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公开(公告)号：US20230407106A1
公开(公告)日：2023-12-21
申请号：US18223268
申请日：2023-07-18
CPC分类号： C09D5/1668 , C09D133/14 , C09D7/63 , C08F20/30 , C08K5/17 , C08K5/24
摘要： Disclosed are architectural compositions, including aqueous paint and stain compositions, that utilized copolymers including bio-based cross-linking monomers and their synthetic analogues that are comparable to copolymers including DAAM cross-linking monomers. The bio-based cross-linking monomers are preferably synthetic version of the bio-based cross-linking monomers.
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2.发明授权公开(公告)号：US09453133B2
公开(公告)日：2016-09-27
申请号：US14531354
申请日：2014-11-03
发明人： Gary Dandreaux , Ashley Brewer , Caleb Jardel , Paulina Ogorzalek , Luz Clarena Shavel , Robert Sheerin
IPC分类号： C09D7/12 , C08F265/02 , C08F265/06 , C09D151/00 , C08F285/00
CPC分类号： C09D7/125 , C08F265/02 , C08F265/06 , C08F285/00 , C09D7/65 , C09D151/003
摘要： The architectural compositions, such as paints and stains, include an additive comprising a plurality of latex particles added to an existing mixture of opacifying pigments and a film-forming binder as an admixture. Each latex particle is made from a latex polymer copolymerized with a polymerizable surfactant. The latex polymer is a non-film forming polymer at ambient temperatures.
摘要翻译： 建筑组合物，例如油漆和污渍，包括添加剂，其添加到现有的不透明颜料混合物和作为混合物的成膜粘合剂中的胶乳颗粒。 每个胶乳颗粒由与可聚合表面活性剂共聚的胶乳聚合物制成。 胶乳聚合物是环境温度下的非成膜聚合物。
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公开(公告)号：US20160186000A1
公开(公告)日：2016-06-30
申请号：US14793013
申请日：2015-07-07
发明人： Shi-Jun Yang , Gary Dandreaux , Robert J. Sheerin , Caleb Jardel
IPC分类号： C09D133/26
CPC分类号： C09D133/26 , C08K5/20 , C08K5/25 , C08L2201/54 , C09D133/12 , C08F2220/1825 , C08F220/14 , C08F212/08 , C08F220/36 , C08F220/06 , C08F220/54 , C08F220/58 , C08F2220/1858 , C08F218/10
摘要： The present invention relates to storage stable film forming latex particles that crosslink under ambient conditions during or after drying. Monomers for the formation of the crosslinkable moieties in the latex particles include diacetone acrylamide (DAAM) or the likes and methacrylamide (MAM) or the likes with or without styrene. A paint composition comprising the storage stable latex particles that may include a small amount or crosslinking agent such as adipic acid dihydrazide (ADH) in the aqueous phase is also described.
摘要翻译： 本发明涉及在干燥期间或之后在环境条件下交联的保存稳定的成膜胶乳颗粒。 用于在胶乳颗粒中形成可交联部分的单体包括双丙酮丙烯酰胺（DAAM）或类似物和甲基丙烯酰胺（MAM）或类似物，或不含苯乙烯。 还描述了包含在水相中可包含少量的储存稳定的胶乳颗粒或交联剂如己二酸二酰肼（ADH）的涂料组合物。
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公开(公告)号：US09115265B2
公开(公告)日：2015-08-25
申请号：US14281150
申请日：2014-05-19
发明人： Shi-Jun Yang , Gary Dandreaux , Robert J. Sheerin
IPC分类号： C08K5/20
CPC分类号： C08K5/20
摘要： The present invention relates to storage stable film forming latex particles substantially free of adipic acid dihydrazide (ADH) that crosslink under ambient conditions during or after drying. Monomers for the formation of the crosslinkable moieties in the latex particles include diacetone acrylamide (DAAM) or the likes and methacrylamide (MAM) or the likes with or without styrene. A paint composition comprising the storage stable latex particles was described.
摘要翻译： 本发明涉及基本上不含在干燥期间或之后在环境条件下交联的己二酸二酰肼（ADH）的保存稳定的成膜胶乳颗粒。 用于在胶乳颗粒中形成可交联部分的单体包括双丙酮丙烯酰胺（DAAM）或类似物和甲基丙烯酰胺（MAM）或类似物，或不含苯乙烯。 描述了包含储存稳定的胶乳颗粒的涂料组合物。
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5.发明申请Grafted Pigment Dispersing Polymeric Additive and Paint Employing the Same with Improved Hiding 有权接枝颜料分散聚合物添加剂和涂料使用与改进隐藏公开(公告)号：US20140171585A1
公开(公告)日：2014-06-19
申请号：US13717781
申请日：2012-12-18
IPC分类号： C08F257/02 , C08F265/04
CPC分类号： C08F257/02 , C08F265/02 , C08F265/04 , C08F265/06 , C08F285/00 , C09D151/003
摘要： The present invention relates to a grafted pigment dispersing polymeric additive for opacifying pigments, prepared by polymerizing monomers in the presence of a polymeric pigment dispersant. The polymeric pigment dispersant has low molecular weight, high acid number and is dissolvable in alkali solution. When incorporated into paint compositions, hiding is improved with less opacifying pigments.
摘要翻译： 本发明涉及通过在聚合颜料分散剂存在下聚合单体制备的用于不透明颜料的接枝颜料分散聚合物添加剂。 聚合颜料分散剂具有低分子量，高酸值，可溶于碱溶液。 当掺入油漆组合物中时，用较少的不透明颜料改善遮盖性。
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公开(公告)号：US20240336800A1
公开(公告)日：2024-10-10
申请号：US18131137
申请日：2023-04-05
发明人： Samantha Marie Mascetti , Xinyu Wang , Clarena Shavel , Paulina Ogorzalek , Yong Yang , Gary Dandreaux
IPC分类号： C09D119/02 , C09D4/00 , C09D5/14 , C09D7/41 , C09D7/65 , C09D185/02
CPC分类号： C09D119/02 , C09D4/00 , C09D5/14 , C09D7/41 , C09D7/65 , C09D185/02
摘要： Disclosed herein is an aqueous architectural composition forming a paint film on a substrate capable of resisting hydrophobic and hydrophilic stains. The architectural composition includes a film forming latex resin, a high molecular weight silicone resin, and a wax microsphere. The stain resistant architectural composition may also include at least one organic extender pigment, a fluorosurfactant and a phosphate monomer.
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公开(公告)号：US09499680B2
公开(公告)日：2016-11-22
申请号：US14343292
申请日：2012-09-18
发明人： Shi-Jun Yang , Gary Dandreaux , Robert J. Sheerin
IPC分类号： C08L1/08 , C08F6/00 , C08K3/20 , C08B11/08 , C08B11/20 , C08F251/02 , C08F8/10 , C09D151/02 , C08L1/28
CPC分类号： C08K3/20 , C08B11/08 , C08B11/20 , C08F6/006 , C08F8/10 , C08F251/02 , C08L1/08 , C08L1/284 , C09D151/02 , C08F220/18 , C08F212/08 , C08F220/06 , C08F220/56 , C08L51/02
摘要： The present invention relates to latex compositions comprising hydroxyethyl cellulose grafted acrylic polymer emulsions and methods for preparing same without gelling or coagulation. The latex composition comprises at least about 0.2% of HEC by weight relative to the monomer weight, contains at least about 45% solid, and the average mean volume (mV) latex particle size is in the range of about 320-about 850 nm. Paint compositions incorporating the HEC grafted acrylic latex show high viscosity at static conditions and have no color flow and no syneresis compared paints containing a latex without HEC grafting. The present invention also relates to a cross-linking mechanism that cross-links latex particles at ambient conditions. This cross-linking mechanism comprises diacetone acrylamide (DAAM) and methacrylamide (MAM) with or without styrene.
摘要翻译： 本发明涉及包含羟乙基纤维素接枝的丙烯酸聚合物乳液的胶乳组合物及其制备方法而不凝胶化或凝结。 胶乳组合物包含相对于单体重量的至少约0.2重量％的HEC，含有至少约45％的固体，并且平均体积（mV）胶乳粒度在约320-约850nm的范围内。 掺入HEC接枝丙烯酸胶乳的涂料组合物在静态条件下显示出高粘度，并且没有颜色流动，没有脱水收缩比较含有没有HEC接枝的胶乳的涂料。 本发明还涉及在环境条件下交联胶乳颗粒的交联机理。 该交联机理包括具有或不具有苯乙烯的双丙酮丙烯酰胺（DAAM）和甲基丙烯酰胺（MAM）。
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公开(公告)号：US20140323635A1
公开(公告)日：2014-10-30
申请号：US14281150
申请日：2014-05-19
发明人： Shi-Jun Yang , Gary Dandreaux , Robert J. Sheerin
IPC分类号： C08K5/20
CPC分类号： C08K5/20
摘要： The present invention relates to storage stable film forming latex particles substantially free of adipic acid dihydrazide (ADH) that crosslink under ambient conditions during or after drying. Monomers for the formation of the crosslinkable moieties in the latex particles include diacetone acrylamide (DAAM) or the likes and methacrylamide (MAM) or the likes with or without styrene. A paint composition comprising the storage stable latex particles was described.
摘要翻译： 本发明涉及基本上不含在干燥期间或之后在环境条件下交联的己二酸二酰肼（ADH）的保存稳定的成膜胶乳颗粒。 用于在胶乳颗粒中形成可交联部分的单体包括双丙酮丙烯酰胺（DAAM）或类似物和甲基丙烯酰胺（MAM）或类似物，或不含苯乙烯。 描述了包含储存稳定的胶乳颗粒的涂料组合物。
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公开(公告)号：US20140228514A1
公开(公告)日：2014-08-14
申请号：US14343292
申请日：2012-09-18
申请人： Shi-Jun Yang , Gary Dandreaux , Robert J. Sheerin , Columbia Insurance Company , Benjamin Moore & Co.
发明人： Shi-Jun Yang , Gary Dandreaux , Robert J. Sheerin
IPC分类号： C08K3/20
CPC分类号： C08K3/20 , C08B11/08 , C08B11/20 , C08F6/006 , C08F8/10 , C08F251/02 , C08L1/08 , C08L1/284 , C09D151/02 , C08F220/18 , C08F212/08 , C08F220/06 , C08F220/56 , C08L51/02
摘要： The present invention relates to latex compositions comprising hydroxyethyl cellulose grafted acrylic polymer emulsions and methods for preparing same without gelling or coagulation. The latex composition comprises at least about 0.2% of HEC by weight relative to the monomer weight, contains at least about 45% solid, and the average mean volume (mV) latex particle size is in the range of about 320-about 850 nm. Paint compositions incorporating the HEC grafted acrylic latex show high viscosity at static conditions and have no color flow and no syneresis compared paints containing a latex without HEC grafting. The present invention also relates to a cross-linking mechanism that cross-links latex particles at ambient conditions. This cross-linking mechanism comprises diacetone acrylamide (DAAM) and methacrylamide (MAM) with or without styrene.
摘要翻译： 本发明涉及包含羟乙基纤维素接枝的丙烯酸聚合物乳液的胶乳组合物及其制备方法而不凝胶化或凝结。 胶乳组合物包含相对于单体重量的至少约0.2重量％的HEC，含有至少约45％的固体，并且平均体积（mV）胶乳粒度在约320-约850nm的范围内。 掺入HEC接枝丙烯酸胶乳的涂料组合物在静态条件下显示出高粘度，并且没有颜色流动，没有脱水收缩比较含有没有HEC接枝的胶乳的涂料。 本发明还涉及在环境条件下交联胶乳颗粒的交联机理。 该交联机理包括具有或不具有苯乙烯的双丙酮丙烯酰胺（DAAM）和甲基丙烯酰胺（MAM）。
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公开(公告)号：US20230279168A1
公开(公告)日：2023-09-07
申请号：US18016960
申请日：2021-08-10
发明人： Richard Geurtsen , Yong Yang , Gary Dandreaux , Cristian Grigoras
IPC分类号： C08F220/14 , C09D133/14
CPC分类号： C08F220/14 , C09D133/14
摘要： Disclosed herein is a frambinone methacrylate (FMA) or raspberry ketone methacrylate (RKMA) monomer having the following structure:
and
a zingerone methacrylate (ZMA) having the following structure
Also disclosed are homopolymers and co-polymers utilizing same monomer. Also disclosed is a class of methacrylate monomers comprising a bio-based moiety and a reactive ketone moiety. Also disclosed are paint compositions made with a copolymer including FMA and/or ZMA.
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