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    Polyamide supported metallocene catalysts
    1.
    发明授权
    Polyamide supported metallocene catalysts 失效
    聚酰胺负载金属茂催化剂

    公开(公告)号：US07309678B2

    公开(公告)日：2007-12-18

    申请号：US11094681

    申请日：2005-03-29

    申请人： David John Rauscher ,  William John Gauthier ,  Shady Nader Henry ,  Kai Hortmann

    发明人： David John Rauscher ,  William John Gauthier ,  Shady Nader Henry ,  Kai Hortmann

    IPC分类号： B01J31/16

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  Y02P20/52 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/16 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/18

    摘要： Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyamide support comprising spheroidical particles of a polyamide having an average diameter with the range of 5-60 microns, and a porosity permitting distribution of a portion of the co-catalyst within the pore volume of the polyamide particles while retaining a substantial portion on the surface of the particles. The polyamide support is characterized by relatively low surface area, specifically a surface area less than 20 square meters per gram. The metallocene component can take the form of a single metallocene or two or more co-supported metallocenes.

    摘要翻译： 支持的立体定向催化剂和用于衍生自烯属不饱和单体的聚合物链的立体定向扩散的方法，例如丙烯聚合以产生间同立构聚丙烯或全同立构聚丙烯。 载体催化剂包括立体特异性茂金属催化剂组分和包含烷基铝氧烷的助催化剂组分。 金属茂催化剂组分和助催化剂组分均负载在包含平均直径为5-60微米范围的聚酰胺的球形颗粒的颗粒聚酰胺载体上，并且允许一部分助催化剂分布的孔隙率 在聚酰胺颗粒的孔体积内，同时保留颗粒表面上的实质部分。 聚酰胺载体的特征在于相对较低的表面积，特别是小于20平方米/克的表面积。 金属茂组分可以采用单一茂金属或两种或多种共支撑金属茂的形式。

    Polyamide supported metallocene catalysts
    2.
    发明授权
    Polyamide supported metallocene catalysts 失效
    聚酰胺负载金属茂催化剂

    公开(公告)号：US06878787B2

    公开(公告)日：2005-04-12

    申请号：US10648716

    申请日：2003-08-26

    申请人： David John Rauscher ,  William John Gauthier ,  Shady Nader Henry ,  Kai Hortmann

    发明人： David John Rauscher ,  William John Gauthier ,  Shady Nader Henry ,  Kai Hortmann

    IPC分类号： C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  C08F4/42

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/06 ,  Y02P20/52 ,  Y10S526/904 ,  Y10S526/943 ,  C08F4/65916 ,  C08F2500/16 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/18

    摘要： Supported stereospecific catalysts and processes for the stereotactic propagation of a polymer chain derived from ethylenically unsaturated monomers such as the polymerization of propylene to produce syndiotactic polypropylene or isotactic polypropylene. The supported catalyst comprises a stereospecific metallocene catalyst component and a co-catalyst component comprising an alkylalumoxane. Both the metallocene catalyst component and the co-catalyst component are supported on a particulate polyamide support comprising spheroidical particles of a polyamide having an average diameter with the range of 5-60 microns, and a porosity permitting distribution of a portion of the co-catalyst within the pore volume of the polyamide particles while retaining a substantial portion on the surface of the particles. The polyamide support is characterized by relatively low surface area, specifically a surface area less than 20 square meters per gram. The metallocene component can take the form of a single metallocene or two or more co-supported metallocenes.

    摘要翻译： 支持的立体定向催化剂和用于衍生自烯属不饱和单体的聚合物链的立体定向扩散的方法，例如丙烯聚合以产生间同立构聚丙烯或全同立构聚丙烯。 载体催化剂包括立体特异性茂金属催化剂组分和包含烷基铝氧烷的助催化剂组分。 金属茂催化剂组分和助催化剂组分均负载在包含平均直径为5-60微米范围的聚酰胺的球形颗粒的颗粒聚酰胺载体上，并且允许一部分助催化剂分布的孔隙率 在聚酰胺颗粒的孔体积内，同时保留颗粒表面上的实质部分。 聚酰胺载体的特征在于相对较低的表面积，特别是小于20平方米/克的表面积。 金属茂组分可以采用单一茂金属或两种或多种共支撑金属茂的形式。

    Process for Reducing Carbon Monoxide in Olefin-Containing Hydrocarbon Feedstocks
    6.
    发明申请
    Process for Reducing Carbon Monoxide in Olefin-Containing Hydrocarbon Feedstocks 审中-公开
    含烯烃含烃原料中一氧化碳还原方法

    公开(公告)号：US20100234662A1

    公开(公告)日：2010-09-16

    申请号：US12664889

    申请日：2008-06-20

    申请人： Kai Hortmann

    发明人： Kai Hortmann

    IPC分类号： C07C7/12

    CPC分类号： B01D53/02 ,  B01D2253/112 ,  B01D2256/24 ,  B01D2257/502 ,  B01J20/06 ,  B01J20/28061 ,  B01J20/3204 ,  B01J20/3236 ,  C07C7/12 ,  C07C11/02

    摘要： A process for removing carbon monoxide from an olefin-containing hydrocarbon feedstock comprising the steps of: a) passing the said hydrocarbon feedstock over a material comprising nickel deposited on a support material wherein said nickel is present as both nickel oxide and metallic nickel; and b) recovering a hydrocarbon stream having a substantially reduced carbon monoxide content.

    摘要翻译： 一种用于从含烯烃的烃原料中除去一氧化碳的方法，包括以下步骤：a）使所述烃原料通过沉积在载体材料上的包含镍的材料，其中所述镍以氧化镍和金属镍的形式存在; 和b）回收具有显着降低的一氧化碳含量的烃流。