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公开(公告)号:US20240246819A1
公开(公告)日:2024-07-25
申请号:US18564223
申请日:2022-05-25
Applicant: CASALE SA
Inventor: Raffaele OSTUNI , Pierdomenico BIASI , Alberto GARBUJO , Nicola PANZERI , Fabio OLDANI , Michal Tadeusz BIALKOWSKI
Abstract: A process for the synthesis of nitric acid comprising the steps of treating ammonia in presence of oxygen or air to a catalytic oxidation step to yield a combusted gas, subjecting the combusted gas to a catalytic decomposition step to yield a N2O depleted gas stream, subjecting the N2O depleted gas stream to a cooling step to yield a cooled stream and subjecting said cooled stream to an absorption step in presence of water to yield a nitric acid and a tail gas retaining NOx; the catalytic decomposition step is carried out at a temperature comprises between 450° C. and 700° C. on one or more iron zeolites catalyst deposited, coated, or coextruded onto a catalyst support provided with gas permeable channels.
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公开(公告)号:US20200317534A1
公开(公告)日:2020-10-08
申请号:US16305351
申请日:2017-04-20
Applicant: CASALE SA
Inventor: Raffaele OSTUNI , Cristina FERRINI , Javier GOICOCHEA
Abstract: A process for the synthesis of ammonia from a make-up gas containing hydrogen and nitrogen, comprising at least two steps for the synthesis of ammonia, wherein: said reactive steps are performed in series and each of said reactive steps provides an ammonia-containing product gas; the second and any subsequent reactive step receives, as a feed stream, at least a portion of the product gas of the previous reactive step; an intermediate adsorptive step of ammonia is performed between consecutive reactive steps, so that the product gas of each step is depleted of ammonia prior to the subsequent reactive step of said series.
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3.
公开(公告)号:US20170284667A1
公开(公告)日:2017-10-05
申请号:US15631739
申请日:2017-06-23
Applicant: Casale SA
Inventor: Raffaele OSTUNI , Federico ZARDI
CPC classification number: F23J15/02 , B01D53/56 , B01D53/8625 , B01D53/8631 , B01D2251/2062 , C01C1/04 , C01C1/0405 , C25B1/04 , F23J15/006 , F23J2215/10 , F23J2219/10 , Y02E50/12 , Y02E60/366 , Y02P20/52 , Y10T29/49716
Abstract: A method for the control of nitrogen oxides content in the combustion fumes of a thermal power plant is disclosed; the method comprises the on-site production of ammonia by the steps of: electrolysis of water as a source of hydrogen; separation of air as a source of nitrogen, formation of a make-up gas and synthesis of ammonia in a suitable synthesis loop; said on-site produced ammonia, or a solution thereof, is used for a process of reduction of nitrogen oxides in the combustion fumes.
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公开(公告)号:US20160311680A1
公开(公告)日:2016-10-27
申请号:US15104448
申请日:2014-12-16
Applicant: CASALE SA
Inventor: Ermanno FILIPPI , Raffaele OSTUNI
CPC classification number: C01B3/025 , B01J7/02 , B01J19/0046 , B01J2219/0059 , B01J2219/00756 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/043 , C01B2203/046 , C01B2203/048 , C01B2203/143
Abstract: A process and a related equipment for producing ammonia synthesis gas from a hydrocarbon-containing feedstock (20), the process comprising the steps of: primary reforming with steam (21), secondary reforming with an oxidant stream (23), and purification of the effluent of said secondary reforming, said purification comprising a step of shift conversion (13) of carbon monoxide, wherein the synthesis gas (25) produced by said secondary reforming is subject to a medium-temperature shift over a copper-based catalyst, and the global steam to carbon ratio of the process is not greater than 2.
Abstract translation: 一种用于从含烃原料(20)生产氨合成气的方法和相关设备,该方法包括以下步骤:用蒸汽(21)进行一次重整,用氧化剂流(23)进行二次重整,并纯化 所述二次重整的流出物,所述纯化包括一氧化碳的转移转化(13)的步骤,其中由所述二次转化产生的合成气(25)经受铜基催化剂的中温转变,并且 全球蒸汽碳比过程不大于2。
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公开(公告)号:US20200290869A1
公开(公告)日:2020-09-17
申请号:US16887191
申请日:2020-05-29
Applicant: Casale SA
Inventor: Raffaele OSTUNI , Geoffrey Frederick SKINNER , Ermanno FILIPPI
IPC: C01B3/38 , C01B3/02 , C10K1/00 , C10J3/00 , C10J3/46 , B01D53/22 , B01J8/06 , C10J3/82 , F25J3/02
Abstract: Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.
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6.
公开(公告)号:US20190137098A1
公开(公告)日:2019-05-09
申请号:US16230548
申请日:2018-12-21
Applicant: Casale SA
Inventor: Raffaele OSTUNI , Federico ZARDI
Abstract: A method for the control of nitrogen oxides content in the combustion fumes of a thermal power plant is disclosed; the method comprises the on-site production of ammonia by the steps of: electrolysis of water as a source of hydrogen; separation of air as a source of nitrogen, formation of a make-up gas and synthesis of ammonia in a suitable synthesis loop; said on-site produced ammonia, or a solution thereof, is used for a process of reduction of nitrogen oxides in the combustion fumes.
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公开(公告)号:US20170283371A1
公开(公告)日:2017-10-05
申请号:US15508758
申请日:2015-08-05
Applicant: Casale SA
Inventor: Geoffrey Frederick Skinner , Raffaele OSTUNI
IPC: C07C273/10 , F01N5/02 , B01J7/00 , C01B3/02 , C01C1/04
CPC classification number: C07C273/10 , B01J7/00 , C01B3/025 , C01B2203/0233 , C01B2203/0244 , C01B2203/0255 , C01B2203/0283 , C01B2203/0288 , C01B2203/0415 , C01B2203/0475 , C01B2203/068 , C01B2203/0894 , C01B2203/142 , C01B2203/84 , C01C1/0405 , C01C1/0452 , C01C1/0488 , F01N5/02 , Y02P20/123 , Y02P20/129 , Y02P20/13 , Y02P20/52
Abstract: A process for producing ammonia and a derivative of ammonia from a natural gas feed comprising conversion of natural gas into a make-up synthesis gas; synthesis of ammonia; use of said ammonia to produce said derivative of ammonia, wherein a portion of the natural gas feed is used to fuel a gas engine; power produced by said gas engine; is transferred to at least one power user of the process, such as a compressor; heat is re-covered from exhaust gas of said gas engine;, and at least part of said heat may be recovered as low-grade heat available at a temperature not greater than 200° C., to provide process heating to at least one thermal user of the process, such as CO2 removal unit or absorption chiller; a corresponding plant and method of modernization are also disclosed.
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公开(公告)号:US20240359982A1
公开(公告)日:2024-10-31
申请号:US18291324
申请日:2022-06-09
Applicant: CASALE SA
Inventor: Matteo MANSATTI , Michele CORBETTA , Raffaele OSTUNI , Michal Tadeusz BIALKOWSKI , Fabio OLDANI
Abstract: An integrated process for the synthesis of ammonia and nitric acid, including the production of hydrogen from electrolysis of water, is controlled by a selective switching between a first mode of operation and a second mode of operation, wherein in the first mode of operation ammonia is produced in excess and is stored in a suitable ammonia storage: in the second mode of operation the ammonia from said ammonia storage is used to provide an additional input of ammonia to the production of nitric acid: the switching between said first mode and second mode is based on the amount of power which is transferred to the electrolysis of water.
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9.
公开(公告)号:US20210156560A1
公开(公告)日:2021-05-27
申请号:US17167168
申请日:2021-02-04
Applicant: Casale SA
Inventor: Raffaele OSTUNI , Federico ZARDI
Abstract: A method for the control of nitrogen oxides content in the combustion fumes of a thermal power plant is disclosed; the method comprises the on-site production of ammonia by the steps of: electrolysis of water as a source of hydrogen; separation of air as a source of nitrogen, formation of a make-up gas and synthesis of ammonia in a suitable synthesis loop; said on-site produced ammonia, or a solution thereof, is used for a process of reduction of nitrogen oxides in the combustion fumes.
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10.
公开(公告)号:US20180266758A1
公开(公告)日:2018-09-20
申请号:US15527989
申请日:2015-11-25
Applicant: Casale SA
Inventor: Ermanno Filippi , Raffaele OSTUNI
Abstract: Process for the synthesis of ammonia from a make-up gas containing hydrogen and nitrogen, said process comprising: generation of a synthesis gas (8) containing hydrogen and nitrogen in a molar ratio lower than 3, inside a front-end section (2); a first cryogenic purification, designed to remove nitrogen and raise said molar ratio; conversion of the synthesis gas into ammonia (13) inside a high-pressure synthesis loop (6), with extraction from said loop of a purge stream (14) containing hydrogen and inert gases; wherein at least a portion of said purge stream (14) undergoes a further purification in order to recover at least part of the hydrogen contained therein, obtaining at least one stream (15, 15a, 16, 18) containing recovered hydrogen which is recycled to the process.
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