Monitoring and in-system concentration control of polyelectrolytes using
fluorochromatic dyes
    6.
    发明授权
    Monitoring and in-system concentration control of polyelectrolytes using fluorochromatic dyes 失效
    使用荧光染料对聚电解质进行监测和系统浓度控制

    公开(公告)号:US5389548A

    公开(公告)日:1995-02-14

    申请号:US219126

    申请日:1994-03-29

    摘要: Concentration of a polyelectrolyte in the water of an aqueous system is controlled by first withdrawing a sample of the water and adding a known or standard amount of a fluorochromatic reagent to the sample. Then light energy is directed into the sample whereby light energy of a selected excitation wavelength for the fluorochromatic dye is available for absorption by the fluorochromatic reagent. The intensity of light emitted about a selected emission wavelength for the fluorochromatic reagent is measured and the intensity of the emitted light is compared to a standard curve, comprising a plot of fluorescence emission intensity of the fluorochromatic reagent in the presence of a polyelectrolyte versus concentration the polyelectrolyte. The concentration of the polyelectrolyte in the sample of water is determined from the comparison.

    摘要翻译: 通过首先取出水样品并向样品中加入已知或标准量的荧光染料试剂来控制水性体系水中聚电解质的浓度。 然后将光能引导到样品中,由此用于荧光染料的所选择的激发波长的光能可用于由荧光染料试剂吸收。 测量针对荧光色素试剂的选定发射波长发射的光的强度,并将发射光的强度与标准曲线进行比较,其包括在聚电解质存在下荧光染料试剂的荧光发射强度与浓度之间的关系曲线 聚电解质 从比较中确定水样品中聚电解质的浓度。

    On-line iron (II) concentration monitoring to continuously determine
corrosion in boiler systems
    7.
    发明授权
    On-line iron (II) concentration monitoring to continuously determine corrosion in boiler systems 失效
    在线铁(II)浓度监测,以连续测定锅炉系统的腐蚀

    公开(公告)号:US5236845A

    公开(公告)日:1993-08-17

    申请号:US965130

    申请日:1992-10-22

    IPC分类号: G01N31/22

    CPC分类号: G01N31/22

    摘要: A method for determining the presence of ferrous ion in boiler waters is described. The method can be used to directly measure the rate of corrosion occurring in boiler waters, and can measure the corrosion rates in the presence of boiler water treatment chemicals. The method uses a complex formed between only ferrous ion and a chemical 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine-p,p'-disulfonic acid monohydrate reagent.

    摘要翻译: 描述了一种用于确定锅炉水中亚铁离子的存在的方法。 该方法可用于直接测量锅炉水中腐蚀速率,并可在锅炉水处理化学品存在下测量腐蚀速率。 该方法使用仅在亚铁离子和化学3-(2-吡啶基)-5,6-二苯基-1,2,4-三嗪-p,对二磺酸一水合物试剂之间形成的络合物。

    Modified polymers incorporating fatty amines
    8.
    发明授权
    Modified polymers incorporating fatty amines 失效
    掺入脂肪胺的改性聚合物

    公开(公告)号:US4999161A

    公开(公告)日:1991-03-12

    申请号:US297272

    申请日:1989-01-13

    IPC分类号: C08F8/32 C23F11/173

    CPC分类号: C23F11/173 C08F8/12

    摘要: The invention is a method of making water-insoluble aliphatic primary or secondary amines, water-soluble or dispersible, which comprises reacting at a temperature of at least 120.degree. C. these amines with water-soluble acrylamide polymer which contains at least 5 mole percent acrylamide to transamidate not more than 50% mole percent of the acrylamide polymer with the water-insoluble aliphatic primary or secondary amine. The invention also covers a water-soluble or dispersible polymeric composition comprising an acrylic acid polymer having a molecular weight within the range of 500-100,000 which contains between 0.5-50 mole percent of the acrylic acid groups in the form of the amides of a water-insoluble aliphatic primary or secondary amine which contains from 10-36 carbon atoms.

    摘要翻译: 本发明是制备水不溶性脂族伯或仲胺水溶性或分散性的方法,其包括在至少120℃的温度下使这些胺与水溶性丙烯酰胺聚合物反应,所述丙烯酰胺聚合物含有至少5摩尔% 丙烯酰胺以不超过50%摩尔百分比的丙烯酰胺聚合物与水不溶性脂族伯或仲胺反应。 本发明还涵盖水溶性或分散性聚合物组合物,其包含分子量在500-100,000范围内的丙烯酸聚合物,其含有0.5-50摩尔%的水形式的丙烯酸基团 不溶性脂族伯或仲胺,其含有10-36个碳原子。

    Method for inhibiting scale formation and/or dispersing iron in reverse
osmosis systems
    9.
    发明授权
    Method for inhibiting scale formation and/or dispersing iron in reverse osmosis systems 失效
    在反渗透系统中抑制铁垢的形成和/或分散的方法

    公开(公告)号:US5256303A

    公开(公告)日:1993-10-26

    申请号:US916905

    申请日:1992-07-20

    摘要: A method for inhibiting calcium sulfate scale formation and deposition and/or dispersing iron from a feedstream passing through a reverse osmosis system which comprises the steps of: controlling the pH of the feedstream within the range between about 6.0 to about 7.0; controlling the temperature of the feedstream within the range between about 50.degree. to about 80.degree. F.; and adding a scale inhibitor and/or iron disperant to the feedstream in an amount between about 0.002 ppm per ppm hardness (as CaCO.sub.3) of the feedstream to about 0.005 ppm per ppm hardness (as CaCO.sub.3) of the feedstream, the scale inhibitor comprising a water-soluble organic phosphonate and an N-substituted acrylamide polymer containing an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, R.sub.1 is a hydrogen or an alkyl, and R is alkylene or phenylene and X is sulfonate, (poly) hydroxyl, (poly) carboxyl or carbonyl, and combinations thereof, with the weight ratio of polymer to phosphonate being within the range of about 0.2:1 to about 2:1; provided that when X is sulfonated then R--X-- is selected from the group consisting of sulfomethyl and 2-sulfoethyl.

    摘要翻译: 一种通过反渗透系统从进料流中抑制硫酸钙垢形成和沉积和/或分散铁的方法,其包括以下步骤:将原料流的pH控制在约6.0至约7.0之间的范围内; 将进料流的温度控制在约50至约80°F之间的范围内; 并且以进料流的每ppm硬度(作为CaCO 3)的约0.002ppm至进料流的每ppm硬度(作为CaCO 3)至约0.005ppm的量向进料流中加入防垢剂和/或铁挥发物,阻垢剂包含 水溶性有机膦酸酯和含有酰胺结构的N-取代丙烯酰胺聚合物如下:其中R 2是氢或甲基,R 1是氢或烷基,R是亚烷基或亚苯基,X是磺酸酯(聚 )羟基,(多)羧基或羰基及其组合,聚合物与膦酸酯的重量比在约0.2:1至约2:1的范围内; 条件是当X被磺化时,则R-X-选自磺基甲基和2-磺乙基。