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    Cross-linkable compounds, optionally containing MQ silicon resins
    1.
    发明授权
    Cross-linkable compounds, optionally containing MQ silicon resins 有权
    可交联的化合物，任选地含有MQ硅树脂

    公开(公告)号：US06274692B1

    公开(公告)日：2001-08-14

    申请号：US09381414

    申请日：1999-09-30

    申请人： Christian Herzig ,  Oliver Zoellner ,  Friedrich Hockemeyer ,  Robert Banfic

    发明人： Christian Herzig ,  Oliver Zoellner ,  Friedrich Hockemeyer ,  Robert Banfic

    IPC分类号： C08G7720

    CPC分类号： C09D183/04 ,  C08G77/20 ,  C09D183/14 ,  C08L83/00

    摘要： The invention relates to new, cross-linkable compounds containing (A1) linear organopolysiloxanes with aliphatically unsaturated hydrocarbon radicals, said organopolysiloxanes being of general formula (I) R1aR3-aSiO(R2SiO)c[R2Si—Y—SiR2O(R2SiO)c]dSiR3-bR1b, wherein R can be the same or different, and represents a monovalent, optionally halogenated hydrocarbon radical which is free of terminal aliphatic carbon—carbon multiple bonds, R1 represents a monovalent aliphatically unsaturated hydrocarbon radical, Y represents a bivalent organic radical which is free of terminal aliphatic carbon—carbon multiple bonds, a is 0 or 1, b is 0 or 1, and the sum of a+b per molecule is 1 or 2, c is a whole number to the value of 1 to 1000, d is 0 or a whole number to the value of 1 to 10, and optionally, (A2) MQ silicone resins which are soluble in (A1), on the condition that if MQ silicone resins (A2) are not used, the sum of a+b in the formula (I) is 1.3 to 1.9 on average and that if MQ silicone resins (A2) are used, the sum of a+b in formula (I) is 1.0 to 1.9 on average; (B) organo-silicon compounds with Si-bonded hydrogen atoms; (C) catalysts which promote the formation of an aliphatic multiple bond by Si-bonded hydrogen; and optionally, (D) agents which slow down the formation of an aliphatic multiple bond by Si-bonded hydrogen at room temperature.

    摘要翻译： 本发明涉及含有（A1）具有脂肪族不饱和烃基的线性有机聚硅氧烷的新的可交联化合物，所述有机聚硅氧烷具有通式（I）R1aR3-aSiO（R2SiO）c [R2Si-Y-SiR2O（R2SiO）c] dSiR3 -bR1b，其中R可以相同或不同，并且表示没有末端脂族碳 - 碳多重键的单价任选卤代烃基，R1表示一价脂族不饱和烃基，Y表示二价有机基团，其为 没有末端脂肪族碳 - 碳多重键，a为0或1，b为0或1，每分子a + b的和为1或2，c为1至1000的整数，d （A1）中可溶的（A2）MQ有机硅树脂，如果不使用MQ有机硅树脂（A2），则为0或0〜1的整数， 式（I）中的+ b平均为1.3〜1.9，如果MQ有机硅树脂 （A2），式（I）中a + b的和平均为1.0〜1.9; （B）具有硅键合氢原子的有机硅化合物; （C）促进通过Si键合氢形成脂族多重键的催化剂; 和任选的（D）在室温下通过Si键合的氢减慢形成脂族多重键的试剂。

    Crosslinkable compositions and their use in the production of coatings which repel sticky substances
    2.
    发明授权
    Crosslinkable compositions and their use in the production of coatings which repel sticky substances 失效
    可交联组合物及其在生产涂覆物质的涂料中的用途

    公开(公告)号：US5134203A

    公开(公告)日：1992-07-28

    申请号：US691912

    申请日：1991-04-26

    申请人： Friedrich Hockemeyer ,  Christian Herzig

    发明人： Friedrich Hockemeyer ,  Christian Herzig

    IPC分类号： C08L83/05 ,  C08L83/06 ,  C08L83/07 ,  C08L83/08 ,  C09D183/04 ,  C09D183/06 ,  C09D183/07 ,  C09D183/08 ,  C09J7/02 ,  C09J183/00 ,  C09J183/07 ,  D21H19/32 ,  D21H27/00 ,  D21H27/06

    CPC分类号： D21H27/001 ,  C08L83/06 ,  C08L83/08 ,  C09D183/06 ,  C09D183/08 ,  D21H19/32 ,  D21H27/06

    摘要： Crosslinkable compositions containing(1) An organopolysiloxane having alkenyloxy functional groups and containing Si-bonded radicals Y of the formula--(CH.sub.2).sub.2 --R.sup.1 --(A--R.sup.2).sub.z --O--R.sup.3 --CH.dbd.CH.sub.2, in whichA represents --O--, --S--or ##STR1## group, R.sup.1 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical of a cycloalkylene radical having from 5 to 7 carbon atoms per radical,R.sup.2 represents a straight-chain or branched alkylene radical having from 2 to 4 carbon atoms per radical, which can be substituted by a hydroxyl group, methoxy group, ethoxy group or trimethylsiloxy group,R.sup.3 represents a straight-chain or branched alkylene radical having from 1 to 7 carbon atoms per radical, and z is 0, 1 or 2,(2) an organopolysiloxane containing Si-bonded hydrogen atoms, and(3) a catalyst which promotes the addition of Si-bonded hydrogen to an aliphatic double bond.

    摘要翻译： 含有（1）具有烯氧基官能团并含有式 - （CH 2）2 -R 1 - （A-R 2）z O-R 3 -CH = CH 2的Si键合基团Y的有机聚硅氧烷的交联组合物，其中A表示-O- ，-S-或基团，R 1表示每个基团具有5至7个碳原子的环亚烷基基团具有1至7个碳原子的直链或支链亚烷基，R 2表示直链或 每个基团具有2至4个碳原子的支链亚烷基，其可被羟基，甲氧基，乙氧基或三甲基甲硅烷氧基取代，R 3表示每个基团具有1至7个碳原子的直链或支链亚烷基 ，z为0,1或2，（2）含有Si键合的氢原子的有机聚硅氧烷，（3）促进将Si键合的氢加成脂肪族双键的催化剂。

    Radiation-curing compositions
    4.
    发明授权
    Radiation-curing compositions 失效
    辐射固化组合物

    公开(公告)号：US06437015B2

    公开(公告)日：2002-08-20

    申请号：US09775767

    申请日：2001-02-02

    申请人： Jochen Dauth ,  Christian Herzig ,  Josef Wolferseder ,  Oliver Zoellner

    发明人： Jochen Dauth ,  Christian Herzig ,  Josef Wolferseder ,  Oliver Zoellner

    IPC分类号： C08J328

    CPC分类号： C09D183/06 ,  C09D183/14 ,  C08L2666/28

    摘要： Radiation-curable compositions containing linear organopolysiloxanes bearing (meth)acryloxy groups and a photosensitizer are useful for release coatings particularly release coatings with enhanced adhesion to the substrate onto which they are coated, for example those used for adhesives such as pressure sensitive adhesive labels.

    摘要翻译： 含有带有（甲基）丙烯酰氧基的线性有机聚硅氧烷和光敏剂的可辐射固化组合物可用于脱模涂层，特别是具有增强的与其所涂覆的基材的粘附性的剥离涂层，例如用于粘合剂如压敏粘合剂标签的那些。

    Polymeric organosilicon compounds, their production and use
    5.
    发明授权
    Polymeric organosilicon compounds, their production and use 失效
    聚合有机硅化合物，其生产和使用

    公开(公告)号：US06258913B1

    公开(公告)日：2001-07-10

    申请号：US09341485

    申请日：1999-08-13

    申请人： Christian Herzig ,  Robert Banfic ,  Reinhard Stallbauer ,  Bernward Deubzer ,  David Heuttner

    发明人： Christian Herzig ,  Robert Banfic ,  Reinhard Stallbauer ,  Bernward Deubzer ,  David Heuttner

    IPC分类号： C08G7708

    CPC分类号： C08G77/50 ,  C08G77/20 ,  C09D183/14 ,  Y10T428/31663 ,  C08L83/00

    摘要： The invention relates to novel polymeric organosilicon compounds comprising hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position. To produce these compounds, (A) compounds containing at least one aliphatic carbon-carbon double bond per molecule, in a terminal position, are reacted with (B) oligomeric or polymeric organosilicon compounds containing units of the general formula R1R2SiO1/2 and units of the general formula HRSiO and/or HSiO3/2 and possibly units of the general formula R2SiO, where R is a monovalent, possibly substituted, hydrocarbon radical with between 1 and 18 carbon atoms per radical, which is free of aliphatic carbon-carbon double bonds, and R1 is a monovalent hydrocarbon radical with between 1 and 18 carbon atoms per radical which has at least one aliphatic carbon-carbon double bond in a terminal position, subject to the condition that the sum of the units HRSiO and R1R2SiO1/2 on average is greater than 2.0 if (B) contains no HSiO3/2 units, and the number of R1 radicals per molecule is greater than the number of Si-bonded hydrogen atoms, in the presence of (C) catalysts promoting the addition of Si-bonded hydrogen to aliphatic double-bonds. The ratio of aliphatic double bonds in components (A) and (B) to Si-bonded hydrogen in component (B) is between 1.5 and 10, subject to the condition that the polymeric organosilicon compounds on average contain more than two hydrocarbon radicals with at least one aliphatic carbon-carbon double bond in a terminal position.

    摘要翻译： 本发明涉及包含在最终位置具有至少一个脂族碳 - 碳双键的烃基的新型聚合物有机硅化合物。 为了制备这些化合物，（A）在每个分子中含有至少一个脂族碳 - 碳双键的化合物在末端与（B）含有通式R 1 R 2 SiO 1/2单元的低聚或聚合有机硅化合物反应， 通式HRSiO和/或HSiO3 / 2以及通式R2SiO的可能单元，其中R是每个基团具有1至18个碳原子的单价可能取代的烃基，其不含脂族碳 - 碳双键 并且R 1是每个基团具有1至18个碳原子的单价烃基，其在末端具有至少一个脂族碳 - 碳双键，条件是平均来说单位HRSiO和R 1 R 2 SiO 1/2的总和 如果（B）不含有HSiO3 / 2单元，并且在（C）催化剂的存在下，每分子的R1基团数目大于Si键合的氢原子的数目，则大于2.0，促进添加 硅键键合到脂肪族双键。 组分（B）中组分（A）和（B）中的脂族双键与Si键合的氢的比例为1.5至10，条件是聚合物有机硅化合物平均含有多于两个烃基， 在末端位置具有至少一个脂族碳 - 碳双键。

    Crosslinkable compositions
    6.
    发明授权
    Crosslinkable compositions 失效
    可交联组合物

    公开(公告)号：US5691435A

    公开(公告)日：1997-11-25

    申请号：US782871

    申请日：1997-01-14

    申请人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Robert Banfic

    发明人： Christian Herzig ,  Bernward Deubzer ,  Martina Bloechl ,  Robert Banfic

    IPC分类号： C08L83/05 ,  C07F7/08 ,  C08G77/12 ,  C08G77/48 ,  C08K5/5419 ,  C08L83/07 ,  C09D183/04 ,  C09D183/05 ,  C09D183/07 ,  C09J183/07 ,  C08G77/08

    CPC分类号： C08K5/5419 ,  C07F7/0896 ,  C08G77/12 ,  C08G77/485 ,  C09D183/04

    摘要： The present invention provides crosslinkable compositions comprising (A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds, (B) an organosilicon compound having Si-bonded hydrogen atoms, (C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bond, and optionally (D) an agent which retards the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature and to the use of the crosslinkable compositions for producing coatings which repel tacky substances. The present invention also relates to organosilicon compounds having Si-bonded hydrogen atoms, and to a process for their preparation.

    摘要翻译： 本发明提供可交联组合物，其包含（A）具有含有脂族碳 - 碳多重键的基团的有机硅化合物，（B）具有Si键合氢原子的有机硅化合物，（C）促进加入Si键合氢的催化剂 和任选的（D）在室温下将Si键合的氢加成到脂肪族多键上的试剂，以及使用可交联组合物来制造排斥粘性物质的涂层。 本发明还涉及具有Si键合的氢原子的有机硅化合物及其制备方法。

    Ammonio-containing organosilicon compounds
    7.
    发明授权
    Ammonio-containing organosilicon compounds 失效
    含氨的有机硅化合物

    公开(公告)号：US06835419B2

    公开(公告)日：2004-12-28

    申请号：US10333937

    申请日：2003-07-30

    申请人： Christian Herzig ,  Robert Banfic

    发明人： Christian Herzig ,  Robert Banfic

    IPC分类号： B05D300

    CPC分类号： C04B41/009 ,  C03C17/30 ,  C04B41/4961 ,  C04B41/84 ,  C08G77/388 ,  D06M15/6436 ,  C04B41/463 ,  C04B33/00 ,  C04B14/00

    摘要： The invention relates to novel organosilicon compounds comprising ammonium groups, said compounds being soluble in isopropanol or diethylene glycol monobutyl ether, and containing: a) at least one structural unit of general formula (I) wherein R2 represents a bivalent organic radical containing a hydroxyl group which is conditioned by a ring opening of an epoxy group; R3 represents a hydrogen atom or a monovalent hydrocarbon radical comprising 1 to 60 carbon atoms per radical, and can be split or substituted by at least one separate heteroatom chosen from the group consisting of nitrogen, oxygen, sulphur or halogen atoms; R4 represents a bivalent hydrocarbon radical comprising 1 to 10 carbon atoms per radical; n represents 0 or a whole number from 1 to 10; m represents a whole number from 1 to the total number of nitrogen atoms in (I); x represents 0 or 1; and X− represents an anion, b) at least one siloxane unit of general formula (II), and c) at least two siloxane units of general formula (III) wherein R, R1, a and b have the designation cited in patent claim (1), provided that the siloxane units of formula (III) are connected to the structural unit of formula (I) via the Si atoms via the R2 radicals.

    摘要翻译： 本发明涉及包含铵基的新型有机硅化合物，所述化合物可溶于异丙醇或二甘醇单丁醚，并含有：a）至少一种通式（I）的结构单元，其中R 2表示含二价有机基团 由环氧基的开环调节的羟基; R 3表示氢原子或每个基团含有1至60个碳原子的单价烃基，并且可以被至少一个选自氮，氧，硫或卤素原子的独立杂原子分裂或取代; R 4表示每个基团含有1-10个碳原子的二价烃基; n表示0或1至10的整数; m表示（I）中从1到氮原子总数的整数; x表示0或1; 并且X 1表示阴离子，b）至少一个通式（II）的硅氧烷单元，和c）至少两个通式（III）的硅氧烷单元，其中R，R 1，a和b具有 式（1）中引用的名称，条件是式（III）的硅氧烷单元经由R 2基团经由Si原子连接到式（I）的结构单元。

    Method for producing silicone polyethers
    10.
    发明授权
    Method for producing silicone polyethers 有权
    硅氧烷聚醚的制备方法

    公开(公告)号：US08084552B2

    公开(公告)日：2011-12-27

    申请号：US12921044

    申请日：2009-03-03

    申请人： Christian Herzig

    发明人： Christian Herzig

    IPC分类号： C08F283/06 ,  C08F283/12 ,  C08G77/46

    CPC分类号： C08G77/46 ,  C08G77/12

    摘要： Silicone polyethers are prepared in a two stage process by reacting an unsaturated polyether with a first Si—H functional organopolysiloxane and then with a second organopolysiloxane, in which the weight ratio of silicon bonded hydrogen in the first and second organopolysiloxanes is at least 0.9. The reaction is more rapid than a single step process and produces a product with less unreacted Si—H content.

    摘要翻译： 通过使不饱和聚醚与第一Si-H官能的有机聚硅氧烷，然后与第二有机聚硅氧烷反应制备硅氧烷聚醚，其中第一和第二有机聚硅氧烷中硅键合氢的重量比至少为0.9。 反应比单步法更快，并产生具有较少未反应的Si-H含量的产物。