B01J29/85
CPC classification number: C01B39/48 , B01D53/02 , B01D2253/106 , B01D2253/108 , B01D2253/1085 , B01D2253/1124 , B01D2253/20 , B01D2256/12 , B01D2257/102 , B01D2257/404 , B01J29/035 , B01J29/041 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/70 , B01J29/7015 , B01J29/85 , B01J29/86 , B01J29/87 , B01J29/88 , B01J29/89 , B01J37/08 , B01J37/082 , C01B39/00 , C01B39/06 , C01B39/065 , C01B39/08 , C01B39/082 , C01B39/085 , C01B39/087 , C01B39/12 , C07C1/20 , C07C2/00 , C07C2/12 , C07C5/2518 , C07C5/2737 , C07C5/2775 , C07C6/06 , C07C7/13 , C07C67/37 , C07C209/14 , C07C209/16 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G35/00 , C10G35/065 , C10G47/04 , C10G47/16 , C10G49/08 , C10G50/00 , Y02P30/42 , C07C211/04 , C07C69/14 , C07C11/02
Abstract: This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having IWV topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation templates.
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公开(公告)号:US11642665B2
公开(公告)日:2023-05-09
申请号:US17523485
申请日:2021-11-10
Inventor: Mark E. Davis , Stephen Kramer Brand , Joel E. Schmidt , Michael W. Deem
CPC classification number: B01J29/047 , B01J31/0244 , B01J35/002 , C07D233/66 , C07B2200/07 , C07C2529/04 , G01N23/20075 , G01R33/46
Abstract: This disclosure describes enantiomerically enriched chiral molecular sieves and methods of making and using the same. In some embodiments, the molecular sieves are silicates or germanosilicates of STW topology.
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10.
公开(公告)号:US11213807B2
公开(公告)日:2022-01-04
申请号:US17147866
申请日:2021-01-13
Applicant: California Institute Of Technology
Inventor: Joel E. Schmidt , Mark E. Davis , Ben W. Boal , Jong Hun Kang
IPC: C01B39/02 , B01J29/70 , B01J29/04 , C01B39/06 , C01B39/08 , C01B39/48 , B01J35/00 , B01J37/08 , B01J37/10 , B01J37/30 , C01B39/46
Abstract: The present disclosure is directed to novel germanosilicate compositions and methods of producing the same. In particular, this disclosure describes new silica-rich compositions of the germanosilicate designated CIT-13, with and without added metal oxides. The disclosure also describes methods of preparing and using these new germanosilicate compositions as well as the compositions themselves.
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