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公开(公告)号:US11440266B2
公开(公告)日:2022-09-13
申请号:US16204141
申请日:2018-11-29
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: C08G18/42 , B29C64/129 , B29C64/40 , C08K3/013 , C08K3/01 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B29C71/00 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , C09D175/08 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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2.
公开(公告)号:US20210024775A1
公开(公告)日:2021-01-28
申请号:US17068962
申请日:2020-10-13
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert K. Pinschmidt, JR. , Joseph M. DeSimone , Lloyd M. Robeson
IPC: C09D175/08 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08G18/42 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02
Abstract: A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.
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公开(公告)号:US10899868B2
公开(公告)日:2021-01-26
申请号:US16803047
申请日:2020-02-27
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert K. Pinschmidt, Jr. , Joseph M. DeSimone , Lloyd M. Robeson
IPC: C08F2/46 , C08F2/50 , C08G61/04 , C08G18/42 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , C09D175/08 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object, wherein said three-dimensional object is a footwear sole, heel, innersole or midsole, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.
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公开(公告)号:US20190322785A1
公开(公告)日:2019-10-24
申请号:US16474987
申请日:2018-01-03
Applicant: Carbon, Inc.
Inventor: Matthew S. Menyo , Lloyd M. Robeson
IPC: C08F222/26 , C08L33/14 , B33Y10/00 , B33Y70/00 , B29C64/124 , B29C64/35 , B33Y40/00
Abstract: Provided herein according to some embodiments is a dual cure stereolithography resin that includes a Diels-Alder adduct, which adduct is light polymerizable in the first, light, cure to produce an intermediate object, and on heating the intermediate object yields a bis-maleimide that can further react and/or polymerize during the second, heat, cure.
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公开(公告)号:US10240066B2
公开(公告)日:2019-03-26
申请号:US15428708
申请日:2017-02-09
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C71/02 , B29C71/04 , C09D175/08 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C64/124 , B29C64/135 , B29C64/386 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object of polyurethane, polyurea, or copolymer thereof is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including at least one of: (i) a blocked or reactive blocked prepolymer, (ii) a blocked or reactive blocked diisocyante, or (iii) a blocked or reactive blocked diisocyanate chain extender; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the chain extender; and then (d) heating or microwave irradiating the three-dimensional intermediate sufficiently to form from the three-dimensional intermediate the three-dimensional object of polyurethane, polyurea, or copolymer thereof.
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公开(公告)号:US11358342B2
公开(公告)日:2022-06-14
申请号:US16556404
申请日:2019-08-30
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C64/40 , B29C64/129 , C08K3/013 , C08K3/01 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08G18/42 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B29C71/00 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , C09D175/08 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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7.
公开(公告)号:US20190390081A1
公开(公告)日:2019-12-26
申请号:US16556404
申请日:2019-08-30
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: C09D175/08 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US10434706B2
公开(公告)日:2019-10-08
申请号:US16289991
申请日:2019-03-01
Applicant: Carbon, Inc.
Inventor: Lloyd M. Robeson , Edward T. Samulski , Alexander Ermoshkin , Joseph M. DeSimone
IPC: B29C64/124 , B29C64/20 , B33Y30/00 , B33Y10/00 , B33Y70/00 , B29C64/129
Abstract: A method of forming a three-dimensional object is carried out by: providing a carrier and a pool of immiscible liquid, the pool having a liquid build surface, the carrier and the liquid build surface defining a build region therebetween; filling the build region with a polymerizable liquid, wherein the immiscible liquid is immiscible with the polymerizable liquid (in some embodiments wherein the immiscible liquid has a density greater than the polymerizable liquid); irradiating the build region through at least a portion of the pool of immiscible liquid to form a solid polymer from the polymerizable liquid and advancing the carrier away from the liquid build surface to form the three-dimensional object comprised of the solid polymer from the polymerizable liquid. Optionally, but in some embodiments preferably, the method is carried out while also continuously maintaining a gradient of polymerization zone between the liquid build surface and the solid polymer and in contact with each thereof, the gradient of polymerization zone comprising the polymerizable liquid in partially cured form.
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公开(公告)号:US10259171B2
公开(公告)日:2019-04-16
申请号:US15302843
申请日:2015-04-20
Applicant: Carbon, Inc.
Inventor: Lloyd M. Robeson , Edward T. Samulski , Alexander Ermoshkin , Joseph M. DeSimone
IPC: B29C64/124 , B29C67/00 , B33Y70/00 , B33Y10/00 , B33Y30/00 , B29C64/129 , B29C64/20
Abstract: A method of forming a three-dimensional object is carried out by: providing a carrier and a pool of immiscible liquid, the pool having a liquid build surface, the carrier and the liquid build surface defining a build region therebetween; filling the build region with a polymerizable liquid, wherein the immiscible liquid is immiscible with the polymerizable liquid (in some embodiments wherein the immiscible liquid has a density greater than the polymerizable liquid); irradiating the build region through at least a portion of the pool of immiscible liquid to form a solid polymer from the polymerizable liquid and advancing the carrier away from the liquid build surface to form the three-dimensional object comprised of the solid polymer from the polymerizable liquid. Optionally, but in some embodiments preferably, the method is carried out while also continuously maintaining a gradient of polymerization zone between the liquid build surface and the solid polymer and in contact with each thereof, the gradient of polymerization zone comprising the polymerizable liquid in partially cured form.
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10.
公开(公告)号:US20180361660A1
公开(公告)日:2018-12-20
申请号:US16060568
申请日:2016-12-19
Applicant: Carbon, Inc.
Inventor: Kai Chen , Lloyd M. Robeson , Jason P. Rolland
IPC: B29C64/135 , B29C64/245 , B29C64/393
CPC classification number: B29C64/135 , B29C64/245 , B29C64/393 , B29K2075/02 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00
Abstract: Provided herein is a method of forming a three-dimensional object, comprising: (a) providing a carrier and a fill level having a build region therebetween; (b) filling said build region with a polymerizable liquid comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component; (c) irradiating said build region with light to form a solid polymer scaffold from said first component and also advancing said carrier away from said build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, said three-dimensional object and containing said second solidifiable component carried in said scaffold in unsolidified and/or uncured form; and (d) solidifying and/or curing said second solidifiable component in said three-dimensional intermediate. The solidifying and/or curing step (d) may increase the elasticity and/or decrease the rigidity of said intermediate in forming said three-dimensional object.
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