Laminate and copolymer
    1.
    发明授权

    公开(公告)号:US11110693B2

    公开(公告)日:2021-09-07

    申请号:US16325465

    申请日:2017-07-21

    Abstract: The invention provides a laminate in which a fluororesin layer and a rubber layer are firmly bonded to each other and the fluororesin layer has low fuel permeability and is less likely to suffer solvent cracking. The laminate includes a rubber layer (A) and a fluororesin layer (B). The fluororesin layer (B) contains a copolymer containing a chlorotrifluoroethylene unit, a tetrafluoroethylene unit, and a perfluoroalkyl vinyl ether unit. The copolymer contains 96.0 to 97.4 mol % of the chlorotrifluoroethylene unit and the tetrafluoroethylene unit relative to all the monomer units constituting the copolymer and 2.6 to 4.0 mol % of the perfluoroalkyl vinyl ether unit relative to all the monomer units constituting the copolymer.

    LAMINATE BODY AND METHOD FOR PRODUCING LAMINATE BODY
    3.
    发明申请
    LAMINATE BODY AND METHOD FOR PRODUCING LAMINATE BODY 审中-公开
    层压体和生产层压体的方法

    公开(公告)号:US20140227533A1

    公开(公告)日:2014-08-14

    申请号:US14346429

    申请日:2012-09-21

    Abstract: The present invention aims to provide a laminate in which a metal and a fluoropolymer are directly and firmly attached to each other. The present invention relates to a laminate including a layer (A) including a metal, and a layer (B) formed on the layer (A), wherein the layer (B) includes a copolymer containing a polymer unit based on tetrafluoroethylene and a polymer unit based on a perfluoro(alkyl vinyl ether), the copolymer contains a carboxyl group at a terminus of a main chain and has a melt flow rate of not lower than 20 g/10 min and a melting point of not higher than 295° C., and the metal is at least one selected from the group consisting of copper, stainless steel, aluminum, iron, and an alloy thereof.

    Abstract translation: 本发明旨在提供一种其中金属和含氟聚合物彼此直接且牢固地连接的层压体。 本发明涉及一种包含金属层(A)和层(A)上形成的层(B)的层压体,其中层(B)包括含有基于四氟乙烯的聚合物单元和聚合物 基于全氟(烷基乙烯基醚)的单元,共聚物在主链的末端含有羧基,熔体流动速率不低于20g / 10min,熔点不高于295℃ 金属为选自铜,不锈钢,铝,铁及其合金中的至少一种。

    Flexible pipe
    4.
    发明授权

    公开(公告)号:US09989173B2

    公开(公告)日:2018-06-05

    申请号:US15518145

    申请日:2015-10-06

    Abstract: The present invention provides a flexible pipe having excellent blister resistance in a high-temperature and high-pressure environment even though including a thick resin pipe. The flexible pipe includes a resin pipe having a thickness of greater than 5 mm. The resin pipe is formed from a resin having a CO2 permeability coefficient P(CO2) of 20×10−9 cm3·cm/cm2·s·cmHg or lower at 150° C., a CH4 permeability coefficient P(CH4) of 10×10−9 cm3·cm/cm2·s·cmHg or lower at 150° C., a ratio D(CO2)/S(CO2) between a CO2 diffusion coefficient D(CO2) and a CO2 solubility coefficient S(CO2) of 3×10−5 Pa·m2/s or higher at 150° C., and a ratio D(CH4)/S(CH4) between a CH4 diffusion coefficient D(CH4) and a CH4 solubility coefficient S(CH4) of higher than 15×10−5 Pa·m2/s at 150° C.

    Flexible pipe
    5.
    发明授权

    公开(公告)号:US09920863B2

    公开(公告)日:2018-03-20

    申请号:US15518145

    申请日:2015-10-06

    Abstract: The present invention provides a flexible pipe having excellent blister resistance in a high-temperature and high-pressure environment even though including a thick resin pipe. The flexible pipe includes a resin pipe having a thickness of greater than 5 mm. The resin pipe is formed from a resin having a CO2 permeability coefficient P(CO2) of 20×10−9 cm3·cm/cm2·s·cmHg or lower at 150° C., a CH4 permeability coefficient P(CH4) of 10×10−9 cm3·cm/cm2·s·cmHg or lower at 150° C., a ratio D(CO2)/S(CO2) between a CO2 diffusion coefficient D(CO2) and a CO2 solubility coefficient S(CO2) of 3×10−5 Pa·m2/s or higher at 150° C., and a ratio D(CH4)/S(CH4) between a CH4 diffusion coefficient D(CH4) and a CH4 solubility coefficient S(CH4) of higher than 15×10−5 Pa·m2/s at 150° C.

    LAMINATE
    6.
    发明申请
    LAMINATE 审中-公开
    层压板

    公开(公告)号:US20140248496A1

    公开(公告)日:2014-09-04

    申请号:US14349859

    申请日:2012-10-05

    Abstract: A laminate including: a rubber layer (A); and a fluororesin layer (B) laminated on the rubber layer (A), the rubber layer (A) being formed of a rubber composition for vulcanization containing: at least one unvulcanized rubber (a1) selected from acrylonitrile-butadiene rubber and its hydride, styrene-butadiene rubber, chloroprene rubber, butadiene rubber, natural rubber, isoprene rubber, ethylene-propylene-termonomer-copolymer rubber, silicone rubber, butyl rubber, and acrylic rubber; at least one compound (a2) selected from 1,8-diazabicyclo(5.4.0)undec-7-ene salts, 1,5-diazabicyclo(4.3.0)-non-5-ene salts, 1,8-diazabicyclo(5.4.0)undec-7-ene, and 1,5-diazabicyclo(4.3.0)-non-5-ene; at least one compound (a3) selected from dithiocarbamic acid copper salts, aldehyde-amine compounds, and metal hydrates; magnesium oxide (a4); and silica (a5), the fluororesin layer (B) being formed of a fluoropolymer composition containing a fluoropolymer (b1) having a copolymer unit derived from chlorotrifluoroethylene.

    Abstract translation: 一种层压体,包括:橡胶层(A); 和层压在橡胶层(A)上的氟树脂层(B),橡胶层(A)由用于硫化的橡胶组合物形成,包含:至少一种选自丙烯腈 - 丁二烯橡胶及其氢化物的未硫化橡胶(a1) 苯乙烯 - 丁二烯橡胶,氯丁二烯橡胶,丁二烯橡胶,天然橡胶,异戊二烯橡胶,乙烯 - 丙烯 - 共聚物橡胶,硅橡胶,丁基橡胶和丙烯酸橡胶; 至少一种选自1,8-二氮杂双环(5.4.0)十一碳-7-烯盐,1,5-二氮杂双环(4.3.0) - 壬-5-烯盐,1,8-二氮杂双环( 5.4.0)十一碳-7-烯和1,5-二氮杂双环(4.3.0) - 壬-5-烯; 至少一种选自二硫代氨基甲酸铜盐,醛 - 胺化合物和金属水合物的化合物(a3) 氧化镁(a4); 和二氧化硅(a5),氟树脂层(B)由含有来自三氟氯乙烯的共聚物单元的含氟聚合物(b1)的含氟聚合物组合物形成。

    Laminate
    9.
    发明授权
    Laminate 有权

    公开(公告)号:US11155064B2

    公开(公告)日:2021-10-26

    申请号:US16136701

    申请日:2018-09-20

    Abstract: A laminate including: a rubber layer (A); and a fluororesin layer (B) laminated on the rubber layer (A), the rubber layer (A) being formed of a rubber composition for vulcanization containing: at least one unvulcanized rubber (a1) selected from acrylonitrile-butadiene rubber and its hydride, styrene-butadiene rubber, chloroprene rubber, butadiene rubber, natural rubber, isoprene rubber, ethylene-propylene-termonomer-copolymer rubber, silicone rubber, butyl rubber, and acrylic rubber; at least one compound (a2) selected from 1,8-diazabicyclo(5.4.0)undec-7-ene salts, 1,5-diazabicyclo(4.3.0)-non-5-ene salts, 1,8-diazabicyclo(5.4.0)undec-7-ene, and 1,5-diazabicyclo(4.3.0)-non-5-ene; at least one compound (a3) selected from aldehyde-amine compounds and metal hydrates; magnesium oxide (a4); and silica (a5), the fluororesin layer (B) being formed of a fluoropolymer composition containing a fluoropolymer (b1) having a copolymer unit derived from chlorotrifluoroethylene.

    Laminate
    10.
    发明授权
    Laminate 有权

    公开(公告)号:US10252496B2

    公开(公告)日:2019-04-09

    申请号:US14349859

    申请日:2012-10-05

    Abstract: A laminate including: a rubber layer (A); and a fluororesin layer (B) laminated on the rubber layer (A), the rubber layer (A) being formed of a rubber composition for vulcanization containing: at least one unvulcanized rubber (a1) selected from acrylonitrile-butadiene rubber and its hydride, styrene-butadiene rubber, chloroprene rubber, butadiene rubber, natural rubber, isoprene rubber, ethylene-propylene-termonomer-copolymer rubber, silicone rubber, butyl rubber, and acrylic rubber; at least one compound (a2) selected from 1,8-diazabicyclo(5.4.0)undec-7-ene salts, 1,5-diazabicyclo(4.3.0)-non-5-ene salts, 1,8-diazabicyclo(5.4.0)undec-7-ene, and 1,5-diazabicyclo(4.3.0)-non-5-ene; at least one compound (a3) selected from dithiocarbamic acid copper salts, aldehyde-amine compounds, and metal hydrates; magnesium oxide (a4); and silica (a5), the fluororesin layer (B) being formed of a fluoropolymer composition containing a fluoropolymer (b1) having a copolymer unit derived from chlorotrifluoroethylene.

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