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公开(公告)号：US20130255515A1
公开(公告)日：2013-10-03
申请号：US13430798
申请日：2012-03-27
CPC分类号： B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/08 , B41C2210/10 , B41C2210/12 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41C2210/266
摘要： A positive-working multi-layer lithographic printing plate precursor has an inner imageable layer disposed over a substrate. This inner imageable layer comprises one or more first polymeric binders that are present in a total amount of at least 50 weight % and up to and including 97 weight %, based on total inner imageable layer dry weight. The precursor also has an ink-receptive outer imageable layer disposed over the inner imageable layer and this ink-receptive outer imageable layer comprises one or more second polymeric binders that are different than the first polymeric binder. Each of the one or more first polymeric binders has a weight average molecular weight of at least 200,000 and can also have a polydispersity of at least 4.
摘要翻译： 正性多层平版印刷版原版具有设置在基板上的内部可成像层。 该内部可成像层包含一种或多种第一聚合物粘合剂，其以总内部可成像层干重的总量为至少50重量％且至多且包含97重量％。 前体还具有置于内部可成像层之上的吸墨外部可成像层，并且该油墨接收外部可成像层包含不同于第一聚合物粘合剂的一种或多种第二聚合物粘合剂。 一种或多种第一聚合物粘合剂中的每一种具有至少200,000的重均分子量，并且还可以具有至多4的多分散性。
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2.发明申请公开(公告)号：US20080206674A1
公开(公告)日：2008-08-28
申请号：US11997564
申请日：2006-08-01
CPC分类号： B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262
摘要： Thermally imagable elements are described comprising on a substrate with hydrophilic surface (a) a first layer comprising a first polymer soluble or swellable in aqueous alkaline developer and insoluble in organic solvents with low polarity and (b) a second layer comprising a second polymer soluble or swellable in aqueous alkaline developer, wherein the first polymer is different from the second polymer and the second polymer comprises vinyl acetal repeating units and pendant acidic groups selected from COOH, —SO3H, —PO3H2, —PO4H2, aromatic OH and groups having acidic amide or imide groups.
摘要翻译： 描述了可热成像的元件，其包括在具有亲水表面的基底上（a）第一层，该第一层包含在碱性显影剂的水溶液中可溶或可溶胀的第一聚合物，并且不溶于低极性的有机溶剂中，和（b）第二层， 在水性碱性显影剂中可膨胀，其中第一聚合物不同于第二聚合物，第二聚合物包含乙烯基缩醛重复单元和选自COOH，-SO 3 H，-PO 3， 3个H 2，-PO 4 H 2，芳香族OH和具有酸性酰胺或酰亚胺基团的基团。
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3.发明授权公开(公告)号：US07781148B2
公开(公告)日：2010-08-24
申请号：US11997564
申请日：2006-08-01
IPC分类号： G03F7/26
CPC分类号： B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262
摘要： Thermally imagable elements are described comprising on a substrate with hydrophilic surface (a) a first layer comprising a first polymer soluble or swellable in aqueous alkaline developer and insoluble in organic solvents with low polarity and (b) a second layer comprising a second polymer soluble or swellable in aqueous alkaline developer, wherein the first polymer is different from the second polymer and the second polymer comprises vinyl acetal repeating units and pendant acidic groups selected from COOH, —SO3H, —PO3H2, —PO4H2, aromatic OH and groups having acidic amide or imide groups.
摘要翻译： 描述了可热成像的元件，其包括在具有亲水表面的基底上（a）第一层，该第一层包含在碱性显影剂的水溶液中可溶或可溶胀的第一聚合物，并且不溶于低极性的有机溶剂中，和（b）第二层， 其中第一聚合物不同于第二聚合物，第二聚合物包含乙烯基缩醛重复单元和选自COOH，-SO 3 H，-PO 3 H 2，-PO 4 H 2，芳族OH的侧基酸基和具有酸性酰胺的基团或 酰亚胺组。
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公开(公告)号：US06613494B2
公开(公告)日：2003-09-02
申请号：US09805327
申请日：2001-03-13
IPC分类号： G03F711
CPC分类号： B41C1/1016 , B41C2201/02 , B41C2210/02 , B41C2210/06 , B41C2210/22 , B41C2210/24 , B41C2210/262
摘要： Positive-working imageable elements and methods for their preparation are disclosed. The elements comprise a hydrophilic substrate; a bottom layer, which contains a positive-working photosensitive composition; and a protective overlayer, which has an overlayer material that reduces the solubility of the photosensitive composition in an aqueous alkaline developer. The overlayer may be conveniently applied by a dip and rinse procedure.
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公开(公告)号：US20140065539A1
公开(公告)日：2014-03-06
申请号：US13602367
申请日：2012-09-04
CPC分类号： G03F7/027 , B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41N3/036 , G03F7/0045 , G03F7/09 , G03F7/202 , G03F7/322
摘要： A thermally-sensitive, positive-working lithographic printing plate precursor can be used to prepare lithographic printing plates using high pH, silicate-free processing solutions. The precursor has a grained an anodized aluminum-containing substrate including a poly(vinyl phosphonic acid) interlayer. A first ink receptive layer, and optionally a second ink receptive layer, is disposed directly on the poly(vinyl phosphonic acid) interlayer. This first ink receptive layer comprises an aromatic acid dye that comprises at least two aromatic groups in an amount of least 0.5 weight %. In addition, the precursor comprises an infrared radiation absorber in one of the layers.
摘要翻译： 热敏正性平版印刷版前体可用于制备使用高pH，无硅酸盐处理溶液的平版印刷版。 前体具有含有聚（乙烯基膦酸）中间层的含有阳极氧化的含铝基材。 第一受墨层和任选的第二墨接受层直接设置在聚（乙烯基膦酸）中间层上。 该第一受墨层包含至少两个芳香族基团，其含量至少为0.5重量％。 此外，前体包括在其中一层中的红外辐射吸收剂。
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公开(公告)号：US08936899B2
公开(公告)日：2015-01-20
申请号：US13602367
申请日：2012-09-04
CPC分类号： G03F7/027 , B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41N3/036 , G03F7/0045 , G03F7/09 , G03F7/202 , G03F7/322
摘要： A thermally-sensitive, positive-working lithographic printing plate precursor can be used to prepare lithographic printing plates using high pH, silicate-free processing solutions. The precursor has a grained an anodized aluminum-containing substrate including a poly(vinyl phosphonic acid) interlayer. A first ink receptive layer, and optionally a second ink receptive layer, is disposed directly on the poly(vinyl phosphonic acid) interlayer. This first ink receptive layer comprises an aromatic acid dye that comprises at least two aromatic groups in an amount of least 0.5 weight %. In addition, the precursor comprises an infrared radiation absorber in one of the layers.
摘要翻译： 热敏正性平版印刷版前体可用于制备使用高pH，无硅酸盐处理溶液的平版印刷版。 前体具有含有聚（乙烯基膦酸）中间层的含有阳极氧化的含铝基材。 第一受墨层和任选的第二墨接受层直接设置在聚（乙烯基膦酸）中间层上。 该第一受墨层包含至少两个芳香族基团，其含量至少为0.5重量％。 此外，前体包括在其中一层中的红外辐射吸收剂。
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公开(公告)号：US20140283703A1
公开(公告)日：2014-09-25
申请号：US14296788
申请日：2014-06-05
IPC分类号： B41C1/10
CPC分类号： G03F7/027 , B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41N3/036 , G03F7/0045 , G03F7/09 , G03F7/202 , G03F7/322
摘要： A thermally-sensitive, positive-working lithographic printing plate precursor can be used to prepare lithographic printing plates using high pH, silicate-free processing solutions. The precursor has a grained an anodized aluminum-containing substrate including a poly(vinyl phosphonic acid) interlayer. A first ink receptive layer, and optionally a second ink receptive layer, is disposed directly on the poly(vinyl phosphonic acid) interlayer. This first ink receptive layer comprises an aromatic acid dye that comprises at least two aromatic groups in an amount of least 0.5 weight %. In addition, the precursor comprises an infrared radiation absorber in one of the layers.
摘要翻译： 热敏正性平版印刷版前体可用于制备使用高pH，无硅酸盐处理溶液的平版印刷版。 前体具有含有聚（乙烯基膦酸）中间层的含有阳极氧化的含铝基材。 第一受墨层和任选的第二墨接受层直接设置在聚（乙烯基膦酸）中间层上。 该第一受墨层包含至少两个芳香族基团，其含量至少为0.5重量％。 此外，前体包括在其中一层中的红外辐射吸收剂。
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8.发明申请公开(公告)号：US20070292809A1
公开(公告)日：2007-12-20
申请号：US10574870
申请日：2004-10-11
CPC分类号： B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , B41M5/368
摘要： The invention relates to a process for the production of a heat-sensitive imageable element comprising: (a) providing a substrate, (b) applying a first coating solution, comprising at least one photothermal conversion material, at least one polymer A soluble or swellable in an aqueous alkaline developer and at least one solvent, (c) drying, (d) applying a second coating solution, comprising at least one cross-linkable polyfunctional enolether, at least one polymer B comprising hydroxy groups and/or carboxy groups, and at least one solvent, wherein the polymer used in the first coating solution does not dissolve in this solvent, wherein the second coating solution does not contain a photothermal conversion material, and (e) drying at a temperature of at least 60° C.
摘要翻译： 本发明涉及一种用于生产热敏可成像元件的方法，包括：（a）提供基底，（b）施加包含至少一种光热转换材料的第一涂层溶液，至少一种可溶或可膨胀的聚合物A 在水性碱性显影剂和至少一种溶剂中，（c）干燥，（d）施加包含至少一个可交联的多官能烯烃的至少一种包含羟基和/或羧基的聚合物B的第二涂料溶液，以及 至少一种溶剂，其中在第一涂布溶液中使用的聚合物不溶于该溶剂，其中第二涂布溶液不含光热转换材料，和（e）在至少60℃的温度下干燥。
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公开(公告)号：US08632940B2
公开(公告)日：2014-01-21
申请号：US13089399
申请日：2011-04-19
CPC分类号： B41N3/036 , B41C1/1008 , B41C2201/02 , B41C2201/14 , B41C2210/02 , B41C2210/04 , B41C2210/06 , B41C2210/10 , B41C2210/12 , B41C2210/14 , B41C2210/24 , B41C2210/262
摘要： Electrochemically grained and anodized aluminum supports are treated with a post-treatment coating solution containing a polymer derived at least in part from vinyl phosphonic acid and phosphoric acid. This post-treated support is useful as substrates in the preparation of lithographic printing plate precursors. The post-treatment substrate treatment enables wide latitude in manufacturing and compatibility with silicate-free developers to achieve negligible background staining and oxide attack.
摘要翻译： 用含有至少部分由乙烯基膦酸和磷酸衍生的聚合物的后处理涂层溶液处理电化学和阳极氧化的铝载体。 该后处理支持物可用作制备平版印刷版前体的底物。 后处理底物处理使得制造中的宽范围和与无硅酸盐的显影剂的相容性可以实现可忽略的背景染色和氧化物侵蚀。
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公开(公告)号：US08530141B2
公开(公告)日：2013-09-10
申请号：US13711648
申请日：2012-12-12
CPC分类号： G03F7/095 , B41C1/1008 , B41C1/1016 , B41C2210/02 , B41C2210/06 , B41C2210/14 , B41C2210/22 , B41C2210/24 , B41C2210/262 , C08F220/44 , C08F220/58 , C08F220/60 , C08F222/40 , G03F7/0045 , G03F7/322
摘要： Lithographic printing plate precursors can have an imageable layer that includes a polymeric binder having an acid number of at least 30 mg KOH/g of polymer to and including 150 mg KOH/g of polymer, at least 3 weight % of recurring units derived from one or more N-alkoxymethyl (alkyl)acrylamides or alkoxymethyl (alkyl)acrylates, at least 2 weight % of recurring units having pendant 1H-tetrazole groups, and at least 10 weight % of recurring units having pendant cyano groups. The use of such polymeric binders provides good bakeability and chemical solvent resistance, especially for positive-working precursors.
摘要翻译： 平版印刷版前体可以具有可成像层，其包含酸值为至少30mg KOH / g的聚合物，并且包含150mg KOH / g聚合物的聚合物粘合剂，至少3重量％衍生自一个聚合物的重复单元 或更多的N-烷氧基甲基（烷基）丙烯酰胺或烷氧基甲基（烷基）丙烯酸酯，至少2重量％的具有侧挂的1H-四唑基的重复单元和至少10重量％的具有侧基氰基的重复单元。 使用这种聚合物粘合剂提供良好的烘烤性和耐化学溶剂性，特别是对于正性前体。
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