摘要:
A coolant system is proposed for addressing temperature concerns during start-up and shut-down of a cell stack assembly. The coolant system comprises a coolant exhaust conduit in fluid communication with a coolant exhaust manifold and a coolant pump, the coolant exhaust conduit enabling transportation of exhausted coolant away from a coolant exhaust manifold. A coolant return conduit is provided to be in fluid communication with a coolant inlet manifold and a coolant pump, the coolant return conduit enabling transportation of the coolant to the coolant inlet manifold. The coolant system further includes a bypass conduit in fluid communication with the coolant exhaust conduit and the coolant return conduit, while a bleed valve is in fluid communication with the coolant exhaust conduit and a gaseous stream. Operation of the bleed valve enables venting of the coolant from the coolant channels, and through said bypass conduit.
摘要:
A cell stack assembly (102) coolant system comprises a coolant exhaust conduit (110) in fluid communication with a coolant exhaust manifold (108) and a coolant pump (112). A coolant inlet conduit (120) enables transportation of the coolant to the coolant inlet manifold. The coolant system further includes a bypass conduit (132) in fluid communication with the coolant exhaust manifold and the coolant inlet manifold, while a bleed valve (130) is in fluid communication with the coolant exhaust conduit and a source of gas. Operation of the bleed valve enables venting of the coolant from the coolant channels, and through a shut down conduit (124). An increased pressure differential between the coolant and reactant gases forces water out of the pores in the electrode substrates (107,109). An ejector (250) prevents air form inhibiting the pump. Pulsed air is blown (238,239,243,245) through the coolant channels to remove more water.
摘要:
An operating system for a direct antifreeze cooled fuel cell power plant is disclosed for producing electrical energy from reducing and process oxidant fluid reactant streams. The system includes at least one fuel cell for producing electrical energy from the reducing and oxidant fluid streams; fuel processing components for processing a hydrocarbon fuel into the reducing fluid; a thermal management system that directs flow of a cooling fluid for controlling heat within the plant including a porous water transport plate adjacent and in fluid communication with a cathode catalyst of the fuel cell; a direct antifreeze solution passing through the water transport plate; and, a split oxidant passage that directs the process oxidant stream into and through the fuel cell.
摘要:
A membrane electrode assembly includes an anode including a hydrogen oxidation catalyst; a cathode; a membrane disposed between the anode and the cathode; and a peroxide decomposition catalyst positioned in at least one position selected from the group consisting of a layer between the anode and the membrane and a layer between the cathode and the membrane wherein the peroxide decomposition catalyst has selectivity when exposed to hydrogen peroxide toward reactions which form benign products from the hydrogen peroxide. The peroxide decomposition catalyst can also be positioned within the membrane. Also disclosed is a power-generating fuel cell system including such a membrane electrode assembly, and a process for operating such a fuel cell system. The assembly components contain ionomer material which can be perfluorinated or non-perfluorinated, high temperature, hydrocarbon, and the like.
摘要:
A membrane electrode assembly is provided which includes an anode; a cathode; a membrane between the anode and the cathode; and a protective layer between the membrane and at least one electrode of the anode and the cathode, the protective layer having a layer of ionomer material containing a catalyst, the layer having a porosity of between 0 and 10%, an ionomer content of between 50 and 80% vol., a catalyst content of between 10 and 50% vol., and an electrical connectivity between catalyst particles of between 35 and 75%. A configuration using a precipitation layer to prevent migration of catalyst ions is also provided.
摘要:
Chemical vapor deposition (CVD) techniques for forming tough silicon carbide (SiC) matrix composites. The introduction of methyldichlorosilane (MDS) to a reactor containing a fiber preform which been flushed with a noble gas, causes the formation of a carbon layer around the fibers. The carbon interlayer improves the fracture toughness of the composite.
摘要:
A direct antifreeze cooled fuel cell power plant system is disclosed for producing electrical energy from reducing and process oxidant fluid reactant streams. The system includes at least one fuel cell for producing electrical energy from the reducing and oxidant fluid streams; a thermal management system that directs flow of a cooling fluid for controlling temperature within the plant including a porous water transport plate adjacent and in direct fluid communication with a cathode catalyst of the fuel cell; a direct antifreeze solution passing through the water transport plate; and, fuel processing components secured in fluid communication with the thermal management system for processing a hydrocarbon fuel into the reducing fluid and for controlling a concentration of a direct antifreeze in the direct antifreeze solution. The fuel processing components may include a boiler that receives a portion of the direct antifreeze solution from the thermal management system; a steam separator that directs separated steam from the boiler to a reformer for reforming the hydrocarbon fuel to the reducing fluid, and that directs separated liquid direct antifreeze solution back to the thermal management system. A preferred direct antifreeze solution is an alkanetriol selected from the group consisting of glycerol, butanetriol, and pentanetriol.
摘要:
A method of imprinting a workpiece includes lasing the workpiece to create a depression or other opening, depositing a laser-fusible polymer material into the depression, and then lasing the material so as to fuse the material into the depression. Preferably, the laser-fusible polymer material is fusible in the near infrared spectrum. An alternate method for imprinting using colored powder paints includes an additional step of heating the workpiece to ensure thermosetting of the colored powder paint. Laser fusible materials having particular physical characteristics and compositions may be used to facilitate the process.
摘要:
A method for making a high critical current density Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor includes mixing suitable solid state reactants in amounts sufficient to create a reactant mixture having a ratio of approximately 4 Bi atoms:3 Ca atoms:3 Sr atoms:4 Cu atoms and oxygen. The reactant mixture is heated to a sufficient temperature for a sufficient time to sinter the reactant mixture and form a Bi.sub.2 CaSr.sub.2 Cu.sub.2 O.sub.8 superconductor.
摘要翻译:制备高临界电流密度的方法包括混合合适的固态反应物,其量足以产生具有约4个Bi原子:3个Ca原子:3个Sr原子:4个Cu原子和氧的比例的反应物混合物。 将反应混合物加热到足够的温度足够的时间以烧结反应物混合物并形成Bi 2 Ca 2 SrC 2 O 8超导体。
摘要:
A membrane electrode assembly includes an anode; a cathode; a membrane disposed between the anode and the cathode; and an extended catalyzed layer between the membrane and at least one electrode of the anode and the cathode. The extended catalyzed layer includes catalyst particles embedded in membrane material and preferably includes a first plurality of particles which are electrically connected to the at least one electrode. The extended catalyzed layer may further preferably have a second plurality of particles which are electrically disconnected from the at least one electrode.