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公开(公告)号：US5215737A
公开(公告)日：1993-06-01
申请号：US842684
申请日：1992-02-27
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/16 , B01J29/041 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： There is provided a method for synthesizing a new synthetic composition of ultra-large pore crystalline material which can be used as a sorbent or catalyst component for conversion of organic and inorganic compounds. The crystalline material product of this method exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C. This material may have a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of a least about 13 Angstrom units. The reaction mixture for preparing this material contains silica-alumina hydrogel.
摘要翻译： 提供了一种用于合成可用作有机和无机化合物转化的吸附剂或催化剂组分的超大孔结晶材料的新合成组合物的方法。 该方法的结晶材料产品表现出异常大的吸附能力，其在50托和25℃下苯吸附能力大于约15克苯/ 100克。该材料可具有六角形电子衍射图，其可以用 大于约18埃单位的d100值和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。 用于制备该材料的反应混合物含有二氧化硅 - 氧化铝水凝胶。
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公开(公告)号：US5250277A
公开(公告)日：1993-10-05
申请号：US811360
申请日：1991-12-20
CPC分类号： B01J29/049 , B01J29/70 , C01B39/026 , B01J2229/42
摘要： There is provided a crystalline oxide material with a characteristic X-ray diffraction pattern. This material may be a layered material, which is swollen or pillared. Upon calcination of the swollen material, the layers collapse and condense upon one another in a somewhat disordered fashion to form a non-swellable material. However, the swollen layered material may be intercalated with polymeric oxide pillars to maintain layer separation, even after calcination.
摘要翻译： 提供具有特征X射线衍射图案的结晶氧化物材料。 该材料可以是分层的材料，其被肿胀或支撑。 在煅烧膨胀的材料时，层以相当混乱的方式相互折叠并相互凝结形成不溶胀的材料。 然而，即使在煅烧之后，溶胀的层状材料也可以插入聚合氧化物柱以保持层分离。
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公开(公告)号：US5229341A
公开(公告)日：1993-07-20
申请号：US811384
申请日：1991-12-20
CPC分类号： B01J29/049 , C01B39/026
摘要： There is provided a pillared, layered crystalline oxide material and a method for making this material. This material may be prepared by intercepting a swellable layered oxide before calcination. The intercepted material is swollen and pillared. If the material is not intercepted in this manner, it is transformed into a zeolite by calcination. The pillared material may have a large degree of catalytic activity, and it may have rather porous layers.
摘要翻译： 提供了柱状的层状结晶氧化物材料和制造该材料的方法。 该材料可以通过在煅烧之前截取可溶胀的层状氧化物来制备。 被拦截的材料肿胀和支柱。 如果不以这种方式截留材料，则通过煅烧将其转变成沸石。 柱状材料可能具有大的催化活性，并且它可能具有相当多孔的层。
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4.发明授权Organic conversion with a catalyst comprising a crystalline pillared oxide material 失效用包含结晶柱状氧化物材料的催化剂进行有机转化
公开(公告)号：US5364999A
公开(公告)日：1994-11-15
申请号：US28440
申请日：1993-03-09
IPC分类号： B01J20/18 , B01J29/04 , C01B33/44 , C01B39/02 , C07C1/24 , C07C2/12 , C07C2/00 , C07C4/00 , C07C5/00
CPC分类号： B01J29/049 , C01B39/026
摘要： There is provided a process for converting organic compounds using a catalyst comprising a pillared, layered crystalline oxide material. This material may be prepared by intercepting a swellable layered oxide before calcination. The intercepted material is swollen and pillared. If the material is not intercepted in this manner, it is transformed into a zeolite by calcination. The pillared material may have a large degree of catalytic activity, and it may have rather porous layers.
摘要翻译： 提供了使用包含柱状层状结晶氧化物材料的催化剂转化有机化合物的方法。 该材料可以通过在煅烧之前截取可溶胀的层状氧化物来制备。 被拦截的材料肿胀和支柱。 如果不以这种方式截留材料，则通过煅烧将其转变成沸石。 柱状材料可能具有大的催化活性，并且它可能具有相当多孔的层。
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5.发明授权Pillaring layered silicates with a mixture of swelling agent and pillar precursor 失效用溶胀剂和柱前体的混合物填充层状硅酸盐
公开(公告)号：US5068216A
公开(公告)日：1991-11-26
申请号：US686844
申请日：1991-04-17
申请人： Ivy D. Johnson , Kenneth G. Simmons
发明人： Ivy D. Johnson , Kenneth G. Simmons
CPC分类号： B01J29/049
摘要： There is provided a method for pillaring a layered silicate, such as kenyaite, with polymeric oxide by using a single step treatment with a mixture of swelling agent and pillar precursor. The swelling agent may be an organic cation, such as a cetyltrimethylammonium cation, and the pillar precursor may be a compound which is capable of hydrolyzing to form a polymeric oxide. Tetraethylorthosilicate is an example of such a pillar precursor.
摘要翻译： 提供了一种通过使用溶胀剂和柱前体的混合物进行单步处理来将层状硅酸盐如肯尼特与聚合物氧化物一起支撑的方法。 溶胀剂可以是有机阳离子，例如十六烷基三甲基铵阳离子，并且柱前体可以是能够水解形成聚合物氧化物的化合物。 原硅酸四乙酯是这种柱状前体的一个例子。
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