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公开(公告)号：US06872230B2
公开(公告)日：2005-03-29
申请号：US10197307
申请日：2002-07-16
CPC分类号： C10L10/08 , C10L1/14 , C10L1/2227 , C10L1/232
摘要： The present invention relates to additives for enhancing the lubricity of hydrocarbon fuel oils, the inventive additive composition including one or more of the reaction products of (i) an alkylated polyamine and (ii) urea or isocyanate, or the salt adducts of these reaction products. More particularly, the present invention provides for a process for improving the lubricity of hydrocarbon fuel oils, which are low in inherent lubricity due to treatment to reduce sulfur and aromatic components for improved emissions.
摘要翻译： 本发明涉及用于增强烃燃料油的润滑性的添加剂，本发明的添加剂组合物包括一种或多种（i）烷基化多胺和（ii）脲或异氰酸酯的反应产物或这些反应产物的盐加合物 。 更具体地说，本发明提供了一种用于改善烃燃料油的润滑性的方法，由于用于减少硫和芳族组分以改善排放物的处理，固体润滑性低。
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2.发明授权公开(公告)号：US07576136B2
公开(公告)日：2009-08-18
申请号：US11146954
申请日：2005-06-07
CPC分类号： C10G11/14 , B01F3/0811 , B01F3/0861 , B01F5/0602 , C10G11/18 , Y10S516/924
摘要： The present invention is directed to a method for producing an emulsified aqueous hydrocarbon solution comprising, providing a liquid hydrocarbon stream at a particular temperature and a separate water stream, mixing the water stream with a surfactant at a predetermined ratio, raising the pressure of the hydrocarbon stream to a pressure greater than the vapor pressure of steam at the temperature, spraying the water into the hydrocarbon stream at a pressure greater than that of the hydrocarbon stream in a pre-mix chamber; and passing the pressurized hydrocarbon-water mixture through a static mixing chamber.
摘要翻译： 本发明涉及一种生产乳化的含水烃溶液的方法，其包括：在特定温度下提供液态烃流和单独的水流，以预定比例混合水流与表面活性剂，提高烃的压力 在高于在该温度下的蒸汽压力的压力下流动，将水以比预混合室中的烃流的压力高的速率喷射到烃流中; 并将加压的烃 - 水混合物通过静态混合室。
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公开(公告)号：US07553878B2
公开(公告)日：2009-06-30
申请号：US10425153
申请日：2003-04-29
CPC分类号： C10L1/328
摘要： The present invention provides a feedstock composition for increasing the efficiency of atomization in hydrocarbon processing that includes a water-in-hydrocarbon oil emulsion including a non-ionic surfactant capable of stabilizing the emulsion and having a hydrophilic-lipophilic balance of greater than about 12. The emulsion includes water droplets of about 5 to about 10 microns in diameter, the droplets being dispersed substantially uniformly in the hydrocarbon oil phase. These surfactants are capable of stabilizing the water-in-hydrocarbon oil emulsion under relevant temperature and pressure conditions for hydrocarbon processing. The inventive feedstock composition provides a metastable water-in-oil emulsion where expanding water vapor explodes under spray conditions where the system pressure is released, demolishing a larger oil droplet and producing smaller oil droplets.
摘要翻译： 本发明提供了一种用于提高烃加工中雾化效率的原料组合物，其包括含烃烃油乳液，其包括能够稳定乳液并具有大于约12的亲水亲油平衡的非离子表面活性剂。 该乳液包括直径约5至约10微米的水滴，液滴基本均匀地分散在烃油相中。 这些表面活性剂能够在碳氢化合物加工的相关温度和压力条件下稳定含烃烃油乳液。 本发明的原料组合物提供了一种亚稳定的油包水乳液，其中膨胀水蒸汽在喷雾条件下爆炸，其中释放系统压力，拆除较大的油滴并产生较小的油滴。
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公开(公告)号：US20110301061A1
公开(公告)日：2011-12-08
申请号：US12795217
申请日：2010-06-07
CPC分类号： G01N33/2823 , B01F3/0807 , B01F11/0014 , C10G33/08 , C10G2300/80
摘要： A process for testing the effectiveness of demulsifying additives on oil/water emulsions includes adding samples containing differing combinations of oil, water and demulsifier to a plurality of elongate reactor vials, wherein each the elongate reactor vial has a longitudinal axis extending from its bottom to its rim. The plurality of reactor vials are placed into a reaction block mounted on a platform of a shaker, wherein the reactor vials are received in stations of the reaction block in a vertical orientation such that the longitudinal axis of each reactor vial is perpendicular to the platform. The reaction block is pivoted the so that the longitudinal axis of each reactor vial is parallel with the platform in a horizontal orientation. The method further includes agitating the reactor vials with the shaker to simultaneously form an oil/water emulsion in each reactor vial while the reactor vials are in the horizontal orientation and then pivoting the reaction block to return the reactor vials to a vertical orientation. The demulsification of the oil/water emulsion in the plurality of reactor vials is observed with the reactor vials in the vertical orientation. In one embodiment, the method further includes using an imaging device to record the demulsification of the oil/water emulsion.
摘要翻译： 用于测试乳化添加剂对油/水乳液的有效性的方法包括将含有油，水和破乳剂的不同组合的样品添加到多个细长反应器小瓶中，其中每个细长反应器小瓶具有从其底部延伸到其的 轮缘。 将多个反应器小瓶放置在安装在振荡器的平台上的反应块中，其中反应器小瓶以垂直方向接收在反应块的站中，使得每个反应器小瓶的纵向轴线垂直于平台。 反应块枢转，使得每个反应器小瓶的纵向轴线在水平方向上与平台平行。 该方法还包括用振荡器搅拌反应器小瓶，以在每个反应器小瓶中同时形成油/水乳剂，同时反应器小瓶处于水平取向，然后枢转反应块以将反应器小瓶返回到垂直取向。 在反应器小瓶中以垂直取向观察多个反应器小瓶中的油/水乳液的破乳。 在一个实施方案中，该方法还包括使用成像装置记录油/水乳液的破乳。
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公开(公告)号：US07740750B2
公开(公告)日：2010-06-22
申请号：US11456128
申请日：2006-07-07
申请人： Andre Vanhove , Tiffany N. Morris , Alan E. Goliaszewski , Brian W. Lasiuk , Donato Vinciguerra
发明人： Andre Vanhove , Tiffany N. Morris , Alan E. Goliaszewski , Brian W. Lasiuk , Donato Vinciguerra
IPC分类号： C10G9/16
CPC分类号： G01N21/534 , C10G9/007 , G01N15/0612 , G01N21/05 , G01N21/51 , G01N21/5911 , G01N33/28 , G01N2021/0346
摘要： A system and method for quantifying opaque inhomogeneities within a fluid sample. The system uses an optical lens system to focus a light beam onto a stage where the sample is introduced. The light beam is directed onto the sample in a pattern such that the intensity of transmitted light is measured as a function of path length. A photo detector measures the transmitted light through the sample. Fluctuations in transmitted light intensity are then correlated with detection of opaque inclusions in the sample. The system also includes an automated program which utilizes these optical concentration measurements to determine the fouling potential of visbroken tars, and regulates the introduction of chemical inhibitors into a visbreaker unit to improve the yield of light streams and/or economic value of product.
摘要翻译： 用于量化流体样品中不透明不均匀性的系统和方法。 该系统使用光学透镜系统将光束聚焦到引入样品的台上。 光束以图案的形式被引导到样品上，使得测量透射光的强度作为路径长度的函数。 光检测器测量通过样品的透射光。 然后透射光强度的波动与样品中不透明夹杂物的检测相关。 该系统还包括一个自动程序，利用这些光学浓度测量来确定减粘裂纹的污垢势，并且调节将化学抑制剂引入到抗裂解单元中以提高轻质物流的产率和/或产品的经济价值。
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6.发明授权
公开(公告)号：US5910469A
公开(公告)日：1999-06-08
申请号：US742726
申请日：1996-11-01
IPC分类号： C10G9/16 , C10G75/04 , C10M137/12
CPC分类号： C10G9/16 , C10G75/04 , Y10S585/95
摘要： Alkylphosphonate ester compounds or acids thereof are disclosed as effective fouling inhibitors in liquid hydrocarbonaceous medium undergoing processing at elevated temperatures.
摘要翻译： 烷基膦酸酯化合物或其酸被公开为在高温下进行加工的液体烃类介质中的有效结垢抑制剂。
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公开(公告)号：US5512183A
公开(公告)日：1996-04-30
申请号：US350879
申请日：1994-12-07
IPC分类号： C02F5/14
CPC分类号： C02F5/14
摘要： A water soluble isopropenylphosphonic acid copolymer composition and method of use thereof are disclosed. The copolymer comprises repeat units (a) of the formula: ##STR1## wherein X=OH or OM, wherein M is a cation, and repeat units (b) of the formula: ##STR2## wherein R.sub.1 and R.sub.2 are independently hydrogen, C.sub.1-10 linear or branched alkyl, phenyl or alkyl substituted phenyl. The copolymers are effective in inhibiting the precipitation of scale forming salts and also act to inhibit corrosion in boiler water systems.
摘要翻译： 公开了一种水溶性异丙烯基膦酸共聚物组合物及其使用方法。 共聚物包含下式的重复单元（a）：其中X = OH或OM，其中M为阳离子，并具有下式的重复单元（b）：其中R 1和R 2独立地为氢，C 1 -10直链或支链烷基，苯基或烷基取代的苯基。 共聚物有效抑制垢形成盐的沉淀，并且还起到抑制锅炉水体系中的腐蚀作用。
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公开(公告)号：US4666632A
公开(公告)日：1987-05-19
申请号：US883229
申请日：1986-07-08
CPC分类号： B01J37/06 , B01J23/20 , C07C45/46 , Y10S502/508
摘要： Anthraquinone is produced by reacting phthalic anhydride with benzene in the liquid phase over a super acid catalyst which may be an oxide of the Group 4b metals zirconium, hafnium, and titanium, or the Group 5b metals niobium, tantalum, and vanadium, preferably zirconium oxide, such oxides being treated with sulfuric acid and calcined. The process may also be applied to substituted equivalents, such as methyl phthalic anhydride and toluene.
摘要翻译： 蒽醌是通过邻苯二甲酸酐与苯在液相中超过可以是第4b族金属锆，铪和钛的氧化物或第5b族金属铌，钽和钒的氧化物，优选氧化锆 ，这种氧化物用硫酸处理并煅烧。 该方法也可以应用于取代的等同物，例如甲基邻苯二甲酸酐和甲苯。
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公开(公告)号：US5643500A
公开(公告)日：1997-07-01
申请号：US505934
申请日：1995-07-24
申请人： Bruno Morin , Alan E. Goliaszewski
发明人： Bruno Morin , Alan E. Goliaszewski
CPC分类号： C09K8/54 , Y10S507/939 , Y10S585/95
摘要： The present invention is directed towards the use of a reaction product of an alkynediol and a polyalkylene polyamine to inhibit metal surface corrosion caused by water present in the hydrocarbons in oil pipelines.
摘要翻译： 本发明涉及使用炔二醇和聚亚烷基多胺的反应产物来抑制由油管道中的烃中存在的水引起的金属表面腐蚀。
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10.发明授权Methods and compositions for reducing fouling deposit formation in jet engines 失效用于减少喷气发动机中结垢沉积物形成的方法和组合物
公开(公告)号：US5596130A
公开(公告)日：1997-01-21
申请号：US548110
申请日：1995-10-25
申请人： Bruce E. Wright , William L. Witzig , Alan E. Goliaszewski , William S. Carey , Jeffrey H. Peltier
发明人： Bruce E. Wright , William L. Witzig , Alan E. Goliaszewski , William S. Carey , Jeffrey H. Peltier
CPC分类号： C10L10/02 , C10L1/14 , C10L1/143 , C10L1/2608 , C10L1/2616 , C10L1/2683 , C10L10/04 , C10L10/06 , C10L1/1608 , C10L1/1616 , C10L1/1832 , Y10S585/95
摘要： Methods and compositions are provided for cleaning and inhibiting the formation of fouling deposits on jet engine components during the combustion of turbine combustion fuel oils. Methods and compositions are also provided for inhibiting the formation and emission of soot and smoke from jet engine exhaust during turbine combustion fuel oil combustion. The methods employ a derivative of (thio)phosphonic acid added to the turbine combustion fuel oil. The preferred derivative is pentaerythritol ester of polyisobutenylthiophosphonic acid.
摘要翻译： 提供了用于在涡轮燃烧燃料油的燃烧期间清洁和抑制在喷气发动机部件上形成污垢沉积物的方法和组合物。 还提供了用于在涡轮燃烧燃料油燃烧期间抑制来自喷气发动机排气的烟灰和烟雾的形成和排放的方法和组合物。 该方法使用添加到涡轮燃烧燃料油中的（硫代）膦酸的衍生物。 优选的衍生物是聚异丁烯基硫代膦酸的季戊四醇酯。
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