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公开(公告)号:US11358342B2
公开(公告)日:2022-06-14
申请号:US16556404
申请日:2019-08-30
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C64/40 , B29C64/129 , C08K3/013 , C08K3/01 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08G18/42 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B29C71/00 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , C09D175/08 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US10975193B2
公开(公告)日:2021-04-13
申请号:US15754681
申请日:2016-09-02
Applicant: Carbon, Inc.
Inventor: Julia D. Cushen , James Goodrich , Jason P. Rolland
IPC: C08G59/68 , B33Y10/00 , B33Y70/00 , B29C64/124 , B29C64/35 , B33Y40/20 , B29C71/04 , C08J5/00 , C08L63/00 , B29K63/00 , B29K105/00 , B29K421/00
Abstract: An epoxy dual cure resin useful for additive manufacturing of three-dimensional objects includes: (i) a photoinitiator; (ii) monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light; (iii) optionally, a light absorbing pigment or dye; (iv) an epoxy resin; (v) optionally, but in some embodiments preferably, an organic hardener co-polymerizable with the epoxy resin; (vi) optionally but preferably a dual reactive compound having substituted thereon a first reactive group reactive with said monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light, and a second reactive group reactive with said epoxy resin (e.g., an epoxy acrylate); (vii) optionally a diluent; (viii) optionally a filler; and (ix) optionally, a co-monomer and/or a co-prepolymer. Methods of using the same in additive manufacturing are also described.
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公开(公告)号:US20190390081A1
公开(公告)日:2019-12-26
申请号:US16556404
申请日:2019-08-30
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: C09D175/08 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US10155882B2
公开(公告)日:2018-12-18
申请号:US15587865
申请日:2017-05-05
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C67/00 , C09D175/08 , C08K3/013 , C08K3/01 , G03F7/00 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C64/124 , B29C64/135 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US12179435B2
公开(公告)日:2024-12-31
申请号:US17662706
申请日:2022-05-10
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C64/165 , B29C35/08 , B29C64/106 , B29C64/124 , B29C64/129 , B29C64/135 , B29C64/255 , B29C64/286 , B29C64/386 , B29C64/40 , B29C71/00 , B29D11/00 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00 , B33Y80/00 , C08F220/34 , C08F283/00 , C08F290/06 , C08G18/10 , C08G18/24 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/69 , C08G18/73 , C08G18/75 , C08G18/76 , C08G18/81 , C08J5/00 , C08K3/01 , C08K3/013 , C08K5/00 , C08L75/04 , C08L75/14 , C09D135/02 , C09D175/04 , C09D175/08 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C33/00 , B29K75/00 , B29K105/00 , B29K105/04 , B29K105/16 , B29K509/00 , B29L11/00 , B29L31/00 , B29L31/10
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US11850803B2
公开(公告)日:2023-12-26
申请号:US17655275
申请日:2022-03-17
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C71/02 , B29C71/04 , B29C64/40 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , G03F7/027 , G03F7/038 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08G18/42 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B29C71/00 , B29C64/286 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , C09D175/08 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K105/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/16 , B29K509/00 , B29L31/00
CPC classification number: B29C64/40 , B29C35/0805 , B29C64/106 , B29C64/124 , B29C64/129 , B29C64/135 , B29C64/165 , B29C64/255 , B29C64/286 , B29C64/386 , B29C71/0009 , B29D11/00009 , B29D11/00663 , B33Y10/00 , B33Y30/00 , B33Y50/02 , B33Y70/00 , B33Y80/00 , C08F220/34 , C08F283/006 , C08F290/067 , C08G18/10 , C08G18/244 , C08G18/40 , C08G18/42 , C08G18/4825 , C08G18/4854 , C08G18/69 , C08G18/73 , C08G18/755 , C08G18/758 , C08G18/7671 , C08G18/81 , C08G18/8175 , C08J5/00 , C08K3/01 , C08K3/013 , C08K5/0008 , C08K5/0041 , C08L75/04 , C08L75/14 , C09D135/02 , C09D175/04 , C09D175/08 , G03F7/00 , G03F7/0037 , G03F7/027 , G03F7/038 , G03F7/0757 , G03F7/38 , B29C2033/0005 , B29C2035/0827 , B29C2035/0855 , B29K2075/00 , B29K2075/02 , B29K2105/0002 , B29K2105/0058 , B29K2105/0073 , B29K2105/0091 , B29K2105/043 , B29K2105/16 , B29K2105/251 , B29K2509/00 , B29K2995/0026 , B29L2011/00 , B29L2011/0016 , B29L2011/0075 , B29L2031/001 , B29L2031/10 , C08J2375/14 , C08F283/006 , C08F222/102 , C08F222/1063 , C08F290/067 , C08F222/102 , C08F222/1063 , C08F220/1808 , C08F290/067 , C08F222/102 , C08F220/1811 , C08G18/672 , C08G18/48 , C08F290/067 , C08F222/102 , C08F222/1063
Abstract: A method of forming a three-dimensional object (e.g. comprised of polyurethane, polyurea, or copolymer thereof) is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid comprising a mixture of: (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the second solidifiable component; and then (d) contacting the three-dimensional intermediate to water to form the three-dimensional object.
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公开(公告)号:US20230001634A1
公开(公告)日:2023-01-05
申请号:US17662706
申请日:2022-05-10
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C64/165 , B29C64/286 , B33Y10/00 , B33Y70/00
Abstract: A method of forming a three-dimensional object is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from the first component; (c) irradiating the build region with light through the optically transparent member to form a solid polymer scaffold from the first component and also advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, and containing the second solidifiable component carried in the scaffold in unsolidified and/or uncured form; and (d) concurrently with or subsequent to the irradiating step, solidifying and/or curing the second solidifiable component in the three-dimensional intermediate to form the three-dimensional object.
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公开(公告)号:US20210198419A1
公开(公告)日:2021-07-01
申请号:US17192768
申请日:2021-03-04
Applicant: Carbon, Inc.
Inventor: Julia D. Cushen , James Goodrich , Jason P. Rolland
IPC: C08G59/68 , B33Y10/00 , B33Y70/00 , B29C64/124 , B29C64/35 , B33Y40/20 , B29C71/04 , C08J5/00 , C08L63/00
Abstract: An epoxy dual cure resin useful for additive manufacturing of three-dimensional objects includes: (i) a photoinitiator; (ii) monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light; (iii) optionally, a light absorbing pigment or dye; (iv) an epoxy resin; (v) optionally, but in some embodiments preferably, an organic hardener co-polymerizable with the epoxy resin; (vi) optionally but preferably a dual reactive compound having substituted thereon a first reactive group reactive with said monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light, and a second reactive group reactive with said epoxy resin (e.g., an epoxy acrylate); (vii) optionally a diluent; (viii) optionally a filler; and (ix) optionally, a co-monomer and/or a co-prepolymer. Methods of using the same in additive manufacturing are also described.
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公开(公告)号:US20200223992A1
公开(公告)日:2020-07-16
申请号:US15754681
申请日:2016-09-02
Applicant: Carbon, Inc.
Inventor: Julia D. Cushen , James Goodrich , Jason P. Rolland
Abstract: An epoxy dual cure resin useful for additive manufacturing of three-dimensional objects includes:(i) a photoinitiator; (ii) monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light; (iii) optionally, a light absorbing pigment or dye; (iv) an epoxy resin; (v) optionally, but in some embodiments preferably, an organic hardener co-polymerizable with the epoxy resin; (vi) optionally but preferably a dual reactive compound having substituted thereon a first reactive group reactive with said monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light, and a second reactive group reactive with said epoxy resin (e.g., an epoxy acrylate); (vii) optionally a diluent; (viii) optionally a filler; and (ix) optionally, a co-monomer and/or a co-prepolymer. Methods of using the same in additive manufacturing are also described.
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公开(公告)号:US10647880B2
公开(公告)日:2020-05-12
申请号:US16269710
申请日:2019-02-07
Applicant: Carbon, Inc.
Inventor: Jason P. Rolland , Kai Chen , Justin Poelma , James Goodrich , Robert Pinschmidt , Joseph M. DeSimone , Lloyd M. Robeson
IPC: B29C71/02 , B29C71/04 , C09D175/08 , C08K3/013 , C08K3/01 , B29C64/129 , G03F7/00 , G03F7/038 , G03F7/027 , G03F7/075 , G03F7/38 , B29C64/124 , B29C64/135 , B29C64/386 , C08G18/81 , C08G18/10 , C08G18/76 , C08F220/34 , C08G18/42 , C08F290/06 , C08G18/73 , C08G18/48 , C08G18/24 , C08G18/69 , C08G18/75 , C08F283/00 , C08G18/40 , B33Y10/00 , B33Y70/00 , B29D11/00 , B29C35/08 , C08K5/00 , C08L75/04 , B33Y80/00 , C09D135/02 , C09D175/04 , B29C64/255 , B29C64/106 , B29C64/165 , B33Y30/00 , C08J5/00 , C08L75/14 , B33Y50/02 , B29C33/00 , B29K75/00 , B29K105/04 , B29L11/00 , B29L31/10 , B29K105/00 , B29K105/16 , B29K509/00 , B29L31/00
Abstract: A method of forming a three-dimensional object of polyurethane, polyurea, or copolymer thereof is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including at least one of: (i) a blocked or reactive blocked prepolymer, (ii) a blocked or reactive blocked diisocyanate, or (iii) a blocked or reactive blocked diisocyanate chain extender; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the chain extender; and then (d) heating or microwave irradiating the three-dimensional intermediate sufficiently to form from the three-dimensional intermediate the three-dimensional object of polyurethane, polyurea, or copolymer thereof.
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