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    Compressed metal oxide product
    4.
    发明授权
    Compressed metal oxide product 有权
    压缩金属氧化物产品

    公开(公告)号：US06228802B1

    公开(公告)日：2001-05-08

    申请号：US09379529

    申请日：1999-08-24

    Applicant: Delbert C. Scranton, Jr. ,  Alvin Samuels

    Inventor： Delbert C. Scranton, Jr. ,  Alvin Samuels

    IPC: B01J2024

    CPC classification number: B01J20/28014 ,  B01J20/06 ,  B01J20/24 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/30 ,  B01J2220/4825

    Abstract: The present invention relates to a bound metal oxide particle comprised of metal oxide and a binder, with the binder preferably being a starch solution. The present invention also relates to a method for forming a bound metal oxide particle, with the preferred method including extruding and pelletizing a metal oxide and binder composition to form pelletized metal oxide particles.

    Abstract translation: 本发明涉及由金属氧化物和粘合剂组成的结合金属氧化物颗粒，粘合剂优选为淀粉溶液。 本发明还涉及形成结合的金属氧化物颗粒的方法，优选的方法包括挤出和造粒金属氧化物和粘合剂组合物以形成颗粒状金属氧化物颗粒。

    Sulfite-oxide process for scavenging hydrogen sulfide
    5.
    发明授权
    Sulfite-oxide process for scavenging hydrogen sulfide 失效
    用于清除硫化氢的亚硫酸盐氧化物工艺

    公开(公告)号：US4835043A

    公开(公告)日：1989-05-30

    申请号：US928788

    申请日：1986-11-10

    Applicant: Irwin Fox ,  Alvin Samuels

    Inventor： Irwin Fox ,  Alvin Samuels

    IPC: C02F1/20 ,  C09K8/16 ,  C23F11/18

    CPC classification number: C02F1/20 ,  C09K8/16 ,  C23F11/18

    Abstract: Adding sodium sulfite in the slurry of the iron oxide slurry process for scavenging hydrogen sulfide described in U.S. Pat. No. 4,246,244, eliminates excessive foaming on start-up, stabilizes the suspension of the oxide particles in the slurry, lessens clogging of reacted particles, which otherwise interferes with cleaning out the reactor vessel, and so materially buffers the slurry as to minimize corrosion of the reactor vessel and piping. Further, adding small amounts of oxygen to the gas stream, which would be expected to cause corrosion, does not do so; instead it prolongs the usefulness of the reactant oxide particles and affords increased acid-stability to the reaction products.

    Abstract translation: 在用于清除硫化氢的氧化铁浆料工艺的浆料中加入亚硫酸钠，描述于美国专利No. 消除了起动时的过度起泡，稳定了浆料中的氧化物颗粒的悬浮液，减少了反应颗粒的堵塞，从而阻碍了反应器容器的清洗，并因此对浆料进行了实质性的缓冲以使腐蚀最小化 反应堆容器和管道。 此外，向预期会引起腐蚀的气流中加入少量氧气不会这样做; 相反，它延长了反应物氧化物颗粒的有用性，并且对反应产物提供了增加的酸稳定性。

    Separately removing mercaptans and hydrogen sulfide from gas streams
    8.
    发明授权
    Separately removing mercaptans and hydrogen sulfide from gas streams 失效
    从气流中分别除去硫醇和硫化氢

    公开(公告)号：US5478541A

    公开(公告)日：1995-12-26

    申请号：US440114

    申请日：1995-05-12

    Applicant: Alvin Samuels ,  Irwin Fox

    Inventor： Alvin Samuels ,  Irwin Fox

    IPC: B01D53/04 ,  B01D53/86 ,  B01J23/745 ,  C07C7/148 ,  C10L3/00 ,  C01B17/16 ,  C01B17/20

    CPC classification number: C10L3/00 ,  B01D53/04 ,  B01D53/8606 ,  B01J23/745 ,  C07C7/1485 ,  B01D2253/102 ,  B01D2253/306 ,  B01D2256/24 ,  B01D2257/304 ,  B01D2257/306

    Abstract: The present invention provides a method for separately removing mercaptans and hydrogen sulfide from a hydrocarbon gas stream by passing the gas through a bed which includes iron oxide which catalyzes the formation of disulfides and trisulfides from mercaptans and also reacts with at least part of the hydrogen sulfide to form acid-stable solids; causing the di- and trisulfides to exit the bed in the gas phase; and removing and recovering the di- and trisulfides by adsorption or condensation. Any remaining hydrogen sulfide may be scavenged from the gas stream by passage through a bed containing iron oxide similar to that used first above. If the gas stream contains substantial amounts of hydrocarbon aerosols, they should be filtered out in advance of the bed.

    Abstract translation: 本发明提供了一种从烃气流中分离除去硫醇和硫化氢的方法，该方法是使气体通过包含氧化铁的床，该氧化铁催化二硫化物和三硫化物从硫醇形成，并且还与硫化氢的至少一部分反应 以形成酸稳定的固体; 导致二硫化物和三硫化物在气相中离开床; 并通过吸附或冷凝除去和回收二硫化物和三硫化物。 任何剩余的硫化氢可以通过与上面所使用的类似的含有氧化铁的床，从气流中清除。 如果气流含有大量的烃类气溶胶，则应在床前过滤掉。

    Scavenging natural gas streams with slurry apparatus
    9.
    发明授权
    Scavenging natural gas streams with slurry apparatus 失效
    用泥浆仪清除天然气流

    公开(公告)号：US4405563A

    公开(公告)日：1983-09-20

    申请号：US346525

    申请日：1982-02-08

    Applicant: Alvin Samuels

    Inventor： Alvin Samuels

    IPC: B01D53/00 ,  C07C7/00 ,  C07C7/148 ,  B01D50/00

    CPC classification number: C07C7/005 ,  B01D53/00 ,  C07C7/148

    Abstract: A system of apparatus is especially adapted to react gaseous contaminates of natural gas streams with a slurry of reactant particles and incorporates a contactor tower with a bottom gas inlet having a screen at its dynamic liquid level to confine downwardly a fill of packer-spacer material. Gas entering through the bottom inlet of the tower is divided by the packer-spacer material in tortuous flow paths maintained by the confining screen.In advance of the contactor tower, after an inlet scrubber, is a heater which elevates the temperature of the gas before it enters the contactor tower. This avoids formation of clogging hydrates and liquefication of the gas. Using an outlet scrubber assures against entrance of droplets of any liquid into the pipeline.

    Abstract translation: 一种装置系统特别适用于使天然气流的气体污染物与反应物颗粒的浆料反应，并将具有底部气体入口的接触塔与动态液面的筛网相结合，向下限制封隔器间隔物料的填充物。 通过塔的底部入口进入的气体由封隔器隔离物材料在由限制屏幕保持的曲折的流动路径中分开。 在接触器塔之前，在进气洗涤器之后，是加热器，其在进入接触器塔之前升高气体的温度。 这避免了堵塞水合物的形成和气体的液化。 使用出口洗涤器可确保任何液体的液滴进入管道。

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