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    Sulphonated polyesters as finishing agents in detergent, rinsing, softening and textile treatment compositions
    1.
    发明授权
    Sulphonated polyesters as finishing agents in detergent, rinsing, softening and textile treatment compositions 失效
    磺化聚酯作为洗涤剂，漂洗，软化和纺织品处理组合物中的整理剂

    公开(公告)号：US06579466B1

    公开(公告)日：2003-06-17

    申请号：US09887664

    申请日：1997-11-20

    申请人： Claire David ,  Etienne Fleury ,  Yvette Girardeau

    发明人： Claire David ,  Etienne Fleury ,  Yvette Girardeau

    IPC分类号： D06M950

    CPC分类号： C08G63/6884 ,  C11D3/3715 ,  D06M15/5075

    摘要： New water-dispersible or water-soluble sulphonated polyesters with a number molecular mass lower than 20000, exhibiting a sulphur weight content of the order of 0.5 to 10% and a hydroxyl functional group content, expressed as OH equivalent/kg of polymer, higher than 0.2. They may be employed as antisoiling and/or antiredeposition agents and optionally detergents in detergent compositions, in rinsing, softening or antisoiling treatment compositions, for washing with or without pretreatment, rinsing, softening or the antisoiling treatment of textiles, especially those polyester-based.

    摘要翻译： 数均分子量小于20000的新型水分散性或水溶性磺化聚酯，其重量含量为0.5〜10％，羟基官能团含量为OH当量/ kg聚合物，高于 0.2。 它们可以用作洗涤剂组合物，漂洗，软化或防污处理组合物中的防污和/或抗再沉积剂和任选的洗涤剂，用于洗涤或不进行预处理，漂洗，软化或织物处理纺织品，特别是那些基于聚酯的洗涤剂。

    Hydrosoluble/hydrodispersible polyesters and sizing of textile threads therewith
    2.
    发明授权
    Hydrosoluble/hydrodispersible polyesters and sizing of textile threads therewith 失效
    水溶性/水分散性聚酯和纺织线的尺寸

    公开(公告)号：US5290631A

    公开(公告)日：1994-03-01

    申请号：US968306

    申请日：1992-10-29

    申请人： Etienne Fleury ,  Yvette Girardeau

    发明人： Etienne Fleury ,  Yvette Girardeau

    IPC分类号： C08G63/668 ,  C08G63/688 ,  C08G63/78 ,  C08G63/82 ,  C08G63/85 ,  D06M15/507 ,  D02G3/00

    CPC分类号： D06M15/507 ,  C08G63/6886 ,  C08G63/85 ,  D06M7/00 ,  D06M2200/40 ,  Y10T428/2913 ,  Y10T428/31786

    摘要： Hydrosoluble/hydrodispersible polyester copolycondensates, well suited for the sizing of textile threads, comprise terephthalate, isophthalate, sulfoaryl dicarboxylate, ethylene glycol and polyoxyethylene glycol recurring structural units, have a glass transition temperature ranging from 15.degree. to 40.degree. C. at 85% relative humidity and the turbidity of aqueous formulations thereof are storage-stable over time; such polyester copolycondensates are conveniently prepared by (i) transesterifying admixture of dimethyl terephthalate, dimethyl sulfoaryl dicarboxylate and ethylene glycol, (ii) introducing isophthalic acid and an additional amount of ethylene glycol into the medium of transesterification and therein directly esterifying same, and (iii) polycondensing the resulting product of transesterification/direct esterification.

    摘要翻译： 非常适合于纺织线的尺寸的水溶性/水分散性聚酯共缩聚物包括对苯二甲酸酯，间苯二甲酸酯，磺基芳基二羧酸酯，乙二醇和聚氧乙烯二醇重复结构单元，玻璃化转变温度为15℃至40℃，相对于85％ 湿度和其水性制剂的浊度随时间保持稳定; 这种聚酯共缩聚物通过（i）酯交换对苯二甲酸二甲酯，二甲基磺酰基二羧酸二甲酯和乙二醇的混合物，（ii）将间苯二甲酸和另外量的乙二醇引入酯交换介质中并在其中直接酯化， ）缩聚得到的酯交换/直接酯化产物。

    Detergent formulation with anti soiling properties for washing laundry
    3.
    发明授权
    Detergent formulation with anti soiling properties for washing laundry 失效
    洗涤剂配方具有抗污染性能，用于洗衣服

    公开(公告)号：US5710117A

    公开(公告)日：1998-01-20

    申请号：US627517

    申请日：1996-04-04

    申请人： Claire David ,  Etienne Fleury

    发明人： Claire David ,  Etienne Fleury

    IPC分类号： C11D3/00 ,  C11D3/12 ,  C11D3/37

    CPC分类号： C11D3/3726 ,  C11D3/0036 ,  C11D3/128 ,  C11D3/3715 ,  Y10S528/904

    摘要： Detergent formulation for washing laundry characterized in that it comprises: from about 10 to 80% of its weight of at least one hydrated zeolite (z) of formula xNa.sub.2 O.yAl.sub.2 O.sub.3.zSiO.sub.2.wH.sub.2 O in which, if y=1, x is from about 0.7 to 1.1, z is from about 1.3 to 3.3 and w is from about 10 to 264 from about 0.005 to 5%, of its weight of a least one polyalkylene terephthalate-polyoxyalkylenebisurethane (PET-UPOEU) copolymeric nonionic or anionic anti-soiling agent, said copolymer being obtained by reaction of a polyalkylene terephthalate (PET) and a polyoxyalkylnebisurethane (UPOEU), the molar ratio of the NCO functions to all of the OH functions or OH function equivalents being from about 0.5 to 1, from about 3 to 40%, of its weight of a least one saturated C.sub.5 -C.sub.24, aliphatic or hydroxyaliphatic alkyl sulphate anionic surfactant (FAS) optionally condensed with approximately 0.5 to 30 mol of ethylene oxide and/or propylene oxide, optionally, up to 15% of its weight of a nonionic surfactant, it not being possible for more than 5% by weight of the said detergent formulation to consist of an alkylbenzenesulphonate. It has been observed that this PET-UPOEU type of anti-soiling agent, present in low amount in detergent compositions based on zeolite and aliphatic alkyl sulphate, has advantageous anti-soiling properties.

    摘要翻译： 用于洗涤衣物的洗涤剂制剂，其特征在于其包含：其重量的约10至80％的至少一种式xNa2O.yAl2O3.zSiO2.wH2O的水合沸石（z），其中如果y = 1，x为约 0.7至1.1，z为约1.3至3.3，w为约0.005至5重量％的至少一种聚对苯二甲酸亚烷基酯 - 聚氧化亚烷基双氨酯（PET-UPOEU）共聚物非离子或阴离子防污剂 所述共聚物是通过聚对苯二甲酸亚烷基酯（PET）和聚氧化亚烷基双氨酯（UPOEU）的反应获得的，NCO官能团与所有OH官能团或OH官能当量的摩尔比为约0.5至1，约3至40 至少一种饱和C 5 -C 24脂族或羟基脂肪族烷基硫酸盐阴离子表面活性剂（FAS）的重量％，任选地与约0.5至30摩尔环氧乙烷和/或环氧丙烷缩合，任选地至多15重量％ 的非离子表面活性剂 超过5重量％的所述洗涤剂配方可能由烷基苯磺酸盐组成。 已经观察到，基于沸石和脂族烷基硫酸盐的洗涤剂组合物中存在的PET-UPOEU型防污剂具有有利的抗污染性能。

    Soil-repellent agent and process for the treatment of articles based on woven cotton
    4.
    发明授权
    Soil-repellent agent and process for the treatment of articles based on woven cotton 失效
    防污剂和基于编织棉处理制品的方法

    公开(公告)号：US06379394B1

    公开(公告)日：2002-04-30

    申请号：US09631657

    申请日：2000-08-03

    申请人： Emmanuelle Chilou ,  Kenneth Wong ,  Jean-Pierre Marchand ,  Claire David ,  Etienne Fleury

    发明人： Emmanuelle Chilou ,  Kenneth Wong ,  Jean-Pierre Marchand ,  Claire David ,  Etienne Fleury

    IPC分类号： D06L112

    CPC分类号： C11D3/3753 ,  C11D1/60 ,  C11D1/62 ,  C11D3/0036 ,  C11D3/227 ,  C11D3/3707 ,  C11D3/3715 ,  C11D3/3776

    摘要： A soil-repellent treatment method for articles based on woven cotton, wherein an amphiphilic soil-repellent agent soluble or dispersible in the treatment medium is deposited on the article during one or more washing, rinsing and/or softening or dying steps, is disclosed. Said soil-repellent agent comprises at least one unit with a function (FAd) capable of being absorbed onto the surface of the cotton by electrostatic interaction; and at least one hydrophobic unit (MH) capayble of configuring said agent at the cotton/water interface. A soil-repellent agent comprising at least one unit with a cationic function (MC) capable of being absorbed onto the surface of the cotton, and the counter-ion thereof, as well as at least one hydrophobic unit (MH) containing at least four carbon atom chemically bonded to the unit having said cationic function (MC) via an oligomeric, polymeric or copolymeric vinyl alcohol chain, is also disclosed.

    摘要翻译： 公开了一种基于编织棉的制品的防污处理方法，其中在一次或多次洗涤，漂洗和/或软化或染色步骤期间，可溶或可分散在处理介质中的两亲性污垢排斥剂沉积在制品上。 所述防污剂包括至少一个具有功能（FAd）的单元，其能够通过静电相互作用吸收到棉花的表面上; 以及在棉/水界面处配置所述试剂的至少一种疏水单元（MH）盖板。 一种防污剂，其包含至少一种能够吸收到棉花表面上的具有阳离子功能（MC）的单元及其抗衡离子，以及至少一种含有至少四个的疏水单元（MH） 还公开了通过低聚，聚合或共聚乙烯醇链与具有阳离子官能团（MC）的单元化学键合的碳原子。

    HYBRID COMPOUNDS BASED ON POLYOL(S) AND AT LEAST ONE OTHER MOLECULAR ENTITY, POLYMERIC OR NON-POLYMERIC, IN PARTICULAR OF THE POLYORGANOSILOXANE TYPE, PROCESS FOR THE PREPARATION THEREOF, AND APPLICATIONS THEREOF
    7.
    发明申请
    HYBRID COMPOUNDS BASED ON POLYOL(S) AND AT LEAST ONE OTHER MOLECULAR ENTITY, POLYMERIC OR NON-POLYMERIC, IN PARTICULAR OF THE POLYORGANOSILOXANE TYPE, PROCESS FOR THE PREPARATION THEREOF, AND APPLICATIONS THEREOF 审中-公开
    基于聚对苯二甲酸乙二醇酯和至少一种其它分子式的聚合物，聚合物或非聚合物，特别是聚硅氧烷类型的混合物，其制备方法及其应用

    公开(公告)号：US20100048738A1

    公开(公告)日：2010-02-25

    申请号：US12300470

    申请日：2007-05-15

    申请人： Etienne Fleury ,  Sami Halila ,  Hugues Driguez ,  Sylvain Cottaz ,  Thierry Hamaide ,  Sebastien Fort

    发明人： Etienne Fleury ,  Sami Halila ,  Hugues Driguez ,  Sylvain Cottaz ,  Thierry Hamaide ,  Sebastien Fort

    IPC分类号： A61K8/06 ,  C08G77/38 ,  C07H5/04 ,  C11D1/00

    CPC分类号： C08G77/42 ,  A61K8/891 ,  A61Q5/02 ,  A61Q19/10 ,  C07H5/06

    摘要： The invention relates to novel hybrid compounds comprising at least one polyon entity (Po)—for example oligomer or polymer—in which at least one of the hydroxyl functions of Po is substituted by at least one entity A that can be of a variable nature, for example polymer (e.g. polyorganosiloxane-POS), hydrocarbonated or mineral. The bond Ro between the entity Po and the entity A is obtained by means of “click chemistry” and corresponds to formula (II.1) or (II.2), Z representing —CH— or —N—. A is an entity selected from the group comprising the various polyols of Po, polyorganosiloxanes (POS), polyalkylene glycols, polyamides, polyesters, polystyrenes, alkyls, alkenyls, alkynyls, aryls, and combinations thereof, in addition to mineral materials such as silica and the combinations thereof. Said hybrid components can be used as emulsifiers, especially for cosmetics.

    摘要翻译： 本发明涉及包含至少一个多元实体（Po）的新型杂化化合物，例如低聚物或聚合物，其中Po的至少一个羟基官能团被至少一个可变性的实体A所取代， 例如聚合物（例如聚有机硅氧烷-P POS），烃或矿物质。 实体Po和实体A之间的键Ro通过“点击化学”获得，对应于式（II.1）或（II.2），Z表示-CH-或-N-。 A是选自Po，聚有机硅氧烷（POS），聚亚烷基二醇，聚酰胺，聚酯，聚苯乙烯，烷基，烯基，炔基，芳基及其组合的各种多元醇的实体，除矿物材料如二氧化硅和 其组合。 所述混合组分可用作乳化剂，特别是用于化妆品。

    Polysaccharides with oxime or amine functions which are used for water treatment and sludge conditioning
    9.
    发明授权
    Polysaccharides with oxime or amine functions which are used for water treatment and sludge conditioning 失效
    具有肟或胺功能的多糖用于水处理和污泥调理

    公开(公告)号：US07169309B2

    公开(公告)日：2007-01-30

    申请号：US10481658

    申请日：2002-06-27

    申请人： Etienne Fleury ,  Cécile Bonnet-Gonnet ,  Yvette Pescher

    发明人： Etienne Fleury ,  Cécile Bonnet-Gonnet ,  Yvette Pescher

    IPC分类号： C02F1/62

    CPC分类号： C02F1/56 ,  C02F11/14 ,  C02F2101/20 ,  Y10S210/912 ,  Y10S210/913 ,  Y10S210/914

    摘要： The invention relates to a particular polymer which is derived from a copolymer polysaccharide formed by a main chain comprising similar or different anhydrohexose units and branches including at least one neutral or anionic anhydropentose and/or anhydrohexose unit. Moreover, the invention relates to the use of said polymer in the treatment of aqueous media, in particular the treatment of aqueous effluents containing heavy metals, the treatment of waste water, drinking water and for sludge conditioning. Said derivative polymer comprises one or more units bearing an oxime function at least at position C2.

    摘要翻译： 本发明涉及一种特定的聚合物，其衍生自由包含相似或不同的脱氢己糖单元的主链和包含至少一个中性或阴离子脱水西糖和/或脱水己糖单元的分支形成的共聚物多糖。 此外，本发明涉及所述聚合物在水性介质的处理中的用途，特别是处理含有重金属的含水废水，处理废水，饮用水和污泥调理。 所述衍生聚合物包含至少在C2位置具有肟功能的一个或多个单元。