公开(公告)号：US20200269211A1

公开(公告)日：2020-08-27

申请号：US16646357

申请日：2018-09-12

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  ÉCOLE NORMALE SUPÉRIEURE DE PARIS ,  ÉCOLE SUPÉRIEURE DE PHYSIQUE ET DE CHIMIE INDUSTRIELLES DE LA VILLE DE PARIS ,  UNIVERSITÉ DE VERSAILLES - SAINT-QUENTIN-EN-YVELINES ,  INSTITUTO SUPERIOR TÉCNICO

发明人： Christian SERRE ,  Moisés L. PINTO

IPC分类号： B01J20/22 ,  B01D53/04 ,  B01J20/28

摘要： The present invention relates, inter alia, to the use of porous crystalline solids constituted of a metal-organic framework (MOF) for the capture of polar volatile organic compounds (VOCs). In particular, the MOF of interest are material comprising an average pores sizes of 0.4 to 0.6 nm and an hydrophobic core formed by a metal oxide and/or hydroxide network connected by linkers, said linkers being selected from the group comprising (i) C6-C24 aromatic polycarboxylate linkers, such as benzyl or naphtyl di-, tri- or tetracarboxylate, and (ii) C6-C16 polycarboxylate aliphatic linkers; the linkers bearing or not apolar fluorinated groups, e.g. —(CF2)n—CF3 groups, n being a integer from 0 to 5, preferably 0 ou 3, and/or apolar C1-C20 preferably C1-C4 alkyl groups, e.g. —CH3 or —CH2—CH3, grafted directly to the linkers and pointing within the pores of the MOF. The MOF solids used in the present invention can be used for the purification of air, for example for the capture of polar VOCs like acetic acid and aldehydes from indoor air in cars, museums and archives, much more efficiently than common adsorbents, particularly in presence of above normal levels of humidity. They can in particular be used for the preservation of cultural heritage.

公开(公告)号：US20220081377A1

公开(公告)日：2022-03-17

申请号：US17421447

申请日：2020-01-07

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  INSTITUTO POLITÉCNICO DE BRAGANÇA ,  ÉCOLE SUPÉRIEURE DE PHYSIQUE ET DE CHIMIE INDUSTRIELLES DE LA VILLE DE PARIS ,  ÉCOLE NORMALE SUPÉRIEURE DE PARIS ,  UNIVERSIDADE DO PORTO

发明人： Christian SERRE ,  Farid NOUAR ,  José SILVA ,  Alírio RODRIGUES ,  Pedro BRÂNTUAS

IPC分类号： C07C7/12 ,  B01J20/22 ,  B01J20/16

摘要： The present invention relates to the use of 2,5-furanedicarboxylate-based MOFs, such as, MIL-160(Al) metal-organic framework, for separating C6 alkane isomers into linear, mono-branched and di-branched isomers. The present invention also relates to the use of 2,5-furanedicarboxylate-based MOFs, such as, MIL-160(Al) metal-organic framework, preferably in combination with Zeolite 5A for producing higher research octane number gasoline blends. Also within the scope of the invention is a system for separating C6 and C5 alkane isomer mixtures into linear, mono-branched and di-branched fractions.

公开(公告)号：US20230001380A1

公开(公告)日：2023-01-05

申请号：US17774430

申请日：2020-11-04

申请人： École Nationale Supérieure d'Ingénieurs de Caen ,  Université de Caen Normandie ,  Centre National de la Recherche Scientifique ,  École Supérieure de Physique et de Chimie Industrielles de la Ville de Paris ,  École Normale Supérieure de Paris ,  TEQOYA SAS

发明人： Marco DATURI ,  Pierre GUITTON ,  Farid NOUAR ,  Nicolas SADOVNIK ,  Christian SERRE

IPC分类号： B01J20/22 ,  B01D53/81 ,  B01D53/96 ,  B01D53/72 ,  B01J20/28 ,  B01J20/20 ,  B01J20/18 ,  B01J20/34

摘要： The present invention relates, inter alia, to the use of porous crystalline solids constituted of a metal-organic framework (MOF) for the selective adsorption of aldehyde volatile organic compounds.
The MOF solids of the present invention can be used for the improved purification of dry or humid air, and for the manufacture of regenerable filters for air purification, particularly leak-free regenerable air filters.

公开(公告)号：US20190248814A1

公开(公告)日：2019-08-15

申请号：US16308686

申请日：2017-06-08

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITÉ DE VERSAILLES - SAINT-QUENTIN-EN- YVELINES

发明人： Sujing WANG ,  Christian SERRE ,  Nathalie GUILLOU ,  Nathalie STEUNOU

IPC分类号： C07F7/28 ,  B01J31/16 ,  B01J35/10 ,  B01J37/04 ,  B01J20/22 ,  B01J20/28 ,  B01J20/30 ,  F17C11/00 ,  C09K9/02 ,  H01M8/1016 ,  A61K47/24

CPC分类号： C07F7/28 ,  A61K47/24 ,  B01J20/226 ,  B01J20/28061 ,  B01J20/28064 ,  B01J20/28066 ,  B01J20/28071 ,  B01J20/28073 ,  B01J20/28076 ,  B01J20/3085 ,  B01J31/1691 ,  B01J31/2226 ,  B01J31/2239 ,  B01J35/004 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J37/04 ,  B01J2531/0216 ,  B01J2531/46 ,  C07F7/003 ,  C09K9/02 ,  C09K2211/183 ,  F17C11/00 ,  H01M8/1016 ,  H01M2300/0065 ,  Y02E60/321

摘要： The present invention relates to a water-stable Titanium-based metal-organic framework (MOF) material having a high degree of condensation, i.e. an oxo to Ti ratio (or oxo to metal ratio, in the case of doped Ti-based MOFs) >1.0; a process of preparing same and uses thereof, particularly for heterogeneously catalyzed chemical reactions, for gas storage/separation/purification, for information storage, laser printing or as an oxygen indicator, or as proton conductive material (fuel cells), optoelectronic material (photovoltaic cells including Grätzel cells), as a matrix for encapsulating active principles (medicaments, cosmetics), or else as sensing material.

公开(公告)号：US20180346500A1

公开(公告)日：2018-12-06

申请号：US16046668

申请日：2018-07-26

申请人： CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE- CNRS ,  UNIVERSITÉ DE VERSAILLES - SAINT-QUENTIN-EN- YVELINES

发明人： Patricia HORCAJADA-CORTES ,  Gérard FEREY ,  Christian SERRE ,  Ruxandra GREF ,  Patrick COUVREUR

IPC分类号： C07F15/02

摘要： The invention relates to nanoparticles made from organometallic hybrid materials made from iron carboxylates, used for example as contrast agents. The particles can also be used for the encapsulation and vectoring of molecules of interest such as active3 pharmaceutical agents, cosmetically interesting compounds and markers. Apart from the intrinsic properties thereof for imaging, said nanoparticles give good results in terms of capacity of loading with medicaments and in biocompatibility.

公开(公告)号：US20160101192A1

公开(公告)日：2016-04-14

申请号：US14878421

申请日：2015-10-08

申请人： COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVE (CEA) ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS) ,  UNIVERSITE VERSAILLES SAINT-QUENTIN-EN-YVELINES ,  UNIVERSITE PARIS-SUD 11

发明人： Thomas BERTHELOT ,  Elena BELLIDO VERA ,  Ruxandra GREF ,  Patricia HORCAJADA CORTES ,  Christian SERRE ,  Patrick COUVREUR

IPC分类号： A61K47/48 ,  A61L31/16 ,  A61K8/81 ,  A61L31/04 ,  A61K31/522 ,  A61K8/02

CPC分类号： A61K47/48869 ,  A61K8/0279 ,  A61K8/8152 ,  A61K31/522 ,  A61K47/58 ,  A61K47/6923 ,  A61K47/6925 ,  A61K2800/614 ,  A61L31/048 ,  A61L31/16 ,  A61Q19/00 ,  C07F15/02 ,  C08F220/10 ,  C08L71/02 ,  C09D4/00 ,  C09D133/06 ,  C09J4/00 ,  C09J133/06

摘要： A process for preparing a porous solid with an outer surface modified by at least one polymer; the polymer being simultaneously synthetized in solution and grafted on the outer surface of the solid, includes contacting: a porous solid; and a polymer-precursor solution comprising an adhesion primer, and at least one polymerizable monomer; under conditions enabling the formation of radical entities.

摘要翻译： 一种制备具有由至少一种聚合物改性的外表面的多孔固体的方法; 聚合物同时在溶液中合成并接枝在固体的外表面上，包括接触：多孔固体; 和包含粘合底漆和至少一种可聚合单体的聚合物 - 前体溶液; 在能够形成激进实体的条件下。