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公开(公告)号：US5820655A
公开(公告)日：1998-10-13
申请号：US848204
申请日：1997-04-29
申请人： Christian Friedrich Gottzmann , Ravi Prasad , Victor Emmanuel Bergsten , Nitin Ramesh Keskar , Bart Antonie van Hassel
发明人： Christian Friedrich Gottzmann , Ravi Prasad , Victor Emmanuel Bergsten , Nitin Ramesh Keskar , Bart Antonie van Hassel
CPC分类号： C01B13/0255 , B01D53/22 , B01D53/326 , B01D63/062 , B01J12/007 , B01J19/2425 , B01J19/2475 , C01B13/0251 , B01D2313/42 , B01J2219/00081 , B01J2219/00085 , B01J2219/0015 , B01J2219/00155 , C01B2210/0046 , C01B2210/0082
摘要： An ion transport reactor and process for using same having at least one ion transport membrane with a retentate side and a permeate side, for extracting oxygen from a feed gas stream as it flows along the retentate side. A reactant gas stream is flowed along the permeate side of the ion transport tubes to react with the oxygen transported therethrough. Heat is transferred to a fluid stream flowing through the ion transport reactor while the temperature of the membrane is maintained within its operating range.
摘要翻译： 离子迁移反应器及其使用方法，其具有至少一个具有滞留侧和渗透侧的离子迁移膜，用于当其沿着渗余物侧流动时从进料气流中提取氧气。 反应物气流沿离子输送管的渗透侧流动，以与从其中输送的氧气反应。 将热量转移到流过离子迁移反应器的流体流中，同时膜的温度保持在其工作范围内。
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公开(公告)号：US06368383B1
公开(公告)日：2002-04-09
申请号：US09589425
申请日：2000-06-07
IPC分类号： B01D5322
CPC分类号： B01D69/12 , B01D53/228 , B01D69/02 , B01D71/024 , B01D2257/104 , B01D2325/021 , B01D2325/26 , C01B13/0255 , C01B2210/0046 , C01B2210/0051
摘要： A method of separating oxygen from an oxygen containing gas with a composite membrane capable of conducting oxygen ions and electrons. In accordance with the method, the composite membrane is subjected to an operational temperature and the oxygen containing gas at a cathode side thereof. The composite membrane has a dense layer, at least one active porous layer contiguous to the dense layer, and at least one porous support layer. The active porous layer has a thickness and a distribution of pore radii. The distribution of pore radii has a standard deviation from a theoretical radius that would produce a maximum operation flux through the thickness when the thickness is about equal to a product of a constant and the square root of the theoretical radius. The constant is a function of a material used to fabricate the active porous layer, the operational temperature and an oxygen partial pressure within the active porous layer, and a porosity and a tortuosity produced by the pore radii. The standard deviation of the log of the theoretical radius is equal to a product of 1.45 and a shape factor, the shape factor being greater than 0 and no greater than about 0.5.
摘要翻译： 从含氧气体中分离出氧和能够导电氧离子和电子的复合膜的方法。 根据该方法，复合膜经受操作温度，阴极侧含有含氧气体。 复合膜具有致密层，与致密层邻接的至少一个活性多孔层和至少一个多孔载体层。 活性多孔层具有孔半径的厚度和分布。 孔半径的分布与理论半径的标准偏差，当理论半径的厚度约等于理论半径的常数和平方根的乘积时，将产生通过厚度的最大工作磁通。 常数是用于制造活性多孔层的材料的功能，活性多孔层内的操作温度和氧分压，以及由孔半径产生的孔隙率和曲折度。 理论半径的对数的标准偏差等于1.45的乘积和形状因子，形状因子大于0且不大于约0.5。
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3.发明授权Process for reducing carbon production in solid electrolyte ionic conductor systems 有权降低固体电解质离子导体系统碳生产的方法
公开(公告)号：US6106591A
公开(公告)日：2000-08-22
申请号：US185959
申请日：1998-11-05
CPC分类号： B01D53/22 , B01D53/326 , B01D63/06 , B01D63/087 , C01B13/0251 , C01B3/36 , B01D2313/10 , B01D2313/22 , B01D2313/42 , C01B2210/0046
摘要： A process for inhibiting the formation of carbon and/or coke from a carbon-containing reactive gas stream on the permeate side of an oxygen ion transport membrane, or for increasing the oxygen partial pressure thereon, by separating a feed gas stream to form an oxygen-depleted gas stream on the retentate side and a gas stream containing oxygen reaction products on the permeate side. The permeate side is purged with the carbon-containing reactive gas stream, and at least a portion of the exhaust gas stream formed from the reaction of the reactive gas stream with the separated oxygen is recirculated to purge the permeate side.
摘要翻译： 通过分离进料气流以形成氧气的方法，用于抑制在氧离子迁移膜的渗透侧上的含碳反应性气流形成碳和/或焦炭，或用于增加其上的氧分压 在渗余物侧的脱气气流和在渗透侧含有氧反应产物的气流。 用含碳反应性气流吹扫渗透侧，并且将由反应气流与分离的氧的反应形成的废气流的至少一部分再循环以净化渗透侧。
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公开(公告)号：US6066307A
公开(公告)日：2000-05-23
申请号：US396199
申请日：1999-09-15
CPC分类号： C01B3/36 , B01D53/228 , B01D53/32 , C01B13/0251 , C01B13/0255 , B01D2257/104 , C01B2210/0046
摘要： A process for producing synthesis gas and hydrogen by passing a compressed and heated oxygen-containing gas mixture into a reactor having at least one solid electrolyte oxygen ion transport membrane to separate transported oxygen Organic fuel reacts with the oxygen to form synthesis gas. The resulting synthesis gas is separated into hydrogen gas through at least one solid electrolyte hydrogen transport membrane to separate the transported hydrogen in the same or different separator.
摘要翻译： 通过使压缩和加热的含氧气体混合物进入具有至少一个固体电解质氧离子迁移膜的反应器以分离运输的氧气来生产合成气和氢的方法。有机燃料与氧气反应形成合成气。 所得合成气通过至少一个固体电解质氢输运膜分离成氢气，以分离相同或不同分离器中输送的氢。
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公开(公告)号：US06010614A
公开(公告)日：2000-01-04
申请号：US89512
申请日：1998-06-03
CPC分类号： B01J19/2475 , B01D53/22 , C01B13/0251 , C01B3/36 , C01B3/382 , C01B2210/0046
摘要： A method for maintaining the temperature of an oxygen-selective ion transport membrane within a desired temperature range includes providing an ion transport reactor with the oxygen-selective ion transport membrane. An oxygen-donating feed gas is delivered to a cathode side at a first temperature, at a first rate, and at a first oxygen partial pressure and a reactant gas is supplied to an anode side at a second temperature and a second rate. A physical condition is then established within the ion transport reactor that favors the transport of elemental oxygen through the oxygen selective ion transport membrane as oxygen ions. One or more process variables are then regulated to maintain the temperature of the oxygen selective ion transport membrane within the desired range.
摘要翻译： 将氧选择性离子迁移膜的温度保持在所需温度范围内的方法包括向离子转运反应器提供氧选择性离子迁移膜。 供氧进料气体在第一温度，第一速率和第一氧分压下输送到阴极侧，并且反应气体以第二温度和第二速率供应到阳极侧。 然后在离子转运反应器内建立有利于通过氧选择性离子迁移膜作为氧离子转运元素氧的物理条件。 然后调节一个或多个过程变量以将氧选择性离子迁移膜的温度保持在所需范围内。
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公开(公告)号：US06537514B1
公开(公告)日：2003-03-25
申请号：US09427066
申请日：1999-10-26
IPC分类号： C01B3120
摘要： In a method for the production of carbon dioxide, an oxygen-containing first process gas is flowed along a cathode side of a first oxygen selective ion transport membrane. The membrane is at operating conditions effective to transport a first permeate oxygen portion from the cathode side to an opposite anode side. A carbon-containing second process gas is flowed along the anode side at a flow rate effective to provide a stoichiometric surplus of oxygen on combination with the first permeate oxygen portion. A first mixture of a second process gas and the first permeate oxygen portion is combusted such that substantially all of the second process gas is converted into a second mixture of water and carbon dioxide. The carbon dioxide is separated from such second mixture.
摘要翻译： 在制造二氧化碳的方法中，含氧的第一工艺气体沿着第一氧选择性离子迁移膜的阴极侧流动。 膜处于有效地将第一渗透氧部分从阴极侧输送到相对的阳极侧的操作条件。 含碳的第二工艺气体沿着阳极侧以与第一渗透氧部分组合以提供化学计量的剩余氧气的流量流动。 将第二工艺气体和第一渗透氧部分的第一混合物燃烧，使得基本上所有的第二工艺气体转化为水和二氧化碳的第二混合物。 二氧化碳与第二混合物分离。
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7.发明授权
公开(公告)号：US6139604A
公开(公告)日：2000-10-31
申请号：US185523
申请日：1998-11-04
IPC分类号： B01D53/04 , B01D53/047 , B01D53/22 , C01B13/02 , C01B21/04
CPC分类号： B01D53/22 , B01D53/0462 , B01D53/047 , B01D53/229 , B01D63/06 , C01B13/0251 , C01B21/0438 , B01D2256/10 , B01D2256/12 , B01D2257/504 , B01D2257/702 , B01D2257/80 , B01D2259/40001 , B01D2259/40052 , B01D2259/40079 , B01D2259/40081 , B01D2313/22 , B01D2313/40 , C01B2210/0046 , C01B2210/0062 , Y02C10/08 , Y02C10/10 , Y02P20/129 , Y02P20/131 , Y02P20/152
摘要： A low energy cost process for the co-production of oxygen and nitrogen employing a fuel tube extending into the first oxygen selective ion transport membrane whereby fuel is introduced adjacent to the closed end and flows cocurrently with oxygen containing gas in the annulus and an oxygen selective ion transport membrane having a separator section and a reactor section. An oxygen-containing feedstock, typically air, is compressed and then contacts the cathode side of the separator section where a portion of the oxygen contained within the feedstock is transported to the anode side of the separator section and recovered as an oxygen product gas. Substantially the remainder of the oxygen contained within the feedstock is transported from the cathode side of the reactor section to the anode side and exothermically reacted with a fuel. Following the exothermic reaction, hot nitrogen rich product gas is expanded in a turbine to generate the power necessary to compress the feedstock. Expanded nitrogen rich product gas may then be recovered from the turbine exhaust.
摘要翻译： 使用延伸到第一氧选择性离子迁移膜中的燃料管共同生产氧气和氮气的低能量成本过程，由此燃料在闭合端附近引入并且与环中的含氧气体并流并且具有氧选择性 离子传送膜，其具有分隔部和反应部。 含氧原料（通常为空气）被压缩，然后接触分离器部分的阴极侧，其中原料中所含的一部分氧被输送到分离器部分的阳极侧并作为氧产物气体回收。 基本上将原料中所含的剩余氧气从反应器部分的阴极侧输送到阳极侧，并与燃料放热反应。 在放热反应之后，富含热氮的产物气体在涡轮机中膨胀以产生压缩原料所需的功率。 然后可以从涡轮机废气中回收膨胀的富氮产物气体。
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公开(公告)号：US5837125A
公开(公告)日：1998-11-17
申请号：US567699
申请日：1995-12-05
CPC分类号： B01D53/226 , B01D53/326
摘要： A system and process for producing a high-purity product from a feed stream containing elemental oxygen by applying the feed stream to at least one separator including a feed zone and a permeate zone separated by a solid electrolyte membrane, and driving a portion of oxygen contained in the feed stream from the feed zone to the permeate zone via the membrane by applying to the permeate zone a reactive purge stream containing a reactive gas which combines with oxygen to establish a lower partial pressure of oxygen in that zone. Oxygen-depleted retentate is withdrawn as a high-purity product stream.
摘要翻译： 通过将进料流施加到至少一个分离器的系统和方法，所述系统和方法由含有元素氧的进料流生产高纯度产物，所述至少一个分离器包括由固体电解质膜分离的进料区和渗透区，并驱动所含的一部分氧 在通过向渗透物区域施加包含与氧结合的反应性气体的反应性气流以在该区域中建立较低的氧分压的通过膜从进料区到渗透区的进料流中。 作为高纯度产物流取出缺氧的渗余物。
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9.发明授权
公开(公告)号：US6017646A
公开(公告)日：2000-01-25
申请号：US089513
申请日：1998-06-03
IPC分类号： H01M8/02 , B01D53/32 , C01B3/36 , C01B3/38 , C01B13/02 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/12 , H01M14/00
CPC分类号： C01B3/36 , B01D53/326 , C01B13/0251 , C01B3/386 , H01M8/06 , H01M8/0662 , H01M8/1231 , C01B2210/0046 , C01B2210/0051 , C01B2210/0062 , H01M2008/1293 , H01M2300/0074 , H01M8/04014 , H01M8/04022 , Y02P20/129
摘要： An integrated system utilizing a solid oxide fuel cell and at least one ion transport reactor to generate electric power and a product gas by delivering an oxygen-containing gas, typically air, to a first cathode side of the solid oxide fuel cell and delivering a gaseous fuel to a first anode side. Oxygen ions are transported through a membrane in the fuel cell to the first anode side and exothermally react with the gaseous fuel to generate electric power and heat. The heat and oxygen transport produces a higher-temperature, reduced-oxygen-content gaseous retentate stream exiting the cathode side of the solid oxide fuel cell which is delivered to a first ion transport reactor where a substantial portion of the residual oxygen is transported through an oxygen selective ion transport membrane. A product gas stream is then recovered.
摘要翻译： 一种利用固体氧化物燃料电池和至少一个离子迁移反应器通过将含氧气体（通常为空气）输送到固体氧化物燃料电池的第一阴极侧并产生气体的集成系统， 燃料到第一阳极侧。 氧离子通过燃料电池中的膜输送到第一阳极侧，并与气体燃料放热反应以产生电力和热量。 热和氧传输产生离开固体氧化物燃料电池的阴极侧的更高温度，低氧含量的气态滞留物流，其被输送到第一离子迁移反应器，其中大部分残余氧被输送通过 氧选择性离子迁移膜。 然后回收产物气流。
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10.发明授权Solid electrolyte ionic conductor with adjustable steam-to-oxygen production 失效固体电解质离子导体，具有可调节的蒸汽 - 氧气生产
公开(公告)号：US5964922A
公开(公告)日：1999-10-12
申请号：US972412
申请日：1997-11-18
CPC分类号： B01D53/32 , B01D53/22 , C01B13/0251 , C10J3/00 , C10J3/723 , B01D2257/106 , C01B2210/0046 , C01B2210/0062 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0979 , C10J2300/1671 , C10J2300/1807 , Y02E20/16 , Y02E20/18
摘要： A process for producing a gas stream containing oxygen and steam to feed a coal gasifier or other downstream process by compressing and heating a feed gas stream, and separating the heated feed gas stream into an oxygen-depleted gas stream on a retentate side of an ion transport membrane and an oxygen-containing gas stream on a permeate side. The permeate side is purged with a purge gas stream containing steam to produce a gas stream containing oxygen and steam, and at least a portion of the gas stream containing oxygen and steam is fed to the coal gasifier after blending with a pure oxygen stream recovered from the remaining portion of the purge stream or by a parallel nonpurged ion transport separator in the system to achieve the appropriate steam-to-oxygen ratio for the downstream process.
摘要翻译： 一种用于生产含有氧气和蒸汽的气流以通过压缩和加热进料气流来供给煤气化器或其它下游方法的方法，并将加热的进料气流分离成离子的渗余物侧上的贫氧气体流 输送膜和含氧气流在渗透侧。 用含有蒸汽的吹扫气流吹扫渗透侧，产生含有氧气和蒸汽的气流，并且将含有氧气和蒸汽的气流的至少一部分与从回收的纯氧气流混合后进料到煤气化器 净化流的剩余部分或通过系统中的并联非膨胀离子迁移分离器，以实现用于下游方法的适当的蒸汽 - 氧气比。
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