摘要:
A method of separating oxygen from an oxygen containing gas with a composite membrane capable of conducting oxygen ions and electrons. In accordance with the method, the composite membrane is subjected to an operational temperature and the oxygen containing gas at a cathode side thereof. The composite membrane has a dense layer, at least one active porous layer contiguous to the dense layer, and at least one porous support layer. The active porous layer has a thickness and a distribution of pore radii. The distribution of pore radii has a standard deviation from a theoretical radius that would produce a maximum operation flux through the thickness when the thickness is about equal to a product of a constant and the square root of the theoretical radius. The constant is a function of a material used to fabricate the active porous layer, the operational temperature and an oxygen partial pressure within the active porous layer, and a porosity and a tortuosity produced by the pore radii. The standard deviation of the log of the theoretical radius is equal to a product of 1.45 and a shape factor, the shape factor being greater than 0 and no greater than about 0.5.
摘要:
An ion transport reactor and process for using same having at least one ion transport membrane with a retentate side and a permeate side, for extracting oxygen from a feed gas stream as it flows along the retentate side. A reactant gas stream is flowed along the permeate side of the ion transport tubes to react with the oxygen transported therethrough. Heat is transferred to a fluid stream flowing through the ion transport reactor while the temperature of the membrane is maintained within its operating range.
摘要:
A method of separating oxygen from an oxygen containing stream in which compressed and heated oxygen is introduced into cathode side of an oxygen transport membrane reactor. Oxygen is permeated from the cathode side to the anode side. Motive fluid that is introduced into an ejector draws an oxygen permeate containing stream from the anode side at a subatmospheric pressure to form an oxygen containing product stream. The motive fluid, which can be steam raised by combustion used in heating the reactor, can be separated from the oxygen containing product stream to form an oxygen product stream. The use of an ejector lowers the partial pressure of the oxygen at the anode side of the membrane reactor and therefore the degree to which the oxygen containing stream need be compressed.
摘要:
An ion-transport membrane assembly including a tubular, ion-transport membrane that is fabricated from one or more ion-transport, ceramic materials capable of ionic transport at an operational temperature of greater than 400° C. The membrane may be an oxygen transport membrane or a hydrogen transport membrane. A plurality of structural supporting members, fabricated from an open porous material and having an outer cylindrical surface, are inserted within the membrane, without being bonded to the membrane, to inhibit inward collapse of the membrane under application of a pressure applied to an exterior surface of the membrane. The structural supporting members are configured to permit relative movement between the outer surface of the structural supporting member and the interior surface of the tubular membrane during heating to or cooling from the operational temperature thereof.
摘要:
A low energy cost process for the co-production of oxygen and nitrogen employing a fuel tube extending into the first oxygen selective ion transport membrane whereby fuel is introduced adjacent to the closed end and flows cocurrently with oxygen containing gas in the annulus and an oxygen selective ion transport membrane having a separator section and a reactor section. An oxygen-containing feedstock, typically air, is compressed and then contacts the cathode side of the separator section where a portion of the oxygen contained within the feedstock is transported to the anode side of the separator section and recovered as an oxygen product gas. Substantially the remainder of the oxygen contained within the feedstock is transported from the cathode side of the reactor section to the anode side and exothermically reacted with a fuel. Following the exothermic reaction, hot nitrogen rich product gas is expanded in a turbine to generate the power necessary to compress the feedstock. Expanded nitrogen rich product gas may then be recovered from the turbine exhaust.
摘要:
A system and process for producing a high-purity product from a feed stream containing elemental oxygen by applying the feed stream to at least one separator including a feed zone and a permeate zone separated by a solid electrolyte membrane, and driving a portion of oxygen contained in the feed stream from the feed zone to the permeate zone via the membrane by applying to the permeate zone a reactive purge stream containing a reactive gas which combines with oxygen to establish a lower partial pressure of oxygen in that zone. Oxygen-depleted retentate is withdrawn as a high-purity product stream.
摘要:
A method of producing a crude syngas product stream or a syngas product stream by further processing of the crude syngas product stream. Both the crude and syngas product stream comprise carbon monoxide and hydrogen. The crude syngas product stream additionally comprises carbon dioxide and moisture. In accordance with the method, methane in a feed stream is converted into the hydrogen and carbon monoxide in at least two stages, thereby to form a crude syngas stream. An initial stage has an oxygen transport membrane reactor having a catalyst to promote carbon dioxide or steam methane reforming. Since, the conversion is shared between two stages, the oxygen transport membrane reactor can be operated at a sufficiently low temperature to avoid ceramic membrane deterioration due to creep effect. The subsequent stage can be operated at a higher temperature with more favorable equilibrium conditions to complete the conversion of the methane.
摘要:
In a method for the production of carbon dioxide, an oxygen-containing first process gas is flowed along a cathode side of a first oxygen selective ion transport membrane. The membrane is at operating conditions effective to transport a first permeate oxygen portion from the cathode side to an opposite anode side. A carbon-containing second process gas is flowed along the anode side at a flow rate effective to provide a stoichiometric surplus of oxygen on combination with the first permeate oxygen portion. A first mixture of a second process gas and the first permeate oxygen portion is combusted such that substantially all of the second process gas is converted into a second mixture of water and carbon dioxide. The carbon dioxide is separated from such second mixture.
摘要:
An exothermic reaction and an endothermic reaction are thermally combined in a reactor having at least one oxygen selective ion transport membrane that provides the exothermic reaction with oxygen from an oxygen-containing gas such as air. The thermal requirements of the endothermic reaction are satisfied by the exothermic reaction. Dependent on the reactor design employed, the exothermic and endothermic reactions may be gaseously combined.
摘要:
Syngas, a mixture of hydrogen and carbon monoxide, is an intermediate in the conversion of methane to liquid fuels. For certain applications, it is desirable to maintain an H2/CO molar ratio of about 3. This molar ratio is achieved by steam reforming of methane in accordance with: CH4+H2O→3H2+CO. To provide the heat required to drive the endothermic steam reforming reaction, a low grade fuel is combusted in a reactor and the heat of combustion conducted to the endothermic reaction. By using an oxygen selective ion transport membrane element to transport the oxygen required for combustion, the formation of undesirable NOx compounds is minimized.