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公开(公告)号：US4459189A
公开(公告)日：1984-07-10
申请号：US467088
申请日：1983-02-16
摘要： An electrode in particular an oxygen-evolving anode for metal electrowinning from an acid electrolyte comprises a body of aluminum or other metal coated with lead or a lead alloy by electroplating preferably from a non-aqueous electrolyte. The substrate can be a sheet of aluminium or compacted particles of aluminium plated with lead or a lead alloy. A sheet of lead or lead alloy is clad to the electroplated substrate and advantageously an electrocatalytic material such as surface-activated valve metal sponge is applied to the surface of the lead or lead alloy.
摘要翻译： 电极，特别是用于从酸性电解液进行金属电解提取的氧气放出阳极，包括铝或其他金属的主体，其涂覆有铅或铅合金，优选通过非水电解质电镀。 该基材可以是铝或铝的压片颗粒，其中镀铝的铅或铅合金。 一片铅或铅合金被包覆到电镀基板上，并且有利地将电催化材料如表面活化的阀金属海绵施加到铅或铅合金的表面。
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2.发明授权
公开(公告)号：US4721656A
公开(公告)日：1988-01-26
申请号：US879233
申请日：1986-05-16
申请人： Christopher J. Vance , Thinh Nguyen
发明人： Christopher J. Vance , Thinh Nguyen
IPC分类号： C25D3/56
CPC分类号： C25D3/56 , C25D3/565 , Y10T428/12736
摘要： A coating for metallic faces comprising an alloy of aluminum with at least one of zinc, cadmium or manganese is proposed, whereby the alloy coating is applied onto the metal surface by means of electrodeposition using a non-aqueous electrolyte. The electrolyte comprises toluene as a solvent for chlorides of the alloy components. The coating may be used e.g. for corrosion protection.
摘要翻译： PCT No.PCT / EP85 / 00471 Sec。 371日期：1986年5月16日 102（e）日期1986年5月16日PCT提交1985年9月14日PCT公布。 出版物WO86 / 01840 日本公开1986年3月27日。提出了一种金属表面涂层，其包括铝与锌，镉或锰中的至少一种的合金，由此通过使用非水电解质的电沉积将合金涂层施加到金属表面上 。 电解质包含甲苯作为合金成分氯化物的溶剂。 涂层可以例如使用。 防腐蚀。
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公开(公告)号：US4560446A
公开(公告)日：1985-12-24
申请号：US683006
申请日：1984-12-18
CPC分类号： C25D3/54 , C25D3/56 , Y10T428/12736 , Y10T428/12743 , Y10T428/1275 , Y10T428/12757 , Y10T428/12806 , Y10T428/12812 , Y10T428/12819 , Y10T428/12826
摘要： Transition metals of the groups IVB, VB and VIB or alloys thereof with Al are electrodeposited in a system of an electrolyte based on an aromatic hydrocarbon. The electrolyte is originally prepared by dissolving 0.02 to 0.2 moles of an inexpensive high oxidation state transition metal halide and 0.2 to 0.5 moles AlBr.sub.3 in 1.00 mole of the aromatic hydrocarbon. Additions of transition metal powders or Mg or Al particles lead to the pre-reduction of the high oxidation state transition metal ions to lower oxidation states. Alkali metal or Mg halides may be used to establish favorable bath conditions. The electrolysis is carried out with dissolvable metal anodes, to maintain the bath composition. The plating current density, bath composition and method of preparation are chosen to obtain the desired composition of the coatings.
摘要翻译： 将基团IVB，VB和VIB或其与Al的合金的过渡金属电沉积在基于芳族烃的电解质体系中。 电解质最初通过在1.00摩尔芳烃中溶解0.02至0.2摩尔便宜的高氧化态过渡金属卤化物和0.2至0.5摩尔AlBr 3来制备。 添加过渡金属粉末或Mg或Al颗粒导致高度氧化态过渡金属离子的预还原以降低氧化态。 可以使用碱金属或卤化镁来建立有利的浴条件。 电解是用可溶解的金属阳极进行的，以保持浴组成。 选择电镀电流密度，浴组成和制备方法以获得所需的涂层组成。
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公开(公告)号：US4073702A
公开(公告)日：1978-02-14
申请号：US731374
申请日：1976-10-12
摘要： The invention relates to electrochemical cells whereof one electrode is of a particulate type which may comprise a fluidized bed electrode, a packed bed electrode or a circulating bed electrode, an electrolyte being passed through the particulate electrode possibly for fluidizing and/or circulating the particles of the electrode. Whereas in previous cells of this kind a diaphragm has been arranged between the particulate electrode and the counterelectrode of the cell, it has been discovered that such a cell can be operated with the counterelectrode actually in contact with particles of the particulate electrode provided the material of the surface of the counterelectrode is suitably chosen. Among the materials mentioned are graphite, ruthenium oxide, lead oxide and iron oxide.
摘要翻译： 本发明涉及电化学电池，其中一个电极是颗粒型，其可以包括流化床电极，填充床电极或循环床电极，电解质通过颗粒电极可能用于使颗粒的颗粒流体化和/或循环 电极。 而在以前的这种类型的电池中，已经在颗粒电极和电池的反电极之间布置了隔膜，已经发现这样的电池可以与实际上与电极的颗粒接触的反电极操作， 适当地选择反电极的表面。 所提及的材料是石墨，氧化钌，氧化铅和氧化铁。
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