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公开(公告)号：US07709580B2
公开(公告)日：2010-05-04
申请号：US11207366
申请日：2005-08-19
IPC分类号： C08F8/32
CPC分类号： C08F234/00 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F4/16
摘要： The present invention is directed to a method for preparation of polyolefins containing exo-olefin chain ends. The method involves quenching a cationic quasi-living polyolefin polymer system with a nitrogen-containing five-membered aromatic ring having at least two hydrocarbyl substituent compounds attached to the ring.
摘要翻译： 本发明涉及一种制备含有外烯烃链末端的聚烯烃的方法。 该方法包括用具有至少两个连接到该环上的烃基取代基化合物的含氮五元芳环淬灭阳离子准活性聚烯烃聚合物体系。
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公开(公告)号：US07420019B2
公开(公告)日：2008-09-02
申请号：US11207377
申请日：2005-08-19
IPC分类号： C08F8/32
CPC分类号： C08C19/22 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F4/16
摘要： The present invention is directed to a method for preparation of polyolefins containing exo-olefin chain ends. The method involves quenching a cationic quasi-living polyolefin polymer system with one or more hindered secondary or tertiary amines.
摘要翻译： 本发明涉及一种制备含有外烯烃链末端的聚烯烃的方法。 该方法包括用一个或多个受阻的仲胺或叔胺淬灭阳离子准活性聚烯烃聚合物体系。
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3.发明授权Method for preparing polyolefins containing a high percentage of exo-olefin chain ends 有权制备含有高百分比的外烯链末端的聚烯烃的方法公开(公告)号：US07705090B2
公开(公告)日：2010-04-27
申请号：US11207264
申请日：2005-08-19
IPC分类号： C08F8/32
CPC分类号： C08F8/26 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F2500/03
摘要： The present invention is directed to a method for preparing polyolefins containing a high percentage of exo-olefin chain ends. The method involves ionizing a polyolefin containing tert-chloride chain ends and reacting the ionized polyolefin with one or more nitrogen-containing five-membered aromatic ring or one or more hindered secondary or tertiary amines, or mixtures thereof.
摘要翻译： 本发明涉及一种制备含有高百分比的外烯链末端的聚烯烃的方法。 该方法包括使包含氯化物链末端的聚烯烃电离，并使离子化聚烯烃与一种或多种含氮五元芳环或一个或多个受阻仲胺或叔胺或其混合物反应。
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4.发明授权Method for preparing polyolefins containing a high percentage of exo-olefin chain ends 有权制备含有高百分比的外烯链末端的聚烯烃的方法公开(公告)号：US08530586B2
公开(公告)日：2013-09-10
申请号：US12767672
申请日：2010-04-26
IPC分类号： C08F214/02
CPC分类号： C08F8/26 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F2500/03
摘要： The present invention is directed to a method for preparing polyolefins containing a high percentage of exo-olefin chain ends. The method involves ionizing a polyolefin containing tert-chloride chain ends and reacting the ionized polyolefin with one or more nitrogen-containing five-membered aromatic ring or one or more hindered secondary or tertiary amines, or mixtures thereof.
摘要翻译： 本发明涉及一种制备含有高百分比的外烯链末端的聚烯烃的方法。 该方法包括使包含氯化物链末端的聚烯烃电离，并使离子化聚烯烃与一种或多种含氮五元芳环或一个或多个受阻仲胺或叔胺或其混合物反应。
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5.发明申请METHOD FOR PREPARING POLYOLEFINS CONTAINING A HIGH PERCENTAGE OF EXO-OLEFIN CHAIN ENDS 有权含有高脂肪超链烯烃链的聚烯烃的制备方法公开(公告)号：US20100311913A1
公开(公告)日：2010-12-09
申请号：US12767672
申请日：2010-04-26
申请人： Casey D. Stokes , Kelby Simison , Robson F. Storey
发明人： Casey D. Stokes , Kelby Simison , Robson F. Storey
IPC分类号： C08F114/02
CPC分类号： C08F8/26 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F2500/03
摘要： The present invention is directed to a method for preparing polyolefins containing a high percentage of exo-olefin chain ends. The method involves ionizing a polyolefin containing tert-chloride chain ends and reacting the ionized polyolefin with one or more nitrogen-containing five-membered aromatic ring or one or more hindered secondary or tertiary amines, or mixtures thereof.
摘要翻译： 本发明涉及一种制备含有高百分比的外烯链末端的聚烯烃的方法。 该方法包括使包含氯化物链末端的聚烯烃电离，并使离子化聚烯烃与一种或多种含氮五元芳环或一个或多个受阻仲胺或叔胺或其混合物反应。
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6.发明申请公开(公告)号：US20100249001A1
公开(公告)日：2010-09-30
申请号：US12415829
申请日：2009-03-31
IPC分类号： C07D207/26 , C08F8/30
CPC分类号： C08F8/30 , C08F8/18 , C08F2810/40 , C10L1/238 , C10L10/04 , C10L10/06 , C10M133/58 , C10M2215/30 , C10N2230/04 , C10N2230/041 , C10N2270/00 , C08F10/10
摘要： Disclosed is a method of preparing terminally functionalized telechelic polymers using a cationic living polymer product or a terminal tert-chloride chain end of a carbocationic quasiliving polymer product, which comprises quenching the polymer product with a functionalized N-substituted pyrrole to thereby introduce the functionalized N-substituted pyrrole at the terminal reactive polymer chain end(s). A method is also disclosed whereby the N-substituent may be derivatized to a basic amine containing functional group. Also disclosed are the terminal functionalized polyisobuyl N-substituted pyrrole compounds where the polyisobutyl group is substituted at the 2 and 3 position of the N-substituted pyrrole.
摘要翻译： 公开了一种使用阳离子活性聚合物产物或碳阳离子准共聚物产物的末端叔氯化物链末端制备末端官能化遥爪聚合物的方法，其包括用官能化的N-取代吡咯猝灭聚合物产物，从而引入官能化的N 在末端反应性聚合物链末端的取代吡咯。 还公开了一种方法，其中N-取代基可以衍生为含碱性胺官能团。 还公开了末端官能化聚异丁酰N-取代吡咯化合物，其中聚异丁基在N-取代吡咯的2位和3位被取代。
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7.发明授权Living and quasiliving cationic telechelic polymers quenched by N-substituted pyrrole and methods for their preparation 有权活性和准备由N-取代吡咯淬灭的阳离子遥爪聚合物及其制备方法公开(公告)号：US06969744B2
公开(公告)日：2005-11-29
申请号：US10600898
申请日：2003-06-19
IPC分类号： C07D207/06 , C08F2/38 , C08F2/42 , C08F4/00 , C08F8/00 , C08F8/30 , C08F110/10 , C10L1/22 , C10L1/222 , C10L1/232 , C10L1/236 , C10L1/238 , C10L1/24 , C10L1/26 , C10L10/00 , C10L10/08 , C10M149/10 , C08C19/22
CPC分类号： C10M149/10 , C08F2/38 , C08F2/42 , C08F8/04 , C08F8/26 , C08F8/30 , C08F8/34 , C08F110/10 , C08F2810/40 , C10L1/222 , C10L1/232 , C10L1/236 , C10L1/238 , C10L1/2468 , C10L1/2475 , C10L1/2608 , C10L1/2641 , C10L1/2675 , C10L1/2683 , C10L10/04 , C10M2217/028 , C10N2230/04 , C08F4/06 , C08F2500/03
摘要： Disclosed is a method of preparing terminally functionalized telechelic polymers using a cationic living polymer product or a terminal tert-chloride chain end of a carbocationic quasiliving polymer product, which comprises quenching the polymer product with an N-substituted pyrrole to thereby functionalize the N-substituted pyrrole at the terminal reactive polymer chain end(s). Also disclosed are the terminal functionalized polyisobuyl N-substituted pyrrole compounds where the polyisobutyl group is substituted at the 2 and 3 position of the N-substituted pyrrole.
摘要翻译： 公开了一种使用阳离子活性聚合物产物或碳阳离子准共聚物产物的末端叔氯化物链末端制备末端官能化遥爪聚合物的方法，其包括用N-取代的吡咯猝灭聚合物产物，从而使N-取代的 末端反应性聚合物链端的吡咯。 还公开了末端官能化聚异丁酰N-取代吡咯化合物，其中聚异丁基在N-取代吡咯的2位和3位被取代。
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8.发明授权公开(公告)号：US08552122B2
公开(公告)日：2013-10-08
申请号：US12415829
申请日：2009-03-31
IPC分类号： C08C19/22 , C07D207/00 , C07D207/30
CPC分类号： C08F8/30 , C08F8/18 , C08F2810/40 , C10L1/238 , C10L10/04 , C10L10/06 , C10M133/58 , C10M2215/30 , C10N2230/04 , C10N2230/041 , C10N2270/00 , C08F10/10
摘要： Disclosed is a method of preparing terminally functionalized telechelic polymers using a cationic living polymer product or a terminal tert-chloride chain end of a carbocationic quasiliving polymer product, which comprises quenching the polymer product with a functionalized N-substituted pyrrole to thereby introduce the functionalized N-substituted pyrrole at the terminal reactive polymer chain end(s). A method is also disclosed whereby the N-substituent may be derivatized to a basic amine containing functional group. Also disclosed are the terminal functionalized polyisobuyl N-substituted pyrrole compounds where the polyisobutyl group is substituted at the 2 and 3 position of the N-substituted pyrrole.
摘要翻译： 公开了一种使用阳离子活性聚合物产物或碳阳离子准共聚物产物的末端叔氯化物链末端制备末端官能化遥爪聚合物的方法，其包括用官能化的N-取代吡咯猝灭聚合物产物，由此引入官能化的N 在末端反应性聚合物链末端的取代吡咯。 还公开了一种方法，其中N-取代基可以衍生为含碱性胺官能团。 还公开了末端官能化聚异丁酰N-取代吡咯化合物，其中聚异丁基在N-取代吡咯的2位和3位被取代。
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公开(公告)号：US08383736B2
公开(公告)日：2013-02-26
申请号：US12767676
申请日：2010-04-26
IPC分类号： C08F8/32
CPC分类号： C08F234/00 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F4/16
摘要： The present invention is directed to a method for preparation of polyolefins containing exo-olefin chain ends. The method involves quenching a cationic quasi-living polyolefin polymer system with a nitrogen-containing five-membered aromatic ring having at least two hydrocarbyl substituent compounds attached to the ring.
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公开(公告)号：US20100311915A1
公开(公告)日：2010-12-09
申请号：US12767676
申请日：2010-04-26
IPC分类号： C08F8/30
CPC分类号： C08F234/00 , C08F8/00 , C08F110/10 , C08F2810/30 , C08F2810/40 , C08F2/38 , C08F4/16
摘要： The present invention is directed to a method for preparation of polyolefins containing exo-olefin chain ends. The method involves quenching a cationic quasi-living polyolefin polymer system with a nitrogen-containing five-membered aromatic ring having at least two hydrocarbyl substituent compounds attached to the ring.
摘要翻译： 本发明涉及一种制备含有外烯烃链末端的聚烯烃的方法。 该方法包括用具有至少两个连接到该环上的烃基取代基化合物的含氮五元芳环淬灭阳离子准活性聚烯烃聚合物体系。
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