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公开(公告)号:US09337505B2
公开(公告)日:2016-05-10
申请号:US14007667
申请日:2012-03-31
CPC分类号: H01M8/0618 , C01B3/382 , C01B2203/0244 , C01B2203/042 , C01B2203/0485 , C01B2203/065 , C01B2203/1023 , C01B2203/1247 , C01B2203/1614 , C10G27/04 , C10G2300/1022 , C10G2300/1051 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/4006 , C10G2300/70 , C10G2300/80 , C10G2300/805 , C10G2300/807 , C10G2400/04 , C10G2400/08
摘要: A process of reforming a liquid fuel comprising from greater than 50 ppmw sulfur to less than 400 ppmw sulfur, the process comprising contacting a liquid hydrocarbon fuel comprising one or more organosulfur compounds in a concentration from greater than 50 ppmw to less than 400 ppmw sulfur with an oxidant and steam or water, the contacting occurring in a catalyst bed comprising a reforming catalyst deposited on an ultra-short-channel-length metal substrate, such that the process is conducted at a peak catalyst temperature greater than 950° C. so as to produce a reformate mixture comprising hydrogen and carbon monoxide.
摘要翻译: 将包含大于50ppmw硫的液体燃料重整为小于400ppmw的硫的方法,该方法包括将含有一种或多种浓度从大于50ppmw至小于400ppmw硫的一种或多种有机硫化合物的液体烃燃料与 氧化剂和蒸汽或水,所述接触发生在催化剂床中,所述催化剂床包含沉积在超短通道长度金属基底上的重整催化剂,使得该方法在高于950℃的峰值催化剂温度下进行,以便 以产生包含氢和一氧化碳的重整产物混合物。
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公开(公告)号:US20140017583A1
公开(公告)日:2014-01-16
申请号:US14007667
申请日:2012-03-31
IPC分类号: H01M8/06
CPC分类号: H01M8/0618 , C01B3/382 , C01B2203/0244 , C01B2203/042 , C01B2203/0485 , C01B2203/065 , C01B2203/1023 , C01B2203/1247 , C01B2203/1614 , C10G27/04 , C10G2300/1022 , C10G2300/1051 , C10G2300/1055 , C10G2300/202 , C10G2300/207 , C10G2300/4006 , C10G2300/70 , C10G2300/80 , C10G2300/805 , C10G2300/807 , C10G2400/04 , C10G2400/08
摘要: A process of reforming a liquid fuel comprising from greater than 50 ppmw sulfur to less than 400 ppmw sulfur, the process comprising contacting a liquid hydrocarbon fuel comprising one or more organosulfur compounds in a concentration from greater than 50 ppmw to less than 400 ppmw sulfur with an oxidant and steam or water, the contacting occurring in a catalyst bed comprising a reforming catalyst deposited on an ultra-short-channel-length metal substrate, such that the process is conducted at a peak catalyst temperature greater than 950° C. so as to produce a reformate mixture comprising hydrogen and carbon monoxide.
摘要翻译: 将包含大于50ppmw硫的液体燃料重整为小于400ppmw的硫的方法,该方法包括将含有一种或多种浓度从大于50ppmw至小于400ppmw硫的一种或多种有机硫化合物的液体烃燃料与 氧化剂和蒸汽或水,所述接触发生在催化剂床中,所述催化剂床包含沉积在超短通道长度金属基底上的重整催化剂,使得该方法在高于950℃的峰值催化剂温度下进行,以便 以产生包含氢和一氧化碳的重整产物混合物。
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公开(公告)号:US20110016791A1
公开(公告)日:2011-01-27
申请号:US12460543
申请日:2009-07-21
申请人: Subir Roychoudhury , David Spence , Richard Mastanduno , Dennis E. Walsh , Jun Iwamoto , Go Motohashi , Hitoshi Mikami , Eric Walker
发明人: Subir Roychoudhury , David Spence , Richard Mastanduno , Dennis E. Walsh , Jun Iwamoto , Go Motohashi , Hitoshi Mikami , Eric Walker
IPC分类号: C10J3/48
CPC分类号: B01J8/0278 , B01J4/002 , B01J4/02 , B01J8/001 , B01J2208/00548 , C01B3/386 , C01B2203/0261 , C01B2203/1235 , C01B2203/1247 , C01B2203/1276 , C01B2203/169
摘要: An apparatus for fuel reforming is provided that utilizes pulsed injectors for a fuel flow controller and an air flow controller, and the injectors are integrated with an atomizing mixer thereby producing a fuel-air mixture having an O/C Ratio which, in turn, is passed to a Catalytic Partial Oxidation reactor. Use of this apparatus permits beneficial long term operation of this Catalytic Partial Oxidation reactor.
摘要翻译: 提供一种用于燃料重整的装置,其利用用于燃料流量控制器和空气流量控制器的脉冲喷射器,并且喷射器与雾化混合器一体化,从而产生具有O / C比率的燃料 - 空气混合物,O / C比又是 传递到催化部分氧化反应器。 使用该装置允许这种催化部分氧化反应器的有益的长期操作。
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公开(公告)号:US07396969B2
公开(公告)日:2008-07-08
申请号:US11104858
申请日:2005-04-14
IPC分类号: C07C2/66
CPC分类号: C07C2/66 , C07C15/073
摘要: A process for producing alkyl aromatic compounds which comprises contacting at least one aromatic compound with at least one alkylating agent or transalkylating agent possessing at least one aliphatic group having from 1 to 5 carbon atoms under alkylation or transalkylation reaction conditions and in the presence of an alkylation or transalkylation catalyst, to provide an alkylated aromatic product possessing at least one alkyl group derived from said alkylating agent or transalkylating agent, said catalyst comprising a binder-free molecular sieve having an X-ray diffraction pattern that includes the lines set forth in Table A.
摘要翻译: 一种制备烷基芳族化合物的方法,其包括在烷基化或烷基转移反应条件下和在烷基化存在下使至少一种芳族化合物与至少一种具有至少一个具有1-5个碳原子的脂肪族基团的烷基化剂或烷基转移剂接触 或烷基转移催化剂,以提供具有至少一种衍生自所述烷基化剂或烷基转移剂的烷基的烷基化芳族产物,所述催化剂包含具有X射线衍射图的无粘合剂分子筛,其包括表A所示的线 。
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公开(公告)号:US06641714B2
公开(公告)日:2003-11-04
申请号:US09900069
申请日:2001-07-06
申请人: Dennis E. Walsh
发明人: Dennis E. Walsh
IPC分类号: C10G6902
摘要: Low sulfur gasoline of relatively high octane number is produced from a catalytically or thermally cracked, olefin-rich, sulfur-containing hydrocarbon stream by hydrodesulfurization followed by treatment over an acidic catalyst containing a molecular sieve belonging to the MCM-22 family in combination with a metal component, preferably selected from the transition elements of the 4th and 5th periods of the Periodic Table. The treatment over the acidic catalyst in the second step restores the octane loss which takes place as a result of the hydrogenative treatment and results in a low sulfur gasoline product with an octane number comparable to that of the hydrocarbon feed.
摘要翻译: 相对高辛烷值的低硫汽油是通过加氢脱硫从催化或热裂解的富烯烃,含硫烃流中产生的,然后在含有属于MCM-22族的分子筛的酸性催化剂上与 金属组分,优选选自周期表第4和第5个周期的过渡元素。 在第二步骤中对酸性催化剂的处理恢复了由于氢化处理而发生的辛烷值损失,并导致具有与烃进料相当的辛烷值的低硫汽油产物。
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公开(公告)号:US5053576A
公开(公告)日:1991-10-01
申请号:US456703
申请日:1989-12-26
申请人: Scott Han , Robert E. Palermo , Judy A. Pearson , Dennis E. Walsh
发明人: Scott Han , Robert E. Palermo , Judy A. Pearson , Dennis E. Walsh
IPC分类号: C07C2/84
CPC分类号: C07C2/84 , C07C2529/40 , Y10S585/943
摘要: There is provided a process for the direct partial oxidation of methane with oxygen, whereby organic compounds comprising higher hydrocarbons are produced. The catalyst used in this reaction is a ZnZSM-5 catalyst. This catalyst may be prepared by ion exchanging or impregnating a ZSM-5 catalyst with a suitable zinc salt such as zinc nitrate.
摘要翻译: 提供了用氧直接部分氧化甲烷的方法,由此产生包含高级烃的有机化合物。 在该反应中使用的催化剂是ZnZSM-5催化剂。 该催化剂可以通过用合适的锌盐如硝酸锌离子交换或浸渍ZSM-5催化剂来制备。
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公开(公告)号:US5023392A
公开(公告)日:1991-06-11
申请号:US454536
申请日:1989-12-21
申请人: Scott Han , Robert E. Palermo , Judy A. Pearson , Dennis E. Walsh
发明人: Scott Han , Robert E. Palermo , Judy A. Pearson , Dennis E. Walsh
CPC分类号: C07C29/50 , C07C2/84 , C07C2529/46 , Y10S585/943
摘要: There is provided a process for the direct partial oxidation of methane with oxygen, whereby organic compounds comprising higher hydrocarbons are produced. The catalyst used in this reaction is a CuZSM-5 catalyst. This catalyst may be prepared by ion exchanging or impregnating a ZSM-5 catalyst with a suitable copper salt such as copper nitrate.
摘要翻译: 提供了用氧直接部分氧化甲烷的方法,由此产生包含高级烃的有机化合物。 在该反应中使用的催化剂是CuZSM-5催化剂。 该催化剂可以通过用合适的铜盐如硝酸铜离子交换或浸渍ZSM-5催化剂来制备。
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公开(公告)号:US5012029A
公开(公告)日:1991-04-30
申请号:US422367
申请日:1989-10-16
IPC分类号: C07C2/84
CPC分类号: C07C2/84 , C07C2529/40 , C07C2529/65 , C07C2529/70 , Y10S585/943
摘要: A mixture of organic compounds comprising a major amount of liquid hydrocarbons, mostly aromatic, is formed by the direct partial oxidation of methane in the presence of a ZSM-5 catalyst. The reaction conditions are substantially the same as those required for the direct homogeneous partial oxidation to methanol. However, liquid hydrocarbon formation depends on the presence of a small amount of an impurity such as propane or propylene in the feed; in the absence of such, only methanol is formed. With such modifier present, controls of reaction parameters, e.g., temperature, permits synthesis of both methanol and liquid hydrocarbons in desired proportions. Properly processed natural gas can serve to provide methane and at least part of the reaction modifier.
摘要翻译: 通过在ZSM-5催化剂的存在下甲烷的直接部分氧化形成包含主要量的液体烃(主要是芳族)的有机化合物的混合物。 反应条件与直接均相部分氧化成甲醇所需的条件基本相同。 然而,液态烃的形成取决于进料中少量杂质如丙烷或丙烯的存在; 在不存在的情况下,仅形成甲醇。 使用这种改性剂时,反应参数例如温度的控制允许以所需比例合成甲醇和液态烃。 适当加工的天然气可用于提供甲烷和至少部分反应调节剂。
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公开(公告)号:US4299594A
公开(公告)日:1981-11-10
申请号:US130928
申请日:1980-03-17
申请人: Bruce P. Pelrine , Dennis E. Walsh
发明人: Bruce P. Pelrine , Dennis E. Walsh
CPC分类号: C10L1/04
摘要: A process is provided wherein waste hydrocarbon oils are blended with resids and visbroken resids thereby eliminating the use of more valuable cutting stock.
摘要翻译: 提供了一种方法,其中废烃油与残渣和减粘渣混合,从而消除了更有价值的切割料的使用。
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10.
公开(公告)号:US20110061299A1
公开(公告)日:2011-03-17
申请号:US12924876
申请日:2010-10-06
CPC分类号: B01F3/04049 , B01D2253/112 , B01D2257/304 , B01F5/045 , B01J8/0214 , B01J8/0221 , B01J8/0278 , B01J8/0285 , B01J8/043 , B01J2208/00203 , B01J2208/0053 , B01J2208/00646 , B01J2208/00716 , C01B3/382 , C01B2203/0244 , C01B2203/0455 , C01B2203/0485 , C01B2203/0894 , C01B2203/1276 , F01N2240/30 , F02M25/12 , F02M27/02 , F02M31/125 , Y02T10/121 , Y02T10/126
摘要: The present invention provides a process and apparatus for the gasification of a liquid fuel and includes providing a supply of a liquid fuel, a supply of oxidant, and a supply of liquid water; atomizing the liquid fuel and mixing it with the oxidant and steam; catalytically reacting the fuel-oxidant-steam mixture in a catalyst bed; initiating the catalytic reaction with an ignition source; positioning a heat exchanger in proximity with the catalyst bed so as to convert the liquid water to steam; and feeding the steam into the catalytic reaction, thereby eliminating the need for a liquid fuel vaporizer. A preferred catalyst bed includes an ultra-short-channel-length metal substrate.
摘要翻译: 本发明提供一种用于液化燃料气化的方法和装置,包括提供液体燃料,氧化剂供应和液态水的供应; 雾化液体燃料并将其与氧化剂和蒸汽混合; 在催化剂床中催化反应燃料 - 氧化剂 - 蒸汽混合物; 引发与点火源的催化反应; 将热交换器定位在催化剂床附近,以便将液态水转化成蒸汽; 并将蒸汽进料到催化反应中,从而不再需要液体燃料蒸发器。 优选的催化剂床包括超短通道长度的金属基材。
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