公开(公告)号：US07111802B2

公开(公告)日：2006-09-26

申请号：US10880412

申请日：2004-06-28

申请人： Claus G. Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

发明人： Claus G. Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

IPC分类号： B02C19/12

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

摘要翻译： 公开了用于组合（即，高通量）材料研究的方法和装置，例如催化研究，涉及用于同时进行诸如研磨，混合，压制，粉碎，筛分和/或分级的机械处理的并行装置。 。 所述方法和装置可用于机械处理催化材料和其它固体材料，包括但不限于电子材料如磷光体，着色剂如颜料，以及药物如结晶药物或药物候选物。 同时协议和并行设备在制备材料阵列（例如催化材料）方面提供总体通量的显着改进。

公开(公告)号：US07503515B2

公开(公告)日：2009-03-17

申请号：US11519358

申请日：2006-09-11

申请人： Claus G. Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

发明人： Claus G. Lugmair ,  Alfred Hagemeyer ,  Lynn Van Erden ,  Anthony F. Volpe, Jr. ,  David M. Lowe ,  Yumin Liu

IPC分类号： B02C17/18

CPC分类号： B07B1/00 ,  B01J19/0046 ,  B01J35/10 ,  B01J37/0036 ,  B01J37/009 ,  B01J2219/00313 ,  B01J2219/00319 ,  B01J2219/00351 ,  B01J2219/00481 ,  B01J2219/00484 ,  B01J2219/00495 ,  B01J2219/00585 ,  B01J2219/007 ,  B01J2219/00704 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00756 ,  B01L3/5025 ,  B22F2998/00 ,  C40B30/08 ,  C40B40/18 ,  G01N31/10 ,  B22F9/04

摘要： Methods and apparatus for combinatorial (i.e., high-throughput) materials research, such as catalysis research, that involves parallel apparatus for simultaneously effecting mechanical treatments such as grinding, mixing, pressing, crushing, sieving, and/or fractionating of such materials are disclosed. The methods and apparatus are useful for mechanically treating catalysis materials and other solid materials, including without limitation, electronic materials such as phosphors, colorants such as pigments, and pharmaceuticals such as crystalline drugs or drug candidates. The simultaneous protocols and parallel apparatus offer substantial improvements in overall throughput for preparing arrays of materials, such as catalysis materials.

公开(公告)号：US06875717B2

公开(公告)日：2005-04-05

申请号：US10621188

申请日：2003-07-16

申请人： Claus G. Lugmair ,  Damodara M. Poojary ,  Alfred Hagemeyer ,  Daniel M. Giaquinta

发明人： Claus G. Lugmair ,  Damodara M. Poojary ,  Alfred Hagemeyer ,  Daniel M. Giaquinta

IPC分类号： B01J19/00 ,  B01J23/89 ,  B01J37/02 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14 ,  B01J21/00 ,  B01J23/00

CPC分类号： B01J37/0201 ,  B01J19/0046 ,  B01J23/892 ,  B01J2219/00315 ,  B01J2219/00317 ,  B01J2219/00527 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00659 ,  B01J2219/00702 ,  B01J2219/00745 ,  B01J2219/00747 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14

摘要： A method and system for the in situ synthesis of a combinatorial library including impregnating a first component with a second component. The method and system advantageously may be employed in the synthesis of materials for screening for usefulness as a catalyst.

摘要翻译： 用于原位合成组合文库的方法和系统，包括用第二组分浸渍第一组分。 该方法和系统有利地用于合成用于筛选作为催化剂的有用性的材料。

公开(公告)号：US06627571B1

公开(公告)日：2003-09-30

申请号：US09516669

申请日：2000-03-01

申请人： Claus G. Lugmair ,  Damodara M. Poojary ,  Alfred Hagemeyer

发明人： Claus G. Lugmair ,  Damodara M. Poojary ,  Alfred Hagemeyer

IPC分类号： B01J3500

CPC分类号： B01J37/0201 ,  B01J19/0046 ,  B01J23/892 ,  B01J2219/00315 ,  B01J2219/00317 ,  B01J2219/00527 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00659 ,  B01J2219/00702 ,  B01J2219/00745 ,  B01J2219/00747 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14

摘要： A method and system for the in situ synthesis of a combinatorial library including impregnating a first component with a second component. The method and system advantageously may be employed in the synthesis of materials for screening for usefulness as a catalyst.

摘要翻译： 用于原位合成组合文库的方法和系统，包括用第二组分浸渍第一组分。 该方法和系统有利地用于合成用于筛选作为催化剂的有用性的材料。

公开(公告)号：US08465678B2

公开(公告)日：2013-06-18

申请号：US13078658

申请日：2011-04-01

申请人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yijun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

发明人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yijun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

IPC分类号： H01B1/12 ,  H01B1/06 ,  H01B1/00

CPC分类号： C08L101/12 ,  B82Y10/00 ,  C08F257/02 ,  C08G61/00 ,  C08G61/10 ,  C08L65/00 ,  C09K9/02 ,  C09K11/06 ,  G01N21/6428 ,  G01N21/643 ,  G01N21/7703 ,  G01N2021/7786 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0044 ,  H01L51/0052 ,  H01L51/0077 ,  H01L51/0545 ,  H01L51/0595 ,  H01L51/428 ,  H01L51/5012 ,  Y02E10/549 ,  C08F232/00

摘要： The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

公开(公告)号：US20110175035A1

公开(公告)日：2011-07-21

申请号：US13078658

申请日：2011-04-01

申请人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yi-Jun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

发明人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yi-Jun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

IPC分类号： H01B1/12

CPC分类号： C08L101/12 ,  B82Y10/00 ,  C08F257/02 ,  C08G61/00 ,  C08G61/10 ,  C08L65/00 ,  C09K9/02 ,  C09K11/06 ,  G01N21/6428 ,  G01N21/643 ,  G01N21/7703 ,  G01N2021/7786 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0044 ,  H01L51/0052 ,  H01L51/0077 ,  H01L51/0545 ,  H01L51/0595 ,  H01L51/428 ,  H01L51/5012 ,  Y02E10/549 ,  C08F232/00

摘要： The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

摘要翻译： 本发明涉及一类具有发色团的发光和导电聚合物组合物，特别是这些组合物的固体膜显示增加的发光寿命，量子产率和放大的发射。 这些所需的性质可以通过具有刚性基团的聚合物来提供，所述刚性基团被设计成防止聚合物重组，聚集或固化时堆积。 这些聚合物在溶剂和热暴露方面也能表现出非常高的稳定性。 本发明还涉及通过这些聚合物的发光和导电性质来感测分析物的传感器和方法。 可以通过在聚合物表面活化发色团来感测分析物。 分析物包括芳族化合物，磷酸酯基团，特别是气态的爆炸物和化学战剂。 本发明还涉及通过引入具有能量迁移途径的聚合物和/或提供聚合物作为嵌段共聚物或作为多层来扩增发射的装置和方法。

公开(公告)号：US07134459B2

公开(公告)日：2006-11-14

申请号：US10860113

申请日：2004-06-03

申请人： Eric Carlson ,  Li Song ,  Daniel M. Pinkas ,  Claus G. Lugmair

发明人： Eric Carlson ,  Li Song ,  Daniel M. Pinkas ,  Claus G. Lugmair

IPC分类号： B65B1/04

CPC分类号： B01F15/0445 ,  B01F3/188 ,  B01F13/0272 ,  B01F13/1055 ,  B01F15/0258 ,  B01F2015/0221 ,  B01F2215/0037 ,  B65B1/16 ,  B65B1/30 ,  G01G13/24

摘要： Method for preparing a mixed powder sample by mixing two or more different powders comprising transferring a quantity of a first powder to a mixing vessel and transferring a quantity of a second powder to the mixing vessel to form a powder bed in the mixing vessel comprising the first and second powders. The quantities of the powders are selected so the mixed sample has a predetermined ratio of first powder to second powder. The powder bed is fluidized to mix the powders and produce a mixed sample. The mixed sample weighs about 5 grams or less. The invention also includes apparatus for preparing mixed powder samples by mixing two or more different powders.

摘要翻译： 通过混合两种或多种不同的粉末来制备混合粉末样品的方法，包括将一定数量的第一粉末转移到混合容器中，并将一定量的第二粉末转移到混合容器中，以在混合容器中形成粉末床， 和第二粉末。 选择粉末的量，使得混合样品具有预定比例的第一粉末与第二粉末。 将粉末床流化以混合粉末并产生混合样品。 混合样品重约5克或更少。 本发明还包括通过混合两种或更多种不同粉末制备混合粉末样品的装置。

公开(公告)号：US07754910B2

公开(公告)日：2010-07-13

申请号：US12011954

申请日：2008-01-29

申请人： Claus G. Lugmair ,  Steven Alan Cohen ,  Gerry W. Zajac ,  Alakananda Bhattacharyya ,  Bhagya Chandra Sutradhar ,  James F. Brazdil, Jr.

发明人： Claus G. Lugmair ,  Steven Alan Cohen ,  Gerry W. Zajac ,  Alakananda Bhattacharyya ,  Bhagya Chandra Sutradhar ,  James F. Brazdil, Jr.

IPC分类号： C07B43/08

CPC分类号： C07C253/24 ,  B01J23/002 ,  B01J23/28 ,  B01J27/0576 ,  B01J2523/00 ,  Y02P20/52 ,  C07C255/08 ,  B01J2523/3725 ,  B01J2523/47 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/42 ,  B01J2523/11

摘要： A process for the ammoxidation of a saturated or unsaturated or mixture of saturated and unsaturated hydrocarbon to produce an unsaturated nitrile, said process comprising contacting the saturated or unsaturated or mixture of saturated and unsaturated hydrocarbon with ammonia and an oxygen-containing gas in the presence of a catalyst composition comprising molybdenum, vanadium, antimony, niobium, tellurium, optionally at least one element select from the group consisting of titanium, tin, germanium, zirconium, hafnium, and optionally at least one lanthanide selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, samarium, europium, gadolinium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium. Such catalysts are characterized by very low levels of tellurium in the composition. Such catalyst compositions are effective for the gas-phase conversion of propane to acrylonitrile and isobutane to methacrylonitrile (via ammoxidation).

摘要翻译： 饱和或不饱和或饱和和不饱和烃的混合物的氨氧化以产生不饱和腈的方法，所述方法包括使饱和或不饱和烃或饱和和不饱和烃的混合物与氨和含氧气体在 包含钼，钒，锑，铌，碲，任选地至少一种选自钛，锡，锗，锆，铪和任选的至少一种镧系元素的催化剂组合物，所述镧系元素选自镧，铈 镨，钕，钐，铕，钆，镝，钬，铒，ium，镱，镥等。 这种催化剂的特征在于组合物中碲含量非常低。 这种催化剂组合物可有效地将丙烷气相转化为丙烯腈和异丁烷至甲基丙烯腈（通过氨氧化）。

公开(公告)号：US07393503B2

公开(公告)日：2008-07-01

申请号：US11252530

申请日：2005-10-17

申请人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yijun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

发明人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yijun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

IPC分类号： C08G61/02

CPC分类号： C08L101/12 ,  B82Y10/00 ,  C08F257/02 ,  C08G61/00 ,  C08G61/10 ,  C08L65/00 ,  C09K9/02 ,  C09K11/06 ,  G01N21/6428 ,  G01N21/643 ,  G01N21/7703 ,  G01N2021/7786 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0044 ,  H01L51/0052 ,  H01L51/0077 ,  H01L51/0545 ,  H01L51/0595 ,  H01L51/428 ,  H01L51/5012 ,  Y02E10/549 ,  C08F232/00

摘要： The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

摘要翻译： 本发明涉及一类具有发色团的发光和导电聚合物组合物，特别是这些组合物的固体膜显示增加的发光寿命，量子产率和放大的发射。 这些期望的性质可以通过具有刚性基团的聚合物来提供，所述刚性基团被设计成在凝固时防止聚合物重组，聚集或π层叠。 这些聚合物在溶剂和热暴露方面也能表现出非常高的稳定性。 本发明还涉及通过这些聚合物的发光和导电性质来感测分析物的传感器和方法。 可以通过在聚合物表面活化发色团来感测分析物。 分析物包括芳族化合物，磷酸酯基团，特别是气态的爆炸物和化学战剂。 本发明还涉及通过引入具有能量迁移途径的聚合物和/或提供聚合物作为嵌段共聚物或作为多层来扩增发射的装置和方法。

公开(公告)号：US07943062B2

公开(公告)日：2011-05-17

申请号：US12693942

申请日：2010-01-26

申请人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yijun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

发明人： Timothy M. Swager ,  Jye-Shane Yang ,  Vance Williams ,  Yijun Miao ,  Claus G. Lugmair ,  Igor A. Levitsky ,  Jinsang Kim ,  Robert Deans

IPC分类号： H01L51/54

CPC分类号： C08L101/12 ,  B82Y10/00 ,  C08F257/02 ,  C08G61/00 ,  C08G61/10 ,  C08L65/00 ,  C09K9/02 ,  C09K11/06 ,  G01N21/6428 ,  G01N21/643 ,  G01N21/7703 ,  G01N2021/7786 ,  H01L51/0035 ,  H01L51/0043 ,  H01L51/0044 ,  H01L51/0052 ,  H01L51/0077 ,  H01L51/0545 ,  H01L51/0595 ,  H01L51/428 ,  H01L51/5012 ,  Y02E10/549 ,  C08F232/00

摘要： The present invention relates to a class of luminescent and conductive polymer compositions having chromophores, and particularly solid films of these compositions exhibiting increased luminescent lifetimes, quantum yields and amplified emissions. These desirable properties can be provided through polymers having rigid groups designed to prevent polymer reorganization, aggregation or π-stacking upon solidification. These polymers can also display an unusually high stability with respect to solvent and heat exposures. The invention also relates to a sensor and a method for sensing an analyte through the luminescent and conductive properties of these polymers. Analytes can be sensed by activation of a chromophore at a polymer surface. Analytes include aromatics, phosphate ester groups and in particular explosives and chemical warfare agents in a gaseous state. The present invention also relates to devices and methods for amplifying emissions by incorporating a polymer having an energy migration pathway and/or providing the polymer as a block co-polymer or as a multi-layer.

摘要翻译： 本发明涉及一类具有发色团的发光和导电聚合物组合物，特别是这些组合物的固体膜显示增加的发光寿命，量子产率和放大的发射。 这些所需的性质可以通过具有刚性基团的聚合物来提供，所述刚性基团被设计成防止聚合物重组，聚集或固化时堆积。 这些聚合物在溶剂和热暴露方面也能表现出非常高的稳定性。 本发明还涉及通过这些聚合物的发光和导电性质来感测分析物的传感器和方法。 可以通过在聚合物表面活化发色团来感测分析物。 分析物包括芳族化合物，磷酸酯基团，特别是气态的爆炸物和化学战剂。 本发明还涉及通过引入具有能量迁移途径的聚合物和/或提供聚合物作为嵌段共聚物或作为多层来扩增发射的装置和方法。