公开(公告)号：US11028225B2

公开(公告)日：2021-06-08

申请号：US16615481

申请日：2018-07-19

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Keizo Inoue

IPC: C08G65/26 ,  C09D11/101 ,  C09D11/30

Abstract: Provided is a monomer mixture that is rapidly cured to form a cured product having high hardness, excellent alkali resistance, and excellent adhesion to a substrate. The monomer mixture of the present invention is a monomer mixture containing at least: a compound represented by Formulas (a-1) and/or (a-2); a compound (2B) including two cationically polymerizable groups per molecule, at least one of the cationically polymerizable groups being an epoxy group; a compound (3B) including three or more cationically polymerizable groups per molecule, at least one of the cationically polymerizable groups being an epoxy group; and a compound represented by Formula (c-1).

公开(公告)号：US11339245B2

公开(公告)日：2022-05-24

申请号：US16611296

申请日：2018-07-19

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Keizo Inoue

IPC: C08G59/22 ,  B33Y10/00 ,  B33Y70/00 ,  B29C64/112 ,  C08G59/24 ,  C08J5/00 ,  C09D4/00 ,  C09D11/101 ,  C09D11/322 ,  C09J4/00 ,  C08F216/14 ,  C08G65/18 ,  C08L63/00 ,  C08L71/00 ,  C08L29/10 ,  B33Y80/00 ,  B29K105/00

Abstract: The present invention is to provide a monomer mixture that is cured rapidly even in the presence of oxygen and that forms a cured product having high hardness and excellent adhesion to metals and/or glass. The monomer mixture according to an embodiment of the present invention contains two or more types of cationically polymerizable monomers. As the cationically polymerizable monomers, the monomer mixture contains at least 10 wt. %, based on a total amount of the monomer mixture, of a compound having at least one cationically polymerizable group selected from the group consisting of a vinyl ether group, an epoxy group, and an oxetanyl group, and at least one hydroxy group in a molecule, and at least 5 wt. %, based on the total amount of the monomer mixture, of a compound represented by Formula (b). In the formula, R represents an s-valent straight-chain or branched saturated aliphatic hydrocarbon group or an s-valent group having two or more straight-chain or branched saturated aliphatic hydrocarbon groups bonded to each other through an ether bond, and s represents an integer of 2 or greater.

公开(公告)号：US11028224B2

公开(公告)日：2021-06-08

申请号：US16622222

申请日：2019-01-25

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Keizo Inoue

IPC: C08G65/18 ,  C08F16/32 ,  C09D11/322 ,  C09J171/02 ,  C08G59/24

Abstract: The present invention provides a monomer mixture that rapidly cures even in high humidity environments, and is useful as a raw material for a curable composition that forms a cured product having excellent adhesion to metals and glass, as well as of course to paper and plastic.
The monomer mixture according to an embodiment of the present invention contains two or more types of cationically polymerizable monomers. The monomer mixture contains, as the cationically polymerizable monomers, a compound (A) having a vinyl ether group and a hydroxyl group; a compound (B) having an oxetanyl group and a hydroxyl group; and a compound (C) represented by Formula (c) below. A total content of the compound (A), the compound (B), and the compound (C) is 50 wt. % or greater of the total amount of the monomer mixture, and a content [A] of the compound (A) and a content [B] of the compound (B) satisfy Relationship (1) below. A/(A+B)≥0.3  (1)

公开(公告)号：US10472466B2

公开(公告)日：2019-11-12

申请号：US15321432

申请日：2015-06-23

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Keizo Inoue

IPC: C08G65/18 ,  B41J2/01 ,  B41M5/00 ,  C08G59/24 ,  C09D11/30 ,  C08G59/68 ,  C09D11/101 ,  C09D11/102 ,  C09D4/00 ,  C09D11/32

Abstract: Provided is a monomer composition that has rapid curability and can be cured rapidly, even in the presence of oxygen and/or water, to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition according to the present invention contains a vinyl ether compound (A). The vinyl ether compound (A) includes a vinyl ether compound (a) having a cyclic ether skeleton. The monomer composition further contains at least one compound selected from the group consisting of a vinyl ether compound (a′) having a chain hydrocarbon skeleton, a divinyl ether compound (a″-1) having a cyclic hydrocarbon skeleton, an oxetane compound (B), and an epoxy compound (C).

公开(公告)号：US10882953B2

公开(公告)日：2021-01-05

申请号：US16213626

申请日：2018-12-07

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Keizo Inoue

IPC: C08G65/18 ,  B41J2/01 ,  B41M5/00 ,  C08G59/24 ,  C08G59/68 ,  C09D4/00 ,  C09D11/32 ,  C08G65/10 ,  C09D11/30 ,  C09D11/101 ,  C09D11/102

Abstract: Provided is a monomer composition that has rapid curability and can be cured rapidly, even in the presence of oxygen and/or water, to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition according to the present invention contains a vinyl ether compound (A). The vinyl ether compound (A) includes a vinyl ether compound (a) having a cyclic ether skeleton. The monomer composition further contains at least one compound selected from the group consisting of a vinyl ether compound (a′) having a chain hydrocarbon skeleton, a divinyl ether compound (a″-1) having a cyclic hydrocarbon skeleton, an oxetane compound (B), and an epoxy compound (C).

公开(公告)号：US10118322B2

公开(公告)日：2018-11-06

申请号：US14764095

申请日：2014-01-27

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Takuya Osaka ,  Katsuhiro Nakaguchi ,  Arimichi Okumura ,  Hiroto Miyake ,  Masaya Omura ,  Naotaka Nishio

IPC: B29C43/36 ,  B29C33/00 ,  B81C99/00 ,  B29C43/02 ,  B29C59/02 ,  C08L83/04 ,  G03F7/00 ,  B29C33/40 ,  B29L31/00 ,  B29C33/42

Abstract: Provided is a sheet-shaped mold possessing a high strength and having a low breakage rate in demolding even in a case where the mold is thin and has a large-area. The sheet-shaped mold is prepared by combining a cured silicone rubber containing a polyorganosiloxane and a fiber for reinforcing the cured silicone rubber. The fiber may comprise a cellulose nanofiber. The sheet-shaped mold may have an uneven pattern on at least one surface (or side) thereof. The fiber may be surface-treated with a hydrophobizing agent. The fiber may forma nonwoven fabric, and the nonwoven fabric may be impregnated with the cured silicone rubber. The cured silicone rubber may comprise a two-component curable silicone rubber having a polydimethylsiloxane unit. The sheet-shaped mold may be a mold for nanoimprint lithography using a photo-curable resin.

公开(公告)号：US10703951B2

公开(公告)日：2020-07-07

申请号：US15737685

申请日：2016-06-13

Applicant: Daicel Corporation

Inventor： Masao Iwaya ,  Tomoya Mizuta ,  Naotaka Nishio ,  Yutaka Isobe ,  Masatake Kudoh ,  Masanori Yoshikane

IPC: C09K5/14 ,  C09K5/06 ,  F28D20/02

Abstract: Disclosed is a heat transport medium to be transported with a fluid that is liquid in an operating temperature range containing a porous material and a latent heat storage material penetrated in the pores of the porous material, wherein the latent heat storage material is incompatible with the fluid and has a melting point within the operating temperature range, and the porous material has a liquid repellency to the fluid, an affinity for the latent heat storage material, and a sponge hardness of not more than 50. This invention achieves stable heat transport with a high heat conversion efficiency even by circulating the medium through a pipeline over a long period of time. The porous material has an apparent density of about 0.05 to 0.5 g/cm3.

公开(公告)号：US10392473B2

公开(公告)日：2019-08-27

申请号：US15321271

申请日：2015-06-23

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Keizo Inoue

IPC: C08G65/26 ,  C08F16/14 ,  C08F216/14 ,  C09D11/101 ,  C09D11/30 ,  C09D4/00

Abstract: Provided is a monomer composition that has rapid curability and can be rapidly cured even in the presence of oxygen and/or water to form a cured product having excellent adhesion to a wide variety of substrates. The monomer composition contains a multifunctional vinyl ether compound in an amount of 10 to 80 weight percent, a bifunctional oxetane compound represented by Formula (b) in an amount of 0.5 to 20 weight percent, and a monofunctional oxetane compound represented by Formula (b′) in an amount of 5 to 80 weight percent. In the formulae, Ring Z is selected from an aromatic hydrocarbon ring and a structure including two or more aromatic hydrocarbon rings bonded to each other through a single bond or a linkage group; R represents a monovalent aliphatic hydrocarbon group; R′ is selected from hydrogen and ethyl; and m represents an integer of 0 or more.

公开(公告)号：US20150086907A1

公开(公告)日：2015-03-26

申请号：US14394839

申请日：2013-04-02

Applicant: DAICEL CORPORATION

Inventor： Tomoya Mizuta ,  Hiroto Miyake

IPC: G03H1/02

CPC classification number: G03H1/0248 ,  G03H1/02 ,  G03H2001/0264 ,  G03H2001/186 ,  G03H2260/12 ,  G11B7/24044 ,  G11B7/244 ,  G11B7/245 ,  G11B7/246

Abstract: Provided is a photosensitive composition for volume hologram recording capable of forming a volume hologram recording medium that less shrinks upon curing in hologram recording (in hologram formation) and resists cracking. The photosensitive composition for volume hologram recording contains an alicyclic epoxy compound (A) represented by Formula (I); a thermal acid generator (B); a radically polymerizable compound (C); a radical polymerization initiator (D); and at least one epoxy compound (E) selected from the group consisting of compounds represented by Formula (1), epoxidized fatty acid esters, and epoxidized conjugated diene polymers.

Abstract translation: 提供一种用于体积全息记录的感光组合物，其能够形成在全息记录（全息图形成）中固化时收缩较小并且抗龟裂的体积全息图记录介质。 用于体积全息图记录的光敏组合物含有由式（I）表示的脂环族环氧化合物（A）; 热酸发生器（B）; 自由基聚合性化合物（C）; 自由基聚合引发剂（D）; 和选自由式（1）表示的化合物，环氧化脂肪酸酯和环氧化共轭二烯聚合物组成的组中的至少一种环氧化合物（E）。