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公开(公告)号：US20150191869A1
公开(公告)日：2015-07-09
申请号：US14412733
申请日：2013-07-04
发明人： Ryousuke Hara , Rumi Kawabe , Ikuo Yamamoto , Yuji Gama , Nobuyuki Takahata , Yasuhiro Mitta
IPC分类号： D06M15/248 , C09D133/16 , D06M15/277 , C08L33/16
CPC分类号： D06M15/248 , C08F2/32 , C08F14/00 , C08F14/18 , C08F259/00 , C08L33/16 , C08L2201/02 , C09D133/16 , D06M13/217 , D06M13/2243 , D06M15/256 , D06M15/277 , Y10T442/2172
摘要： Provided is a water and oil repellent composition that provides water and oil repellency that is excellent for base materials such as textile products, and is excellent for preventing adhesion of polymers on rolls during processing. The present invention involves a method for manufacturing a fluorine-containing polymer comprising a first polymer formed from a first monomer, and a second polymer formed from a second monomer. The manufacturing method includes: (I) a step for obtaining the first polymer by polymerizing the first monomer; and (II) a step for obtaining the second polymer by preparing and polymerizing the second monomer in the presence of the first polymer. The first monomer and/or the second monomer includes a fluorine-containing monomer (a), and both the first monomer and the second monomer include a halogenated olefin (b).
摘要翻译： 本发明提供一种防水斥油剂组合物，其具有防水性和拒油性，对于纺织品等基材优异，并且在加工过程中防止聚合物在辊上的粘附性优异。 本发明涉及含有由第一单体形成的第一聚合物和由第二单体形成的第二聚合物的含氟聚合物的制造方法。 制造方法包括：（I）通过聚合第一单体获得第一聚合物的步骤; 和（II）通过在第一聚合物的存在下制备和聚合第二单体获得第二聚合物的步骤。 第一单体和/或第二单体包括含氟单体（a），第一单体和第二单体都包括卤代烯烃（b）。
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公开(公告)号：US09416486B2
公开(公告)日：2016-08-16
申请号：US14412733
申请日：2013-07-04
发明人： Ryousuke Hara , Rumi Kawabe , Ikuo Yamamoto , Yuji Gama , Nobuyuki Takahata , Yasuhiro Mitta
IPC分类号： D06M15/248 , C08F14/00 , C08F14/18 , C08F259/00 , D06M15/256 , D06M15/277 , C08L33/16 , C09D133/16 , C08F2/32
CPC分类号： D06M15/248 , C08F2/32 , C08F14/00 , C08F14/18 , C08F259/00 , C08L33/16 , C08L2201/02 , C09D133/16 , D06M13/217 , D06M13/2243 , D06M15/256 , D06M15/277 , Y10T442/2172
摘要： Provided is a water and oil repellent composition that provides water and oil repellency that is excellent for base materials such as textile products, and is excellent for preventing adhesion of polymers on rolls during processing. The present invention involves a method for manufacturing a fluorine-containing polymer comprising a first polymer formed from a first monomer, and a second polymer formed from a second monomer. The manufacturing method includes: (I) a step for obtaining the first polymer by polymerizing the first monomer; and (II) a step for obtaining the second polymer by preparing and polymerizing the second monomer in the presence of the first polymer. The first monomer and/or the second monomer includes a fluorine-containing monomer (a), and both the first monomer and the second monomer include a halogenated olefin (b).
摘要翻译： 本发明提供一种防水斥油剂组合物，其具有防水性和拒油性，对于纺织品等基材优异，并且防止聚合物在加工过程中在辊上粘附。 本发明涉及含有由第一单体形成的第一聚合物和由第二单体形成的第二聚合物的含氟聚合物的制造方法。 制造方法包括：（I）通过聚合第一单体获得第一聚合物的步骤; 和（II）通过在第一聚合物的存在下制备和聚合第二单体获得第二聚合物的步骤。 第一单体和/或第二单体包括含氟单体（a），第一单体和第二单体都包括卤代烯烃（b）。
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公开(公告)号：US09932504B2
公开(公告)日：2018-04-03
申请号：US14387047
申请日：2013-03-19
发明人： Rumi Kawabe , Ryousuke Hara , Masahiro Miyahara , Masaki Fukumori , Kouji Kubota , Kensuke Mohara , Takashi Enomoto
IPC分类号： D06M15/277 , D06M13/325 , D06M13/402 , D06M15/53 , B01F17/00 , C08K5/20 , C08K5/06 , C08K5/101 , C08L33/16 , C08L71/02 , C09D133/16 , C09D5/16 , C09K3/18 , C08G65/26
CPC分类号： C09K3/18 , B01F17/0028 , B01F17/0035 , B01F17/0042 , B01F17/0085 , C08G65/2609 , C08K5/06 , C08K5/101 , C08K5/20 , C08L33/16 , C08L71/02 , C08L2201/54 , C09D5/16 , C09D133/16 , D06M13/325 , D06M13/402 , D06M15/277 , D06M15/53 , D06M2200/01 , D06M2200/11 , D06M2200/12
摘要： Provided is an aqueous emulsion composition which has excellent chemical stability (stability with respect to impurities) and excellent mechanical stability. Disclosed is an aqueous emulsion composition which contains: (A) a polymer that contains a fluoroalkyl group; and (B) a surfactant that contains (B1) an amidoamine surfactant having an amide group and an amino group, and (B2) a nonionic surfactant. It is preferable that the surfactant does not contain a monool having an unsaturated triple bond or an alkylene oxide addition product of a polyol.
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公开(公告)号：US20150080510A1
公开(公告)日：2015-03-19
申请号：US14387047
申请日：2013-03-19
发明人： Rumi Kawabe , Ryousuke Hara , Masahiro Miyahara , Masaki Fukumori , Kouji Kubota , Kensuke Mohara , Takashi Enomoto
CPC分类号： C09K3/18 , B01F17/0028 , B01F17/0035 , B01F17/0042 , B01F17/0085 , C08G65/2609 , C08K5/06 , C08K5/101 , C08K5/20 , C08L33/16 , C08L71/02 , C08L2201/54 , C09D5/16 , C09D133/16 , D06M13/325 , D06M13/402 , D06M15/277 , D06M15/53 , D06M2200/01 , D06M2200/11 , D06M2200/12
摘要： Provided is an aqueous emulsion composition which has excellent chemical stability (stability with respect to impurities) and excellent mechanical stability. Disclosed is an aqueous emulsion composition which contains: (A) a polymer that contains a fluoroalkyl group; and (B) a surfactant that contains (B1) an amidoamine surfactant having an amide group and an amino group, and (B2) a nonionic surfactant. It is preferable that the surfactant does not contain a monool having an unsaturated triple bond or an alkylene oxide addition product of a polyol.
摘要翻译： 本发明提供了具有优异的化学稳定性（相对于杂质的稳定性）和优异的机械稳定性的水性乳液组合物。 公开了一种水性乳液组合物，其含有：（A）含有氟烷基的聚合物; 和（B）含有（B1）具有酰胺基和氨基的酰氨基胺表面活性剂和（B2）非离子表面活性剂的表面活性剂。 优选表面活性剂不含具有不饱和三键的一元醇或多元醇的烯化氧加成产物。
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公开(公告)号：US11970651B2
公开(公告)日：2024-04-30
申请号：US16997405
申请日：2020-08-19
发明人： Kanako Takahashi , Ryousuke Hara , Ikuo Yamamoto
IPC分类号： C09K3/18 , C08F214/06 , C08F214/08 , C08F214/16 , C08F214/18 , C08F220/18 , C08F220/20 , C08F220/28 , C08F220/34 , C08F220/56 , C08L83/04
CPC分类号： C09K3/18 , C08F214/06 , C08F214/08 , C08F214/16 , C08F214/182 , C08F220/1818 , C08F220/20 , C08F220/283 , C08F220/34 , C08F220/56 , C08L83/04
摘要： A surface treatment agent containing: (A) a water repellent oil repellent polymer having a repeating unit derived from at least one water repellent oil repellent monomer selected from (A1) fluorine-containing monomers and (A2) non-fluorine monomers having a hydrocarbon group with 7-40 carbon atoms; (B) a silicone polymer represented by formula R533Si—O—[—Si(R51)2—O—]a—[—Si(R51)(R52)—O—]b—SiR533 (wherein each R51 group independently represents hydrogen, alkyl having 1-20 carbon atoms, aryl having 6-20 carbon atoms or alkoxy having 1-4 carbon atoms; each R52 independently represents a saturated hydrocarbon group having 23-40 carbon atoms; each R53 independently represents a hydrogen atom, an alkyl group having 1-20 carbon atoms, an aryl group having 6-20 carbon atoms, an alkoxy group having 1-4 carbon atoms or a saturated hydrocarbon group having 23-40 carbon atoms; a represents an integer of 0 or more; b represents an integer of 1 or more; and (a+b) is 10-200); and (C) a liquid medium.
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公开(公告)号：US11746268B2
公开(公告)日：2023-09-05
申请号：US16473737
申请日：2017-12-20
发明人： Ryousuke Hara , Rumi Kawabe , Masahiro Miyahara , Ikuo Yamamoto
IPC分类号： C09K3/18 , C08F214/06 , C08F2/24 , C08K5/10 , C08F220/18 , C08L71/02 , C08L91/08
CPC分类号： C09K3/18 , C08F2/24 , C08F214/06 , C08F220/1818 , C08K5/10 , C08L71/02 , C08L91/08 , C08L2201/52 , C08L2203/12 , C08L2205/03
摘要： A water- and oil-repellent agent that is an aqueous dispersion containing (A) a fluorine-free polymer having repeating units derived from a fluorine-free (meth)acrylic acid ester monomer, (B) a wax, (C) an aqueous medium, and (D) an emulsifier. The fluorine-free (meth)acrylic acid ester monomer is a compound represented by the formula CH2═CA11-C(═O)—O-A12 where A11 is a hydrogen atom or a methyl group and A12 is a linear or branched C18-30 hydrocarbon group. The emulsifier includes a sorbitan ester and another emulsifier, and the emulsifier has a hydrophilic-lipophilic balance (HLB) of 7.5 to 13.5. Also disclosed is a method of producing the water- and oil-repellent agent and a method of producing a treated substrate by applying the water- and oil-repellent agent to a substrate.
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公开(公告)号：US20160237614A1
公开(公告)日：2016-08-18
申请号：US15031104
申请日：2014-10-22
发明人： Rumi Kawabe , Ryousuke Hara , Kyouhei Sawaki , Ikuo Yamamoto
IPC分类号： D06M15/277 , C09D133/16
CPC分类号： D06M15/277 , C08F220/18 , C08F220/22 , C08F220/24 , C09D133/16 , D06M15/248 , D06M15/263 , D06M2200/01 , D06M2200/11 , D06M2200/12 , C08F2220/1883 , C08F2220/1891 , C08F214/06 , C08F2220/1858 , C08F2220/1875
摘要： A fluorine-containing polymer including: (a) a repeat unit in which the α-position is an acrylate ester monomer substituted with a monovalent organic group or a halogen atom and which is derived from a fluorine-containing monomer having a fluoroalkyl group; (b) a repeat unit which is an alkyl acrylate having a C6-13 alkyl group and is derived from a non-fluorine monomer; and (c) a repeat unit derived from a non-fluorine (meth)acrylate monomer having a cyclic hydrocarbon group. Also disclosed is a surface treatment agent containing the fluorine-containing polymer, a method of treating a substrate with the surface treatment agent and a treated substrate.
摘要翻译： 一种含氟聚合物，包括：（a）重复单元，其中α-位是被一价有机基团或卤素原子取代的丙烯酸酯单体，并且衍生自具有氟代烷基的含氟单体; （b）具有C6-13烷基的丙烯酸烷基酯并由非氟单体衍生的重复单元; 和（c）来自具有环状烃基的非氟（甲基）丙烯酸酯单体的重复单元。 还公开了含有含氟聚合物的表面处理剂，用表面处理剂处理基材的方法和处理过的基材。
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